Nutrient chemistry and salinity mapping of the Delhi aquifer,India: source identification perspective

Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na⁺/Cl⁻, SO₄ ²⁻/Cl⁻, Mg²⁺/Ca²⁺ and Ca²⁺/(HCO₃ ⁻ + SO₄ ²⁻) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined landfill sites and drains is the prime cause of NO₃ ⁻ contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined drains.     

Sea Level Variations Associated with Upwelling/ Downwelling Along the West Coast of India

A three-dimensional numerical model is developed and used to study the coastal upwelling processes and corresponding seasonal changes in the sea level along the west coast of India. The upwelling and associated sea level variations are seen as a response of coastal ocean to pure wind stress forcing. The model is designed to represent coastal ocean physics by resolving surface and bottom Ekman layers as realistically as possible. The prognostic variables are the three components of the velocity field, temperature, salinity and turbulent energy. The governing equations together with their boundary conditions are solved by finite-difference techniques. Experiments are performed to investigate sea level fluctuations associated with the thermal response and alongshore currents of the coastal waters. The model is forced with mean monthly wind stress forcing of January, May, July and September representing northeast monsoon and different phases of the southwest monsoon. It is known from the observational study that the upwelling process reaches to the surface waters by May along the coastal waters of the extreme southwest peninsular region. The process is more intense in July compared to May and September and its strength decreases from south to north. However, during the northeast monsoon season, which is represented by January wind stress forcing in the model, downwelling is simulated along the coast. The model simulations of the coastal response are compared with the observations and are found to be in good agreement. The maximum computed vertical velocity of about 2.0 2 10 -3 cm s -1 is predicted in July in the southern region off the coast.     

Characterization of Sediments for Sustainable Development: State of the Art

Sediments are the particulate matter that are transported by the flow of water and eventually get deposited at the bottom of water bodies, such as oceans, rivers, lagoons, and so forth. The deposition of these materials due to continued intervention of natural as well as anthropogenic activities is a serious concern as the storage capacity (or health) of the system is reduced or otherwise affected. Keeping in view the emerging challenges associated with proper disposal and subsequent utilization of sediments, as a manmade resource, their extraction from such locations becomes necessary. Hence, it is essential to characterize the sediments in order to devise strategies to exploit them as a manmade resource in the best possible manner. With this in view, this article highlights the importance of different attributes and aspects of the sediments (viz., physical, chemical, morphological, geotechnical, toxicological, and microbial characteristics) deposited in the water bodies that will help in assessing their potential as a substitute material to natural resources.     

Environment and Deep-Sea Mining: A Perspective

Abstract

As the quest for deep-sea mineral resources is gaining momentum, environment and ocean mining have become important aspects of study. Because many of these deposits occur in international waters, the concern for environmental conservation in view of the effects of deep-sea mining is resulting in these effects being studied in different oceans, and efforts to develop regulations governing this exploitation are also underway at national and international levels. The impact assessment of deep-sea mining needs to encompass a variety of subjects, including environmental, socioeconomic, technological, and legal aspects. At the same time, effects of in situ environmental conditions on mining activities also need to be considered for effecient performance by the mining system. Differences in the degree of impact have been noticed during the mining simulation experiments by different investigating agencies. Therefore, interparameter comparisons, standardization of methods, and improvement in mining design are important considerations for proper utilization of resources, conservation of environment, and cost efficiency of the mining operations.     

Implications of climate change on streamflow of a snow-fed river system of the Northwest Himalaya

Air temperature and snow cover variability are sensitive indicators of climate change. This study was undertaken to forecast and quantify the potential streamflow response to climate change in the Jhelum River basin. The implications of air temperature trends (+0.11°C/decade) reported for the entire north-west Himalaya for past century and the regional warming (+0.7°C/decade) trends of three observatories analyzed between last two decades were used for future projection of snow cover depletion and stream flow. The streamflow was simulated and validated for the year 2007-2008 using snowmelt runoff model (SRM) based on in-situ temperature and precipitation with remotely sensed snow cover area. The simulation was repeated using higher values of temperature and modified snow cover depletion curves according to the assumed future climate. Early snow cover depletion was observed in the basin in response to warmer climate. The results show that with the increase in air temperature, streamflow pattern of Jhelum will be severely affected. Significant redistribution of streamflow was observed in both the scenarios. Higher discharge was observed during spring-summer months due to early snowmelt contribution with water deficit during monsoon months. Discharge increased by 5% 40% during the months of March to May in 2030 and 2050. The magnitude of impact of air temperature is higher in the scenario-2 based on regional warming. The inferences pertaining to change in future streamflow pattern can facilitate long term decisions and planning concerning hydro-power potential, waterresource management and flood hazard mapping in the region.     

