Laboratory investigations of inert gas flow behaviors in compact sandstone

The seepage evolution behavior of compact rock is significant for the stability and safety of many engineering applications. In this research, both hydrostatic and triaxial compression tests were conducted on compact sandstone using an inert gas, namely argon. A triaxial compression test with a water permeability measurement was carried out to study the difference between the gas permeability and water permeability evolutions during the complete stress–strain process. Based on the experimental data, the hydrostatic stress-dependent gas permeability was discussed firstly. A second-order function was proposed to predict and explain the gas slippage effect. The mechanical properties and crack development of the sandstone samples were discussed to better understand the permeability evolution with crack growth during the complete stress–strain process. The results show that the gas permeability evolution can be divided into five stages according to the different crack growth stages. Then, the permeability changes in the crack closure stress \( \sigma_{\text{cc}} \), crack initiation stress \( \sigma_{\text{ci}} \), crack damage stress \( \sigma_{\text{cd}} \) and peak stress \( \sigma_{\text{p}} \) with confining pressures were analyzed. Finally, we found that the difference between the corrected gas permeability and water permeability can be attributed to the interaction between the water and sandstone grains.     

Club convergence and spatial distribution dynamics of carbon intensity in China’s construction industry

Climate change caused by carbon emissions continuously threatens sustainable development. Due to China’s immense territory, there are remarkable regional differences in carbon emissions. The construction industry, which has strong internal industrial differences, further leads to carbon emission disparity in China. Policymakers should consider spatial effects and attempt to eliminate carbon emission inequality to promote the sustainable development of the construction industry and realize emission reduction targets. Based on the classic Markov chain and spatial Markov chain, this paper investigates the club convergence and spatial distribution dynamics of China’s carbon intensity in the construction industry from 2005 to 2014. The results show that the provincial carbon intensity in the construction industry is characterized by “convergence clubs” during the research period, and very low-level and very high-level convergence clubs have strong stability. Moreover, the carbon intensity class transitions of provinces tend to be consistent with that of their neighbors. Furthermore, the transition of carbon intensity types is highly influenced by their regional backgrounds. The provinces with high carbon emissions have a negative influence on their neighbors, whereas the provinces with low carbon emissions have a positive influence. These analyses provide a spatial interpretation to the “club convergence” of carbon intensity.     

基于通用计算的涪江中段径流模拟研究

为了提高传统径流汇流模拟的时效性,提出了一种基于通用计算的径流汇流模型。模型采用纳维-斯托克斯作为基础方程。首先,文章探讨了利用通用计算进行径流汇流模拟的实现方法并设计了模拟计算流程。然后,以涪江流域中段为研究区域,将流域内25个常规站和区域站的实况降水数据为数据源,分别利用本文径流汇流模型和FloodArea模型对流域进行径流模拟,并将两种模型模拟结果与水文站实测数据进行对比分析。结果发现,基于通用计算的径流汇流模型不仅在模拟效率上相对于FloodArea模型有很大程度的提高,而且模拟结果具有更小的水位变化误差,与水文站实测水文数据具有更好拟合效果。模拟时效性和结果准确性的同时提升表明本文的径流汇流模型对暴雨洪涝预警预报具有重要的意义。     

南黄海CSDP-2井晚泥盆世早期真蕨类Shougangia的形态观察

南黄海CSDP-2钻井上泥盆统五通组擂鼓台段2 068.00~2 069.02 m段岩心识别出了早期真蕨类植物。该植物具有至少三次羽状复叶,末二次羽片互生,小羽片扁平,呈扇状、楔状或舌状,基部收缩,至少一次深裂,裂片边缘钝圆,二分叉的叶脉明显。据此,可鉴定为优美守刚蕨（比较种）（Shougangia cf.S.bella）。本研究为南黄海地区上泥盆统五通组增加了古植物学新资料。     

溶液和温度作用下膨润土防水毯的渗透性能

以颗粒状和粉末状膨润土防水毯(GCLs)为对象,运用GDS (global digital systems)全自动渗透仪开展渗透试验,研究CaCl_2溶液作用下GCLs渗透性能的温度效应,初步探讨其机理。试验表明:当水化液为0.05mol/L的CaCl_2溶液时,两种GCLs渗透系数随温度升高呈现增大趋势;当水化液为去离子水时,颗粒状GCL渗透系数随温度升高而减小,粉末状GCL渗透系数随温度升高而增大。去离子水情况下,膨润土吸附结合水量随温度升高而减小;CaCl_2溶液作用下,吸附结合水量较去离子水情况大幅降低。当CaCl_2溶液浓度一定时,膨润土膨胀指数随温度升高而略有增大;当温度一定时,膨润土膨胀指数随CaCl_2溶液浓度升高而显著减小。以去离子水进行试验时:颗粒状和粉末状GCLs渗透系数随温度的变化主要影响因素为凝胶态蒙脱石数量,其次为流体黏滞系数和吸附结合水量;颗粒状GCLs膨润土孔隙结构越不均匀,凝胶态蒙脱石数量的影响就越显著,导致渗透系数随温度升高而减小、固有渗透率随温度升高显著降低。以CaCl_2溶液进行试验时,两种GCLs渗透系数随温度变化的主要受流体黏滞系数和吸附结合水量的影响,而受凝胶态蒙脱石数量的影响较小。孔隙溶液性质、温度和膨润土类型均对GCLs的防渗性能具有重要影响。     

