A new titanium-bearing calcium aluminosilicate phase: II. Crystallography and crystal chemistry of grains formed in slowly cooled melts with bulk compositions of calcium- aluminum-rich inclusions

Abstract The crystallography and crystal chemistry of a new calcium-titanium-aluminosilicate mineral (UNK) observed in synthetic analogs to calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites was studied by electron diffraction techniques. The unit cell is primitive hexagonal or trigonal, with a = 0.790 ± 0.002 nm and c = 0.492 ± 0.002 nm, similar to the lattice parameters of melilite and consistent with cell dimensions for crystals in a mixer furnace slag described by Barber and Agrell (1994). The phase frequently displays an epitactic relationship in which melilite acts as the host, with (0001)_UNK | (001)_mel and <10T0>_UNK | <100>_mel. If one of the two space groups determined by Barber and Agrell (1994) for their sample of UNK is applicable (P3ml or P31m), then the structure is probably characterized by puckered sheets of octahedra and tetrahedra perpendicular to the c-axis with successive sheets coordinated by planar arrays of Ca. In this likely structure, each unit cell contains three Ca sites located in mirror planes, one octahedrally coordinated cation located along a three-fold axis and five tetrahedrally coordinated cations, three in mirrors and two along triads. The octahedron contains Ti but, because there are 1.3–1.9 cations of Ti/formula unit, some of the Ti must also be in tetrahedral coordination, an unusual but not unprecedented situation for a silicate. Tetrahedral sites in mirror planes would contain mostly Si, with lesser amounts of Al while those along the triads correspondingly contain mostly Al with subordinate Ti. The structural formula, therefore, can be expressed as with Si + Ti = 4. Compositions of meteoritic and synthetic Ti-bearing samples of the phase can be described in terms of a binary solid solution between the end-members Ca₃TiAl₂Si₃O₁₄ and Ca₃Ti(AlTi)(AlSi₂)O₁₄. A Ti-free analog with a formula of Ca₃Al₂Si₄O₁₄ synthesized by Paque et al. (1994) is thought to be related structurally but with the octahedral site being occupied by Al, that is      

Ethnicity as a cause of migration in Eastern Europe

Migration within and from Eastern Europe has recently risen as a topic of significance on the European political agenda. One aspect of this complex migration matrix relates to ethnic unrest. This paper examines the scale and spatial ramifications of this movement on a part of the continent recently freed from communist rule.An attempt is made to divide the ethnic quilt of Eastern Europe into those countries with few such problems and those with many. It is possible then to define areas of active migration (hot spots) from those of potential migration (inflammable spots) based on predictions from the current situation.Active ethnic migration results from the present political/military instability in the western Balkans, where refugees have left for other parts of Europe to escape the present Croat-Serb-Muslim conflict. War escalation could encourage potential ethnic migration from Kosovo, the Sandzak and Vojvodina regions,and Macedonia within the former Yugoslavia. Future disquiet elsewhere could stimulate ethnic groups such as the Turks in Bulgaria,and the Hungarian minorities in Slovakia and Romania to join this migration movement scenario.     

Amino acid composition of organic matter associated with carbonate and non-carbonate sediments

Amino acids comprise from 15 to 36% by weight of humic substances from carbonate and non-carbonate sediments. Humic and fulvic acids extracted from carbonate sediments are characterized by an amino acid composition consisting primarily of the acidic amino acids, aspartic and glutamic acid. Humic substances from non-carbonate sediments have a distinctly different amino acid composition consisting primarily of glycine and alanine. Amino acid analyses of various molecular weight fractions of fulvic acids extracted from carbonates show that lower molecular weight fractions have appreciably higher relative abundances of the acidic amino acids compared to higher molecular weight fractions. Based on typical values for carboxyl group content in humic substances, acidic amino acids may be a significant contributor of these functional groups. Carbonate surfaces appear to selectively adsorb aspartic acid-enriched organic matter while non-carbonates do not have this property.     

The place of individuals in the politics of scale

Conceptualizations and re-conceptualizations of scale have been powerful tools for explaining spatial processes that transcend traditionally-bounded territories. Examining the role of individuals within a politics of scale can do even more to explain multi-scalar conflicts. This paper does so by examining struggles over airport expansion in the US, showing how an understanding of the various roles of individuals in the politics of scale – as sites of multiple scales, as actors constituting other scales, and as scales in and of themselves – better explains multi-scalar conflicts and offers more opportunities for resolving them.     

