Origin of rare earth element anomalies in mangrove sediments,Sepetiba Bay,SE Brazil: used as geochemical tracers of sediment sources

Elemental contents were determined in two mangrove habitats along Sepetiba Bay, SE Brazil, an area impacted by local industrial activities, as well as hinterland water diversion networks. This study demonstrates how specific REEs (La, Ce, Nd, Sm, Eu, Tb, Yb and Lu) may be used as a sediment source tracer to mangrove-dominated coastlines. From the two stations studied, a pair of cores was collected, one in the mangrove forest and the other in the tidal flat. Station 1 results show a general enrichment in most of the fractioned patterns of the REEs normalised by Post-Archean Australian Shale. The relatively light rare earth elements are similarly enriched in the generally more polluted Station 1. Despite the probable difference in background sediment characteristics, a common sharp increase in mud contents patterns in the upper part of the mangrove sediment core was related to a lower REE content as well as Eu anomalies. With existing knowledge of clockwise water circulation in the bay, these patterns can be explained by man-made water diversion from the São Francisco and Guandu rivers, initiated more than 30 years ago, whereby suspended matter with relatively large contents of REEs and material originating from industrial sources accumulate in the eastern sector of the bay. This is the first comprehensive assessment of REEs as sedimentary tracers in a mangrove ecosystem in Brazil.     

A long‐term vegetation history of the Mojave–Colorado desert ecotone at Joshua Tree National Park

Thirty‐eight dated packrat middens were collected from upper desert (930–1357 m) elevations within Joshua Tree National Park near the ecotone between the Mojave Desert and Colorado Desert, providing a 30 ka record of vegetation change with remarkably even coverage for the last 15 ka. This record indicates that vegetation was relatively stable, which may reflect the lack of invasion by extralocal species during the late glacial and the early establishment and persistence of many desert scrub elements. Many of the species found in the modern vegetation assemblages were present by the early Holocene, as indicated by increasing Sørenson's Similarity Index values. C₄ grasses and summer‐flowering annuals arrived later at Joshua Tree National Park in the early Holocene, suggesting a delayed onset of warm‐season monsoonal precipitation compared to other Sonoran Desert and Chihuahuan Desert localities to the east, where summer rains and C₄ grasses persisted through the last glacial–interglacial cycle. This would suggest that contemporary flow of monsoonal moisture into eastern California is secondary to the core processes of the North American Monsoon, which remained intact throughout the late Quaternary. In the Holocene, northward displacement of the jet stream, in both summer and winter, allowed migration of the subtropical ridge as far north as southern Idaho and the advection of monsoonal moisture both westward into eastern California and northward into the southern Great Basin and Colorado Plateau. Copyright © 2009 John Wiley & Sons, Ltd.     

Architecture and recognition criteria of ancient shelf ridges; an example from Campanian Almond Formation in Hanna Basin,USA

Shelf ridges are sedimentary bodies formed on the continental shelf due to transgressive reworking (tidal or storm) of lowstand deposits. Common on modern shelves, they are under‐represented in the geological record due to a lack of recognition criteria and facies model. This article proposes a new facies and architectural model for shelf ridges, linked to their inception–evolution–abandonment cycle and the process regime of the basin. The model is mainly based on new outcrop data and interpretations from three sandstone bodies of the Almond Formation, an overall transgressive interval during the infill of the Campanian Western Interior Seaway. Building from the case study, and ancient and modern examples, six characteristics are proposed for the recognition of ancient shelf ridges. Shelf ridges: (i) are encased between thick marine mudstone intervals; (ii) have a basal unconformity that erodes into marine muds or into the remnants of a previous shoreline; (iii) have a non‐erosional upper boundary that transitions into marine muds; (iv) are characterized by clean and well‐sorted sandstones, often cross‐bedded; (v) contain fully marine ichnofauna; and (vi) present compound architectures with large accretion surfaces and lower order structures. Although shelf ridges have been described in previous studies as generated exclusively by either tidal or storm currents, it is clear, from modern examples and the case study, that these two processes can be recorded and preserved in a single shelf ridge. The stratigraphy of these sandstone bodies is therefore much more complex than previously recognized, bearing the signature of changing tidal and storm intensity through time. Because they are developed during transgressions, shelf ridges are commonly subject to strong changes in process regime as sea‐level changes can easily affect the oceanographic conditions and the morphology of the basin. For this reason, shelf ridges can provide the best record of shelf process variability during transgressions.     