Homogenization of Earthquake Catalog for Northeast India and Adjoining Region

A catalog for northeast India and the adjoining region for the period 1897–2009 with 4,497 earthquakes events is compiled for homogenization to moment magnitude M _w,GCMT in the magnitude range 3–8.7. Relations for conversion of m _b and M _s magnitudes to M _w,GCMT are derived using three different methods, namely, linear standard regression, inverted standard regression (ISR) and orthogonal standard regression (OSR), for different magnitude ranges based on events data for the catalog period 1976–2006. The OSR relations for M _s to M _w,GCMT conversion derived in this paper have significantly lower errors in regression parameters compared to the relations reported in other studies. Since the number of events with magnitude ≥7 for this region is scanty, we, therefore, considered whole India region to obtain the regression relationships between M _w,GCMT and M _s,ISC. A relationship between M _w,GCMT and M _w,NEIC is also obtained based on 17 events for the range 5.2 ≤ magnitude ≤ 6.6. A unified homogeneous catalog prepared using the conversion relations derived in this paper can serve as a reference catalog for seismic hazard assessment studies in northeast India and the adjoining region.     

Variation of Seismic Coda Wave Attenuation in the Garhwal Region, Northwestern Himalaya

Seismic coda wave attenuation ( $ Q_{\text{c}}^{ - 1} $ ) characteristics in the Garhwal region, northwestern Himalaya is studied using 113 short-period, vertical component seismic observations from local events with hypocentral distance less than 250?km and magnitude range between 1.0 to 4.0. They are located mainly in the vicinity of the Main Boundary Thrust (MBT) and the Main Central Thrust (MCT), which are well-defined tectonic discontinuities in the Himalayas. Coda wave attenuation ( $ Q_{\text{c}}^{ - 1} $ ) is estimated using the single isotropic scattering method at central frequencies 1.5, 3, 5, 7, 9, 12, 16, 20, 24 and 28?Hz using several starting lapse times and coda window lengths for the analysis. Results show that the ( $ Q_{\text{c}}^{ - 1} $ ) values are frequency dependent in the considered frequency range, and they fit the frequency power law ( $ Q_{\text{c}}^{ - 1} \left( f \right) = Q_{0}^{ - 1} f^{ - n} $ ). The Q ₀ (Q _c at 1?Hz) estimates vary from about 50 for a 10?s lapse time and 10?s window length, to about 350 for a 60?s lapse time and 60?s window length combination. The exponent of the frequency dependence law, n ranges from 1.2 to 0.7; however, it is greater than 0.8, in general, which correlates well with the values obtained in other seismically and tectonically active and highly heterogeneous regions. The attenuation in the Garhwal region is found to be lower than the Q _c ^?1 values obtained for other seismically active regions of the world; however, it is comparable to other regions of India. The spatial variation of coda attenuation indicates that the level of heterogeneity decreases with increasing depth. The variation of coda attenuation has been estimated for different lapse time and window length combinations to observe the effect with depth and it indicates that the upper lithosphere is more active seismically as compared to the lower lithosphere and the heterogeneity decreases with increasing depth.     

Biodegradation Studies on Acid Violet 19, a Triphenylmethane Dye,by Pseudomonas aeruginosa BCH

Acid violet 19 (AV) belongs to the triphenylmethane (TPM) class of dyes which are potentially mutagenic or carcinogenic. However, very little studies on biodegradation of AV were reported as compared to other TPM dyes such as malachite green and crystal violet. In this study, AV was decolorized up to 98% within 30 min by Pseudomonas aeruginosa BCH. The decolorization depends on the initial dye concentration, pH, and temperature. However, the dye was decolorized under wide pH and temperature ranges with an optimum of pH 7 and 30°C. Up to 250 mg L^?1 of dye was found to be tolerated and decolorized by this strain. It showed decolorization ability for seven repeated dye addition cycles. The effect of additional carbon sources on dye decolorization was studied in which mannitol containing medium showed decolorization in 15 min. Induction in the enzyme activities of laccase, NADH‐DCIP reductase, and veratryl alcohol oxidase (VAO) indicates their involvement in AV degradation. Various analytical studies viz. UV–VIS, HPTLC, HPLC, and FTIR confirmed the biodegradation of AV by the bacterium. Based on GC‐MS analysis, a possible degradation pathway for AV was proposed. The phytotoxicity studies using Phaseolus mungo and Sorghum vulgare revealed the less toxic nature of metabolites formed after AV degradation.