Late Cretaceous reactivation of major crustal shear zones in northern Namibia: constraints from apatite fission track analysis

Namibia's passive continental margin records a long history of tectonic activity since the Proterozoic. The orogenic belt produced during the collision of the Congo and Kalahari Cratons in the Early Proterozoic led to a zone of crustal weakness, which became the preferred location for tectonism during the Phanerozoic. The Pan-African Damara mobile belt forms this intraplate boundary in Namibia and its tectonostratigraphic zones are defined by ductile shear zones, where the most prominent is described as the Omaruru Lineament–Waterberg Thrust (OML–WT). The prominance of the continental margin escarpment is diminished in the area of the Central and Northern Zone of the Damara belt where the shear zones are located. This area has been targeted with a set of 66 outcrop samples over a 550-km-long, 60-km-broad coast-parallel transect from the top of the escarpment in the south across the Damara sector to the Kamanjab Inlier in the north. Apatite fission track age and length data from all samples reveal a regionally consistent cooling event. Thermal histories derived by forward modelling bracket this phase of accelerated cooling in the Late Cretaceous. Maximum palaeotemperatures immediately prior to the onset of cooling range from ca. 120 to ca. 60 °C with the maximum occurring directly south of the Omaruru Lineament. Because different palaeotemperatures indicate different burial depth at a given time, the amount of denudation can be estimated and used to constrain vertical displacements of the continental crust. We interpret this cooling pattern as the geomorphic response to reactivation of basement structures caused by a change in spreading geometry in the South Atlantic and South West Indian Oceans.     

Modeling hydrodynamics and aquaculture waste transport in coastal maine

Net-pen aquaculture results in the introduction of excess fish food and fecal matter in coastal waters. These wastes may modify the benthic environment. Mathematical models are developed in this study to simulate tidal and wind-driven currents, waves, and the resulting dispersion of fish food and fecal matter in coastal Maine, a region where limited modelling studies have been performed. Cobscook Bay and Toothacher Bay in Maine are studied in detail through the use of mathematical models and field data. We find that a systematic, site-specific, step-by-step modeling strategy involving the use of numerical models to simulate the overall hydrodynamic environment in combination with a waste-particle transport model can be an extremely powerful method of determining a priori whether aquaculture operations will cause high rates of net-pen waste accumulation at a particular site.     

Current controlled sediment deposition from the shelf to the deep ocean: the cenozoic evolution of circulation through the SW pacific gateway

 The circulation of cold, deep water is one of the controlling factors of the Earth's climate. Forty percent of this water enters the world ocean through the Southwest Pacific as a deep western boundary current (DWBC) flowing northwards at bathyal to abyssal depths, east of the New Zealand microcontinent. South of latitude 50°S, the DWBC is intimately linked with the Antarctic circumpolar current (ACC), which is the prominent force for the shallow-water circulation. The Pacific DWBC is presently the largest single contributor of deep ocean water, and deciphering its evolution is of fundamental importance to understanding ocean and climate history, and global ocean hydrography. The evolution of the DWBC system, and of related circum-Antarctic currents, has taken place since 30–25 Ma when plate movements created the first oceanic gaps south of Australia and South America. The stratigraphic record preserved in sediment drifts of the Southwest Pacific, in eastern New Zealand, is the best available for deciphering the Neogene history of Southern Ocean water masses, and of the circulation of the ACC, DWBC and their precursor systems. Major current activity commenced on the New Zealand margin in the late Eocene or early Oligocene (Hoiho Drift; early ACC) and was widespread by the mid-late Oligocene (Marshall Paraconformity and Weka Pass Limestone drift; ACC). During the Neogene the eastern South Island continental shelf built seawards by accretion at its outer edge of large Miocene current drifts up to tens of kilometres long and hundreds of metres thick (Canterbury drifts). Also commencing in the mid-Cenozoic, but in depths >2000 m, the DWBC emplaced large deep-water sediment drifts. Rates of drift deposition accelerated considerably in the late Neogene, when climatic change (and particularly glacial sea-level falls) caused the delivery of large volumes of turbiditic sediment into the path of the DWBC via the Bounty and Hikurangi channels. Received: 9 August 1995 / Accepted: 15 January 1996     

Magmatic processes that generated the rhyolite of Glass Mountain, Medicine Lake volcano, N. California