强造斜致绳索取心钻具折断分析

在定向钻探固体矿产领域,通常在造斜段使用螺杆钻具,大部分的工作量采用取心回转钻进。造斜段使用螺杆钻具,钻杆不回转,受力较简单;如遇强造斜转换绳索取心钻具稳斜钻进,下部钻具组合容易出现回转困难、下不到底的技术难题,甚至出现丝扣折断事故。为避免强造斜对绳索取心钻具的影响,本文通过建立强造斜段对绳索取心钻具的几何约束变形模型,量化分析强造斜段岩心外管长度与造斜强度、环空间隙之间的约束关系,提供了可快速预判下部钻具参数能否满足强造斜安全钻进的方法。该方法在山东某铁矿定向孔的强造斜致下部钻具折断的事故处理中,通过对绳索取心钻具安全计算模型校核和调整钻具参数,实现了绳索取心钻具通过造斜率0.62°/m的强造斜段安全钻进至靶点,证明对强造斜绳索取心工具安全钻进预测和事故处理计算具有指导意义。     

熊耳山—外方山矿集区中生代Au-Mo成矿系统

熊耳山—外方山矿集区位于秦岭造山带之华北板块南缘,经历了复杂的碰撞造山过程,成矿时间跨度大,成矿强度高,成矿作用多样。复合造山过程和相应的成矿作用已被深入研究,但成矿系统的划分和叠加成矿作用尚需研究。本文将熊耳山—外方山矿集区发育的Au-Mo矿床划分为造山型Mo矿床、斑岩型Mo矿床、岩浆热液脉型Mo矿床、造山型Au矿床和岩浆热液型Au矿床5个类型,对应5种成矿系统：(1)造山型Mo矿床形成于250~227 Ma的同碰撞环境和227~194 Ma的后碰撞环境,为变质热液萃取壳源Mo成矿;(2)斑岩型Mo矿床形成于163~135 Ma的洋陆俯冲环境和135~116 Ma的岩石圈减薄环境,为岩浆热液携带幔源或壳源Mo成矿;(3)岩浆热液脉型Mo矿床形成于227~194 Ma的后碰撞环境,为岩浆热液携带幔源Mo成矿;(4)造山型Au矿床在三叠纪发生了预富集作用,主要形成于163~135 Ma的洋陆俯冲环境和135~103 Ma的岩石圈减薄环境,为变质热液萃取壳源Au成矿;(5)岩浆热液型Au矿床仅形成于135~103 Ma的岩石圈减薄环境,为岩浆热液携带壳源Au成矿。矿集区主要存在两种叠加成矿作用,即不同构造背景下多种成矿系统的叠加和同一构造背景下不同成矿系统的叠加。     

西秦岭太阳山斑岩铜-钼矿床岩体氧逸度及成矿意义

甘肃天水三叠纪太阳山斑岩铜钼矿床位于西秦岭造山带东段。矿体主要赋存于石英闪长斑岩、二长斑岩、石英二长斑岩和泥盆系大草滩群。氧逸度是表征岩石物理化学性质的重要参数,对岩浆热液成矿具有明显的控制作用。在综合评述常用氧逸度计算方法及适用性的前提下,文中应用激光剥蚀等离子质谱分析方法对太阳山矿床含矿岩体锆石微量元素进行测定,选用含量较高的Sm、Nd进行Ce异常计算,查明含矿斑岩岩浆氧逸度,探讨其成矿意义。太阳山矿床岩浆氧逸度计算结果表明,太阳山成矿二长斑岩和石英二长斑岩相对氧逸度ΔFMQ分别为+3.04和+3.15,成矿前石英闪长斑岩相对氧逸度ΔFMQ为-1.83,成矿岩体氧逸度明显高于成矿前岩体。成矿岩体岩浆氧逸度高于成矿前岩体的原因可能与富集地幔有关。富集岩石圈地幔的加入,带来了大量的硫和金属铜,并提高了岩浆氧逸度。     

基于概率积分法的潜山型地裂缝空间预测方法研究

苏南地区锡北镇地裂缝灾害活跃,且为典型的基岩潜山型抽水沉降地裂缝。以无锡锡北镇杨墅里地裂缝为研究对象（31.703174°~31.705488°N,120.452707°~120.453410°E）,基于非连续介质理论,运用概率积分方法建立基岩潜山条件下的抽水沉降裂缝空间预测数学模型。运用该理论模型计算得出基岩潜山上覆岩土体的差异性沉降规律、地表倾斜程度及地表曲率变化规律,并指出地表倾斜程度与地表曲率为地裂缝易发位置的重要评价指标。将地裂缝空间预测数学模型计算出的沉降规律、地裂缝发生位置等结果与物理模型试验结果进行对比研究,结果显示：1）当W"（x）=0时,地表倾斜函数取得极值,此时x=±0.8 m,表明距模型左边界2.6 m与4.2 m处地表倾斜程度最大,差异性沉降最为明显。2）当W"'（x）=0时,地表曲率函数取得极值,x=0,表明在距模型左边界3.4 m处地表曲率最大,为拉应力集中位置。3）模型试验地裂缝集中发生2.4~2.6 m、3.3~3.5 m和3.9~4.2 m这3处;基于概率积分方法的潜山型地裂缝空间预测结果与物理模型试验结果基本一致。预测模型能够合理解释物理模型试验中潜山山腰及潜山山顶三处地裂缝的发生位置,验证了其正确性,为地裂缝空间预测方法提供了新的研究思路。