Geochemical and isotopic evidence for upward flow of saline fluid to the Mississippi River Valley alluvial aquifer,southeastern Arkansas,USA

Hydrogeology Journal - Groundwater from the Quaternary Mississippi River Valley Alluvial (MRVA) aquifer in southeastern Arkansas (SE AR), USA, has higher salinity compared to other MRVA...     

职业足球比赛期间球场周边扒窃犯罪的空间分布特征研究

现阶段,关于足球比赛等体育活动影响周边区域犯罪风险的研究主要关注于一般性验证,而缺少对比赛期间不同时间范围内犯罪风险的态势分析及相关空间影响因素的研究。本文以英国伯明翰市的维拉公园球场为例开展实证研究,对2005—2009年赛季的104场职业足球比赛在比赛日和对照日、开赛前和开赛后等不同时间范围内球场周边3 km区域内发生的扒窃类案件的空间分布特征进行了分析,并利用负二项回归模型研究了相应案件的空间影响要素。结果表明：维拉公园球场周边区域内比赛日期间的扒窃案件发案量要明显高于对照日,而在具体的时间分布上,比赛日开赛时间前2小时到开赛后1小时内发生的扒窃案件显著偏多,并且案件在比赛日和对照日、比赛日的开赛前和开赛后期间的空间分布特征明显不同;回归分析结果显示,比赛日期间餐饮消费类场所的扒窃案件风险较为突出,且高于对照日,而对照日期间的扒窃案件风险则主要集中于休闲娱乐等常规性犯罪热点场所;在比赛日的开赛前,扒窃案件风险主要分布于一些人群聚集的公共场所,而在开赛后则主要集中于餐饮类场所,且随着比赛的开始扒窃案件的风险有转移的趋势。本研究对开展基于大数据分析的大型体育活动的犯罪风险精准防控具有一定的指导意义。     

北美内陆西部白垩纪脊椎动物生物年代学

北美西部内陆白垩纪的脊椎动物生物年代学的研究始于19世纪90年代。前人建议的期,即陆生脊椎动物"期"或陆生哺乳动物"期"名已过十二个,但其中具有精确的定义者甚少,仅有少量的建议受到广泛认可和使用。本文定义或重新定义了10个陆生脊椎动物"期",包括了西部内陆从最老至最新的全部白垩纪—Comobluffian期(～提塘期至欧特里沃期)、Buffalogapian期(～巴列姆期至早阿普特期)、Cashenranchian期(～早阿普特期至晚阿尔布期)、Mussentuchian期(～晚阿尔布期至塞诺曼期)、Fencelakean期(土伦期至晚塞农期)、Aquilan期(～晚塞农期至早坎潘期)、Judithian期(～中坎潘期)、Kirtlandian期(～晚坎潘期)、Edmontonian期(～坎潘期末期至早马斯特里赫特期)以及Lancian期(～早马斯特里赫特期晚期)。每一个"期"的开始由一种恐龙或哺乳动物种类的首现来定义,而其结束由后续的"期"的开始来定义。这样定义的脊椎动物生物年代代表了完整的白垩纪时间表。但有些时间段(尤其是Neocomian(尼欧克姆期)的大部分以及部分"中"白垩世的一部分)缺乏足够的脊椎动物化石特征。这些白垩纪陆生脊椎动物"期"构成了一个能使北美西部内陆的脊椎动物的演化历史得以序和解释年代表。     

An Exploratory Non‐Destructive Provenance Analysis of Two Middle Archaic Greenstone Pendants from Little Salt Spring,Florida, USA