A 16,000 C yr B.P. packrat midden series from the USA–Mexico Borderlands

A new packrat midden chronology from Playas Valley, southwestern New Mexico, is the first installment of an ongoing effort to reconstruct paleovegetation and paleoclimate in the U.S.A.–Mexico Borderlands. Playas Valley and neighboring basins supported pluvial lakes during full and/or late glacial times. Plant macrofossil and pollen assemblages from nine middens in the Playas Valley allow comparisons of two time intervals: 16,000–10,000 and 4000–0 ¹⁴C yr B.P. Vegetation along pluvial lake margins consisted of open pinyon–juniper communities dominated by Pinus edulis, Juniperus scopulorum, Juniperus cf. coahuilensis, and a rich understory of C₄ annuals and grasses. This summer-flowering understory is also characteristic of modern desert grassland in the Borderlands and indicates at least moderate summer precipitation. P. edulis and J. scopulorum disappeared or were rare in the midden record by 10,670 ¹⁴C yr B.P. The late Holocene is marked by the arrival of Chihuahuan desert scrub elements and few departures as the vegetation gradually became modern in character. Larrea tridentata appears as late as 2190 ¹⁴C yr B.P. based on macrofossils, but may have been present as early as 4095 ¹⁴C yr B.P. based on pollen. Fouquieria splendens, one of the dominant desert species present at the site today, makes its first appearance only in the last millennium. The midden pollen assemblages are difficult to interpret; they lack modern analogs in surface pollen assemblages from stock tanks at different elevations in the Borderlands.     

Neutron Activation Analysis Applied to the Determination of Heavy Metals and Other Trace Elements in Sediments from Sepetiba Bay (RJ), Brazil

In this work, instrumental neutron activation analysis (INAA) was applied to the determination of the elements As, Ba, Br, Ce, Co, Cr, Cs, Eu, Fe, Hf, La, Lu, Nd, Rb, Sc, Sm, Ta, Tb, Th, U, Yb, Zn in twenty eight bottom sediment samples from Sepetiba Bay, Rio de Janeiro, Brazil. With the concentration data obtained, contour maps were prepared, by using Kriging method, to show the spatial distribution of the studied elements in the Bay. The elements Co, Cr, Cs, Fe, Sc, Ta and Zn showed similar behaviour in the sediments, with higher concentrations along the northern coast of the bay, where the fluvial water inputs are concentrated. The distribution of U, rare earth elements and Ba in the Bay indicates that these elements are not deposited as contaminants.     

Inorganic nitrogen in coral reef sediments

Representative profiles of inorganic nitrogenous species dissolved in interstitial waters of coral reef sands are presented. Ammonium is the dominant nitrogenous species in these pore waters with concentrations of up to 40 μm. Nitrate is present but in lower concentrations. Nitrite is found only occasionally in trace amounts. Computations of diffusive fluxes and inferences concerning microbial activity are derived from the profile structures. Computed flux rates of nitrogenous species from the sediment to the water column range between 0.75 and 1.37 μM m⁻¹ h⁻¹. These inputs may represent a significant source of recycled nitrogen to the primary producers of the coral reef ecosystem.     

Vegetation changes and sequential flowering after rain in the southern Atacama Desert

We describe the changes in plant cover, species richness, and flowering after rainfall over an entire growing season (September 1989–January 1990) in a southern Atacama Desert site in Chile. One month after the rain, vegetation was dominated by annuals and geophytes which dried out after 19 weeks. Among all species, including shrubs, we found differences of 4–10 weeks in the length and peak of the flowering period. The flowering sequence of the species belonging to the families Brassicaceae, Liliaceae, Onagraceae, and Asteraceae matched closely the sequences described for temperate plant communities, suggesting that this phenological character is phylogenetically determined.