On the Eulerian source-receptor relationship

A new approach is proposed to delineate the source-receptor relationship in an Eulerian model. A small, unique oscillatory signal is superimposed on each emission source in the airshed. At receptor sites the concentration time series are analyzed by a Fourier transform to give the amplitudefrequency spectrum. Distinct peaks found in the spectrum are identified at the emission frequencies. The amplitude of the spectrum at the source frequency represents the individual contribution from that emitter. Various atmospheric transport and diffusion models are solved to show the effects of different physical and chemical processes on the oscillatory signals. Both analytical and numerical solutions are used to demonstrate the performance of the method.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Contents of Volume 30

Volume Contents

Contents of Volume 30     

A composed index of critical accessibility (CICA) to healthcare services in a traditional African City

While empirical works that analyse rural–urban differentials in accessibility to health services are common in the developing countries, systematic studies focusing on intra-urban variations in accessibility to overall healthcare resources remain scant. Yet, many urban dwellers especially in the Sub-Saharan Africa have to travel long distances within the urban space to access basic health services. This study employs composed index of critical accessibility (CICA) to analyse differentials in access to health resources in Ibadan, a traditional African City. Data on healthcare centre location, ownership, doctors’ population were collected through field survey while spatial data on the administrative units and populated places were obtained from archival sources. Also, data on road networks was collected. Results show that the distribution of health facilities across local administrative units varies. In terms health facilities, Ibadan South West has 26 (36 %) of the total number while Ibadan South east has only 7 (9.8 %). The Doctor-Population Ratio also exhibits similar variations as Ibadan North has 20.5 as against 2.2, 1.9 and 0.3 for Ibadan SW, Ibadan NW and Ibadan NE respectively. The CICA analysis shows that 228,938 inhabitants are in high risk of negative accessibility while 49,234 are faced with condition of low risk of negative accessibility, which implies that a significant proportion of the population still finds it difficult to access basic health services as and when needed. The variations in the distribution of this deprived population are also noteworthy as the largest proportion of this group was localized in Ibadan NW. This has grave implication for the health and wellbeing of the population and raises once again the question of spatial equity in the delivery of urban public service. Curiously, these differences in the level of accessibility cut across administrative boundaries which brings to the fore the role of jurisdictional partitioning in ensuring equity in the delivery of urban public services. This opens a vista of research opportunity into the role jurisdictional partitioning in service provision in the urban centres.     

Pseudotachylytes in the Balmuccia peridotite (Ivrea Zone) as markers of the exhumation of the southern Alpine continental crust

Two types of pseudotachylytes are observed in the Balmuccia peridotite of the Ivrea zone (Southern Alps, Italy). A-type pseudotachylytes correspond to previously studied occurrences and were formed under temperatures comprising between 550 and 900 °C and pressures comprising between 0.6 and 1.2 GPa. These conditions were met in the Ivrea crust between 350 and 270 Ma, suggesting that A-type pseudotachylytes were formed during Variscan tectonics or Permian transtensional tectonics. B-type pseudotachylytes post-date A-type pseudotachylytes. Textural characteristics of B-type veins suggest a formation in the upper continental crust, at depths of about 5–10 km or less. Petrological constraints indicate that the exhumation of the Ivrea crust at such shallow depths was achieved later than c.  70 Ma, thus providing a maximum age of 70 Ma for B-type veins. Pseudotachylytes appear as markers of the poly-orogenic evolution of the Alpine belt.     

Application of pyrolysis–GC/MS for the characterisation of suspended particulate organic matter in the Mediterranean Sea: a comparison with the Black Sea

Suspended particulate organic matter (SPOM) both from the oligotrophic Mediterranean and from the more productive Black Sea has been analysed by pyrolysis–gas chromatography/mass spectrometry (Py–GC/MS) and by such conventional techniques as elemental analysis and fluorometry. The data achieved by the two approaches generally confirmed and complemented each other. The relative concentrations of pyrolysis products (termed markers) characteristic of chlorophyll (CHL), lipid, carbohydrate (CBH), and protein (PROT) components of SPOM have been determined. The vertical distribution of lipid markers was more uniform in the Mediterranean surface waters. Their relative abundance increased rapidly in the oxycline of the Black Sea, reaching their highest levels in the suboxic zone, where the protein composition of the SPOM changed significantly. In both seas, the relative concentrations of CHL markers increased consistently within the CHL maximum zone where the CBH markers were less abundant. No lignin markers from terrestrial vegetation were detected at significant levels in the pyrograms.     