Test excavations in 2005 and 2006 of the Little Salt Spring mortuary pond in Southwest Florida (USA) yielded two exotic stone pendants indirectly dated to the Middle Archaic (7000–5000 ¹⁴C year B.P.). Hand‐specimen petrographic observation, combined with non‐destructive environmental scanning electron microscopy, X‐ray fluorescence spectroscopy, and whole‐rock X‐ray diffraction, identified the pendants as (1) a mica‐plagioclase‐edenite amphibolite or schist and (2) an intermediate pyroxene‐ and/or amphibole‐bearing granitoid. Provenance was broadly constrained to a number of potential sources in the southern Appalachian Piedmont of the United States (at a minimum distance of 650 km from the archaeological findspot) utilizing the United States Geological Survey's National Geologic Map Database lithologic search tool (GEOLEX) and Mineral Resources On‐Line Spatial Data GIS database. Due to the absence of lithologic matches within the state of Florida, we propose that the two artifacts most likely arrived at Little Salt Spring through down‐the‐line exchange of materials of prestige value with geologic origins in the southern Appalachian Piedmont, arguing for the existence of small‐scale long‐distance lithic exchange networks reaching into Archaic Florida. From a methodological standpoint, this study illustrates the potential utility of data collected under nonideal, non‐destructive analytical conditions for deriving meaningful archaeological interpretations.     

Natural Radon and Radium Isotopes for Assessing Groundwater Discharge into Little Lagoon,AL: Implications for Harmful Algal Blooms

Naturally occurring isotopes of radon (²²²Rn) and radium isotopes (^{223,224,226,228}Ra) were used as tracers to assess submarine groundwater discharge (SGD) into Little Lagoon, AL (USA), a site of recurring harmful algal blooms (HABs). The radium isotopic data suggests that there are two groundwater sources of these tracers to the lagoon, a shallow (A1) and deeper (A2) aquifer. We estimated the fraction of each source via a three-end-member mixing model consisting of Gulf of Mexico seawater, shallow and deep groundwater. The estimated lagoonwide SGD rates based on a radium mass balance and the mixing model were 1.22?±?0.53 and 1.59?±?0.20 m³ s^-1 for the shallow and deep groundwater discharges, respectively. To investigate temporal variations in SGD, we performed several radon surveys from 2010 through 2012, a period of generally declining groundwater levels due to a drought in the southeastern USA. The total SGD rates based on a radon mass balance approach were found to vary from 0.60 to 2.87 m³ s^-1. We observed well-defined relationships between nutrients and chlorophyll-a in lagoon waters during a period when there was an intense diatom bloom in April 2010 and when no bloom existed in March 2011. A good correlation was also found between radium (groundwater-derived) and nutrients during the April 2010 period, while there was no clear relationship between the same parameters in March 2011. Based on multivariate analysis of chemical and environmental factors, we suggest that nutrient-rich inputs during high SGD may be a significant driver of algal blooms, but during low SGD periods, multiple drivers are responsible for the occurrence of algal blooms.     

Seasonal Alternation Between Groundwater Discharge and Benthic Coupling as Nutrient Sources in a Shallow Coastal Lagoon

Submarine groundwater discharge (SGD) is now recognized as an important source of nutrients and freshwater to some coastal environments. We studied a shallow coastal lagoon (Little Lagoon, AL, USA) in the northern Gulf of Mexico that lacks riverine inputs but has been suspected to receive significant SGD. We observed persistent salinity gradients between the east and west ends of the lagoon and the pass connecting it to the Gulf of Mexico. Covariance between salinity in the lagoon and the groundwater tracer ²²²Rn indicated that SGD was responsible for the salinity gradients and is the primary source of freshwater to the lagoon. Cluster analysis of 246 biweekly samples based on temperature, salinity, and two proxies of SGD revealed two hydrographic regimes with different drivers for nutrient inputs. In samples characterized by high discharge and low temperatures (generally December–April), total nitrogen (TN) was negatively correlated with salinity, while total phosphorus (TP) was positively correlated with temperature. Total nitrogen in the groundwater was very high (0.36–4.80 mM) while total phosphorus was relatively low (0.3–2.3 μM), consistent with SGD as the source of TN during the high-discharge periods. In periods with low discharge and higher temperatures (approx. May–November), TN and TP had strong positive correlations with temperature and are inferred to originate from benthic efflux. Seasonal changes in nutrient stoichiometry in the lagoon water column also indicate an alternation between low TN/TP sediments and high TN/TP groundwater as the primary sources of nitrogen in this system.     

