Basalt geochemistry and tectonic discrimination within continental flood basalt provinces

Continental flood basalts are usually regarded as a single tectonomagmatic entity but frequently quoted examples exhibit a variety of tectonic settings. In one well-studied, classic, flood basalt province, the Mesozoic Karoo province of southern Africa, magmatism occurred in the following tectonic settings: (a) continental rifting leading to ocean-floor spreading in the South Atlantic Ocean (Etendeka suite of Namibia); (b) stretched continental lithosphere and rifting not leading directly to ocean-floor formation (Lebombo suite of southeastern Africa); and (c) an a-tectonic, within-plate, continental setting characterized by an absence of faulting or warping (Lesotho highlands and Karoo dolerites of South Africa). By means of spidergrams of the elements Rb, Ba, Th, Nb, K, La, Ce, Sr, Nd, P, Hf, Zr, Sm, Ti, Tb, Y, V, Ni and Cr, uncontaminated tholeiites from (c) above [i.e. the Lesotho-type continental flood basalts (LTCFB)] are compared with mid-ocean ridge basalts (MORB), ocean-island tholeiites (OIT), and tholeiites and calc-alkali basalts from subduction environments. The comparison reveals the LTCFBs are geochemically distinct. The differences are reflected in relative enrichments or depletions of the more incompatible elements (Rb-Ce) to less incompatible elements (Ce-Y), i.e. the overall slope of the spidergrams, and in anomalous enrichments or depletions of one or more of the elements Th, K, Nb, Sr, Ti, Hf, and Zr. The distinctive geochemical character of the Lesotho LTCFBs is interpreted in terms of a lithospheric mantle source for the basalts. This is supported by isotopic data. There are no major geochemical differences between Lesotho CFBs and basalts of the rift-related Etendeka and Lebombo suites, although the latter are somewhat enriched in Rb, Ba and K. However, unlike the Lesotho basalts, the Lebombo and Etendeka basalts are associated with voluminous silicic volcanics or intrusive centres and late-stage dolerites having MORB/OIT (i.e. asthenospheric) geochemical characteristics. The flood basalt/silicic magmatism/late-stage dyke swarm association is characteristic of several rift or thinned lithosphere environments (e.g., Ethiopia, Skye, eastern Greenland) but in many of these the flood basalts have ocean-island basalt (OIT) geochemical characteristics. The Lesotho-type CFB geochemistry is exhibited by the Grande Ronde Basalt of the Columbia River Group (a possible subduction-related flood basalt province) and the basic rocks associated with Mesozoic rifting in the North and South Atlantic. Basalt geochemistry alone is unhelpful in determining the tectonic setting of CFBs although the rift-related environments may be identified by the petrology and geochemistry of the whole igneous suite. A two-source model is proposed for the mantle-derived basic rocks in rift-related CFB provinces. Early enriched basalts are derived from the lithosphere and, following pronounced lithospheric attenuation or rifting, later MORB-like melts are emplaced from the rising asthenosphere. The presence of both Lesotho- and OIT-type geochemical patterns in rift-related CFBs suggests that the lithosphere exhibits different styles of enrichment.     

'Toheroa Wars': Cultural politics and everyday resistance on a northern New Zealand beach

Abstract:  This paper examines how the cultural politics of resource management were played out on the North Kaipara beach between about 1900 and 1971 between Māori and the representative of the Crown, the Marine Department. Particular attention is devoted to how, after regulations were introduced to protect toheroa, the giant surf clam, Māori struggled to assert their rights through a range of transgressions. The paper argues that this illustrates how cultural politics works both from the top down (the Marine Department's implementation of policy) and the bottom up (Māori resistance). It concludes that through an examination of this particular 'culture war', the foreshore emerges as a contested domain where politics, culture and epistemology are inseparable.     

Poverty, vulnerability and the impact of flooding in the Limpopo Province, South Africa

The article evaluates household vulnerability after the 2000 flood in two poor communities of the Limpopo Province, South Africa. The study analyses the forms of vulnerability which disasters such as floods present. Using data gathered from a survey of households, the study presents the impacts, coping and adapting strategies of households after the 2000 flood. The article argues that beyond the concern over socio-economic circumstances as the major determinant of household vulnerability, the management of the disaster can serve to perpetuate vulnerability.     

Defect properties of albite

Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi₃O₈), as well as the Schottky defect energy for the removal of a Na₂O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.     

Between-Population Differences in Multi-stressor Tolerance During Embryo Development in the American Horseshoe Crab, <Emphasis Type="Italic">Limulus polyphemus</Emphasis>

The American horseshoe crab, Limulus polyphemus, is found along the Atlantic and Gulf of Mexico coasts in genetically isolated populations. Eggs are laid in shoreline beaches that expose developing embryos to combinations of environmental stressors. Whether populations of L. polyphemus differ in multi-stressor tolerance had never been tested. We assessed the multi-stressor tolerance of L. polyphemus embryos from a population in Delaware Bay (DE) and determined whether these differed from the multi-stressor tolerance of embryos from a more southerly Florida Gulf Coast (FGC) population. We monitored the field sediment temperatures and determined multi-stressor tolerance of DE embryos, then compared these to published data for FGC embryos. For multi-stressor tolerance, we assessed development success of embryos in 2-week exposures to 36 full-factorial combinations of temperature (20, 25, 30, 35 °C), salinity (5, 15, and 34 ppt), and ambient O₂ (5, 13, and 21% O₂), followed by 2 weeks in recovery conditions. Sediment temperatures in the DE site ranged from 9.5 to 46 °C, with extended periods exceeding 35 °C. Development success was similar between the DE and FGC populations in 14 of 26 multi-stressor combinations. The DE embryos were generally more successful in conditions that included high temperature or moderate hyposalinity, whereas the FGC embryos were generally more successful in conditions that included extreme hyposalinity. This suggests that although multi-stressor tolerances are generally similar between the two populations, specific differences exist that correlate more with differences in nest microenvironment than latitude.     

Monte Carlo simulation of mixing in Ca3Fe2Ge3O12–Ca4Ge4O12 garnets and implications for the thermodynamic stability of pyrope–majorite solid solution

Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca₃Fe₂Ge₃O₁₂ and Ca₄Ge₄O₁₂. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca²⁺ and Ge⁴⁺ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite.     

Modelling flow resistance in vegetated streams: review and development of new theory

Aquatic macrophytes are often the dominant factor influencing flow conditions within the channels they occupy. Existing knowledge of how stream plants affect the flow is outlined, and the different scales at which vegetation resistance operates are proposed. Resistance is shown to be a function of the size of the plants, their structural properties, location in the channel, and the local flow conditions. Current models to calculate this composite resistance effect are assessed in the light of theoretical considerations of the nature of vegetation resistance. New theory is also presented, which demonstrates the non‐linear relationship between channel resistance and the proportion of the channel occupied by vegetation. Copyright © 2004 John Wiley & Sons, Ltd.