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211.
Franciane de Carvalho Gomes Jos Marcus Godoy Maria Luiza D.P. Godoy Zenildo Lara de Carvalho Ricardo Tadeu Lopes Joan Albert Sanchez-Cabeza Luiz Drude de Lacerda Julio Cesar Wasserman 《Marine pollution bulletin》2009,59(4-7):123
Three sediment cores were sampled at Sepetiba Bay and four cores at Ribeira Bay, Rio de Janeiro State, Brazil. Sediment accumulation rates and chronologies were obtained from 210Pb activity-depth profiles. Sediment accumulation rates in Ribera Bay ranged from 1.2 mm y−1 in the inner bay to 2.6 mm y−1 close to its entrance. In Sepetiba Bay two sediment accumulation rates were observed: a lower rate of 0.35 cm y−1 before the 1960s and 0.76 cm y−1 since then. The cause of this change is due to the construction of the Santa Cecília impoundment (1955) that brings water from the Paraíba do Sul Basin into the Guandu River, which increased its flow from the original 20 m3 s−1 to 160 m3 s−1. Concentration of 44 elements was obtained by ICP-MS after total dissolution of samples from two selected cores. The relative differences between the concentrations of crustal elements, such as Al, Fe and Ti are only about 20% (p < 0.05). Cd and Zn are 15 and four times larger in Sepetiba Bay than in Ribeira Bay, respectively. Other major and minor elements show lower statistically significant differences. The enrichment factors and metal inventories show that Sepetiba Bay can be considered polluted with Bi, Cd, Cr, Cu, Sb and Zn. Particularly, Cd and Zn present concentrations three and four times higher than the Brazilian existing limits. 相似文献
212.
Marinella A. Laurenzi Maria Laura Balestrieri Giulio Bigazzi Julio C. Hadler Neto Pedro J. Iunes Pio Norelli Massimo Oddone Ana Maria Osorio Araya José G. Viramonte 《Geostandards and Geoanalytical Research》2007,31(2):105-124
New analyses have been performed in order to enhance the data-set on the independent ages of four glasses that have been proposed as reference materials for fission-track dating. The results are as follows. Moldavite - repeated 40 Ar/39 Ar age determinations on samples from deposits from Bohemia and Moravia yielded an average of 14.34 ± 0.08 Ma. This datum agrees with other recent determinations and is significantly younger than the 40 Ar/39 Ar age of 15.21 ± 0.15 Ma determined in the early 1980s. Macusanite (Peru) -four K-Ar ages ranging from 5.44 ± 0.06 to 5.72 ± 0.12 Ma have been published previously. New 40 Ar/39 Ar ages gave an average of 5.12 ± 0.04 Ma. Plateau fission-track ages determined using the IRMM-540 certified glass and U and Th thin films for neutron fluence measurements agree better with these new 40 Ar/39 Ar ages than the previously published ages. Roccastrada glass (Italy) - a new 40 Ar/39 Ar age, 2.45 ± 0.04 Ma, is consistent with previous determinations. The Quiron obsidian (Argentina) is a recently discovered glass that has been proposed as an additional reference material for its high spontaneous track density (around 100 000 cm-2 ). Defects that might produce "spurious" tracks are virtually absent. An independent 40 Ar/39 Ar age of 8.77 ± 0.09 Ma was determined and is recommended for this glass. We believe that these materials, which will be distributed upon request to fission-track groups, will be very useful for testing system calibrations and experimental procedures. 相似文献