A laser fluorination method for oxygen isotope analysis of biogenic silica and a new oxygen isotope calibration of modern diatoms in freshwater environments

An empirical calibration for the oxygen isotope fractionation between biogenic silica and water was determined for diatom frustules sampled from living diatom communities in the Jemez Mountains of northern New Mexico, USA. Over a temperature range from 5.1 to 37.8 °C, the silica-water fractionation is defined by the equation 1000 ln α_{(silica-water)} = 2.39(±0.13) × 10⁶T⁻² + 4.23(±1.49). This relationship is in close agreement with other published silica-water fractionation factors for laboratory cultured diatom samples; however, it is as much as 8‰ lower than equilibrium quartz-water fractionations and 3-4‰ lower than observed silica-water fractionations in diatomaceous silica collected from sediment traps and sediment cores. There are three possible explanations for the disparate silica-water fractionation factors observed in diatom silica: (1) silica does not precipitate in equilibrium with ambient water, (2) silica does precipitate in equilibrium with ambient water, but the silica-water fractionation factor for diatom silica is considerably less than the equilibrium fractionation factor for quartz-water, or (3) silica precipitation is influenced by a ‘vital’ effect, where the δ¹⁸O value of the water inside the diatom cell walls is lower than the δ¹⁸O values of ambient water.Post-mortem loss of organic material results in an alteration or ‘maturation’ of diatom silica in which silica reequilibrates with a silica-water fractionation closer to the equilibrium quartz-water fractionation. Alteration is likely to occur rapidly after the diatom frustule loses its organic coating, either as it settles through the water column or at the sediment-water interface; δ¹⁸O values recorded by paleo-diatom silica therefore do not record growing conditions but more likely record conditions at the sediment-water interface. In the case of lacustrine environments, where the bottom water remains at a nearly constant 4 °C, the reequilibration of diatom silica with bottom conditions could reduce or remove the conflating effects of temperature on δ¹⁸O values recorded by paleo-diatom silica and provide direct information on the δ¹⁸O value of the lake water.     

Laboratory Comparison of Crushed Aggregate and Recycled Pavement Material With and Without High Carbon Fly Ash

In-place recycling of asphalt pavement materials is a sustainable rehabilitation method. Existing hot-mix asphalt (HMA) layer is pulverized and blended with some or the entire base course and possibly some subgrade to form a broadly graded material referred to as recycled pavement material (RPM). The RPM is then compacted as the new base course and overlaid by a new layer of HMA. In some occasions, additives are added to increase the strength of RPM base course, such as cement, emulsion, fly ash. It is plausible to utilize high calcium high carbon fly ash, as the high level of carbon prevents fly ash from being used in concrete. A series of laboratory tests were conducted to evaluate the performance of these materials, including crushed aggregate, untreated RPM, and treated RPM with high carbon fly ash. The tests included compaction, California Bearing Ratio, resilient modulus, and unconfined compressive strength for treated RPM. The engineering properties of these materials were compared.     

Field report: Exploring the Doonerak fenster of the central Brooks Range,Alaska, USA

Arctic Alaska is a ‘suspect’ terrane that encompasses approximately 20% of Alaska, stretching from the southern Brooks Range all the way to the continental shelves of the Chukchi and Beaufort Seas. Although the origin and subsequent travels of this large crustal fragment are debated among geologists, most researchers agree upon its composite nature and exotic origin. To constrain the early geological history of this terrane, we describe a recent expedition to the Doonerak fenster of the central Brooks Range. This area has long been regarded as a key locality for understanding the structural evolution of the Mesozoic–Cenozoic Brooks Range orogen; however, our target was different: a unique sequence of volcanic and siliciclastic rocks (Apoon assemblage) exposed beneath a profound pre-Mississippian unconformity, which we argue is of key importance to understanding the early Paleozoic tectonic history of northern Alaska and the greater Arctic.