Glass Mountain consists of a 1 km³, compositionally zoned rhyolite to dacite glass flow containing magmatic inclusions and xenoliths of underlying shallow crust. Mixing of magmas produced by fractional crystallization of andesite and crustal melting generated the rhyolite of Glass Mountain. Melting experiments were carried out on basaltic andesite and andesite magmatic inclusions at 100, 150 and 200 MPa, H₂O-saturated with oxygen fugacity controlled at the nickel-nickel oxide buffer to provide evidence of the role of fractional crystallization in the origin of the rhyolite of Glass Mountain. Isotopic evidence indicates that the crustal component assimilated at Glass Mountain constitutes at least 55 to 60% of the mass of erupted rhyolite. A large volume of mafic andesite (2 to 2.5 km³) periodically replenished the magma reservoir(s) beneath Glass Mountain, underwent extensive fractional crystallization and provided the heat necessary to melt the crust. The crystalline residues of fractionation as well as residual liquids expelled from the cumulate residues are preserved as magmatic inclusions and indicate that this fractionation process occurred at two distinct depths. The presence and composition of amphibole in magmatic inclusions preserve evidence for crystallization of the andesite at pressures of at least 200 MPa (6 km depth) under near H₂O-saturated conditions. Mineralogical evidence preserved in olivine-plagioclase and olivine-plagioclase-high-Ca clinopyroxene-bearing magmatic inclusions indicates that crystallization under near H₂O-saturated conditions also occurred at pressures of 100 MPa (3 km depth) or less. Petrologic, isotopic and geochemical evidence indicate that the andesite underwent fractional crystallization to form the differentiated melts but had no chemical interaction with the melted crustal component. Heat released by the fractionation process was responsible for heating and melting the crust. Received: 26 March 1996 / Accepted: 14 November 1996     

RURAL DEVELOPMENT IN EL HATILLO, NICARAGUA: GENDER, NEOLIBERALISM AND ENVIRONMENTAL RISK

El Hatillo is a rural community in the Sébaco valley in Nicaragua, which suffers from an eroding resource base, high levels of poverty and malnutrition, and a high susceptibility to hazards. Structural adjustment policies have been devastating for small and subsistence farmers and have increased the level of economic, social and environmental marginalisation in rural Nicaragua. This paper explores initiatives to promote sustainable development in Nicaragua in the context of structural adjustment and environmental degradation. Drawing on qualitative research conducted in El Hatillo, it outlines the ways in which women in this community are attempting to address the multiple challenges of rural poverty and environmental risk and considers the potential of these strategies for gender equality.     

The International Laser Ranging Service and its support for IGGOS

The International Laser Ranging Service (ILRS) was established in September 1998 as a service within the IAG to support programs in geodetic, geophysical, and lunar research activities and to provide data products to the International Earth Rotation Service (IERS) in support of its prime objectives. Now in operation for 5 years, the ILRS develops: (1) the standards and specifications necessary for product consistency and (2) the priorities and tracking strategies required to maximize network efficiency. The service collects, merges, analyzes, archives and distributes satellite and lunar laser ranging data to satisfy a variety of scientific, engineering, and operational needs and encourages the application of new technologies to enhance the quality, quantity, and cost effectiveness of its data products. The ILRS works with: (1) the global network to improve station performance; (2) new satellite missions in the design and building of retroreflector targets to maximize data quality and quantity and (3) science programs to optimize scientific data yield. The ILRS Central Bureau maintains a comprehensive web site as the primary vehicle for the distribution of information within the ILRS community. The site, which can be accessed at: http://ilrs.gsfc.nasa.gov is also available at mirrored sites at the Communications Research Laboratory (CRL) in Tokyo and the European Data Center (EDC) in Munich.During the last 2 years, the ILRS has addressed very important challenges: (1) data from the field stations are now submitted hourly and made available immediately through the data centers for access by the user community; (2) tracking on low satellites has been significantly improved through the sub-daily issue of predictions, drag functions, and the real-time exchange of time biases; (3) analysis products are now submitted in SINEX format for compatibility with the other space geodesy techniques; (4) the Analysis Working Group is heavily engaged in Pilot Projects as it works toward an ILRS “standard” global solution and (5) SLR has significantly increased its participation in the International Terrestrial Reference Frame (ITRF) activity, which is important to the success of IGGOS.