Fammenian–Tournaisian dextral ductile shear in the French Variscan belt

The South Armorican Shear Zone consists of a set of faults that runs across the southern Armorican Massif and extends eastwards to the Massif Central. One of its branches, the Cholet Shear Zone of South Brittany, can be correlated with the North-Millevaches–La Courtine Shear Zone in the Massif Central. It was active immediately after the regional Frasnian anatexis (372–368 Ma) as a right-lateral strike-slip fault. The horizontal offset, which can be estimated between 110 and 170 km, was achieved before the emplacement of non-deformed Late Tournaisian calc-alkaline and peraluminous granites (355–350 Ma). This newly established age of activity (Fammenian–Tournaisian) of the Cholet–La Courtine Shear Zone (CCSZ) has to be taken into account in geodynamical reconstructions of the Variscan belt of western Europe. To cite this article: C. Cartannaz et al., C. R. Geoscience 338 (2006).     

Social media insights on public perception and sentiment during and after disasters: The European floods in 2021 as a case study

Detecting and collecting public opinion via social media can provide near real-time information to decision-makers, which plays a vital role in urban disaster management and sustainable development. However, there has been little work focusing on identifying the perception and the sentiment polarity expressed by users during and after disasters, particularly regional flood events. In this article, we comprehensively analyze tweets data related to the “European floods in 2021” over time, topic, and sentiment, forming a complete workflow from data processing, topic modeling, sentiment analysis, and topic and sentiment prediction. The aim is to address the following research questions: (1) What are the public perception and main concerns during and after floods? (2) How does the public sentiment change during and after floods? Results indicate that there is a significant correlation between a flood's trend and the heat of corresponding tweets. The three topics that receive the most public concern are: (1) climate change and global warming; (2) praying for the victims: and (3) disaster situations and information. Negative sentiments are predominant during the floods and will continue for some time. We tested five different classifiers, of which TextCNN-attention turned out to deliver the best predictions in topic and sentiment prediction, and performed well for sparse flood tweets, it can be used to predict the topic and sentiment polarity of a single tweet in real-time during the flood events. Our findings can help disaster agencies to better understand the dynamics of social networks and develop stronger situational awareness towards a disaster, which can contribute to scientifically justified decision-making in urban risk management and also meet the challenges associated with the global sustainable development goal 11 (SDGs) on Sustainable Cities and Communities.     

Soiling of limestone in an urban environment characterized by heavy vehicular exhaust emissions

The inorganic and organic chemical composition of weathering sulphate patinas on the limestone walls of Emmanuel College, Cambridge, UK, have been analysed by FT-IR spectroscopy, pyrolysis gas-chromatography/mass spectrometry and scanning electron microscopy. The College location is characterized by heavy vehicular exhaust emissions including those from diesel powered public transport vehicles due to its proximity to the main Cambridge coach station. A complex mixture of gaseous and particulate air pollutants are found deposited in the weathering patinas including organic compounds (such as PAHs), which represent markers for present-day vehicular pollution. Slight differences in composition between patinas collected at different heights on the building facades with, in particular, more evidence for a biogenic overprint in samples collected at roof level as opposed to ground (street) level are found. Analytical results confirm how building stones in urban areas acted in the past and still do today as passive repositories for any kind of gaseous and particulate air pollutant present in the surrounding atmosphere; accordingly, weathering patinas are slowly changing their composition to accommodate new classes of present-day air pollutants.     

Apparent Microfloral Response to Organic Degradation on Bathyal ­Seafloor: An Analysis Based on Sediment Fatty Acids

Abstract. Abyssal microfloral succession induced by experimental organic degradation was investigated. Notable changes in amounts and compositions of short-chain (C9-20) sediment fatty acids were observed, which indicated the shift of sediment microflora. Biomarker fatty acids for methanotrophs and sulfate-reducing bacteria dominated. Resultant fatty acid compositions were most closely related to those from a nearby methane seep harboring a dense Calyptogena colony; the clams were also seen in close vicinity of the deployed organic mass. These observations suggest that the organic degradation on the bathyal seafloor stimulates the formation of methanotrophic and thio­trophic microflora, resulting in the formation of a methane-seep-type benthic community.