Seasonal surface ocean circulation and dynamics in the Philippine Archipelago region during 2004–2008

The dynamics of the seasonal surface circulation in the Philippine Archipelago (117°E–128°E, 0°N–14°N) are investigated using a high-resolution configuration of the Regional Ocean Modeling System (ROMS) for the period of January 2004–March 2008. Three experiments were performed to estimate the relative importance of local, remote and tidal forcing. On the annual mean, the circulation in the Sulu Sea shows inflow from the South China Sea at the Mindoro and Balabac Straits, outflow into the Sulawesi Sea at the Sibutu Passage, and cyclonic circulation in the southern basin. A strong jet with a maximum speed exceeding 100 cm s⁻¹ forms in the northeast Sulu Sea where currents from the Mindoro and Tablas Straits converge. Within the Archipelago, strong westward currents in the Bohol Sea carry the surface water of the western Pacific (WP) from the Surigao Strait into the Sulu Sea via the Dipolog Strait. In the Sibuyan Sea, currents flow westward, which carry the surface water from the WP near the San Bernardino Strait into the Sulu Sea via the Tablas Strait.These surface currents exhibit strong variations or reversals from winter to summer. The cyclonic (anticyclonic) circulation during winter (summer) in the Sulu Sea and seasonally reversing currents within the Archipelago region during the peak of the winter (summer) monsoon result mainly from local wind forcing, while remote forcing dominates the current variations at the Mindoro Strait, western Sulu Sea and Sibutu passage before the monsoons reach their peaks. The temporal variations (with the mean removed), also referred to as anomalies, of volume transports in the upper 40 m at eight major Straits are caused predominantly by remote forcing, although local forcing can be large during sometime of a year. For example, at the Mindoro Strait, the correlation between the time series of transport anomalies due to total forcing (local, remote and tides) and that due only to the remote forcing is 0.81 above 95% significance, comparing to the correlation of 0.64 between the total and local forcing. Similarly, at the Sibutu Passage, the correlation is 0.96 for total versus remote effects, comparing to 0.53 for total versus local forcing. The standard deviations of transports from the total, remote and local effects are 0.59 Sv, 0.50 Sv, and 0.36 Sv, respectively, at the Mindoro Strait; and 1.21 Sv, 1.13 Sv, and 0.59 Sv at the Sibutu Passage. Nonlinear rectification of tides reduces the mean westward transports at the Surigao, San Bernardino and Dipolog Straits, and it also has non-negligible influence on the seasonal circulation in the Sulu Sea.     

Future vegetation changes in thawing subarctic mires and implications for greenhouse gas exchange—a regional assessment

One of the major concerns regarding climate change in high latitudes is the potential feedback from greenhouse gases (GHG) being released from thawing peat soils. In this paper we show how vegetational patterns and associated GHG fluxes in subarctic palsa (peat mounds with a permanently frozen core) mires can be linked to climate, based on field observations from fifteen palsa sites distributed in northern Fennoscandia. Fine resolution (100?m) land cover data are combined with projections of future climate for the 21st century in order to model the potential future distribution of palsa vegetation in northern Fennoscandia. Site scale climate-vegetational relationships for two vegetation types are described by a climate suitability index computed from the field observations. Our results indicate drastic changes in the palsa vegetational patterns over the coming decades with a 97?% reduction in dry hummock areas by 2041?C2060 compared to the 1961?C1990 areal coverage. The impact of these changes on the carbon balance is a decrease in the efflux of CO₂ from 130 kilotonnes C y^?1 to a net uptake of 11 kilotonnes C y^?1 and a threefold increase in the efflux of CH₄ from 6 to 18 kilotonnes C y^?1 over the same period and over the 5,520?km² area of palsa mires. The combined effect is equivalent to a slight decrease in CO₂-C emissions, from 182 to 152 kilotonnes C y^?1. Main uncertainties involve the ability of the vegetation community to adapt to new conditions, and long-term changes in hydrology due to absence of ice and frost heaving.     

REDISTRIBUTION AND MIXING OF SOIL GRAVELS BY TREE UPROOTING*

Gravel distributions within treethrow mounds and adjacent undisturbed soils in Wisconsin and Pennsylvania were examined to determine the pedoturbation effects of tree uprooting. Erosion of fine materials from the fresh root plate and subsequent treethrow mound leaves gravels as a lag deposit forming surface gravel armors. Continued slow erosion of remaining nongravelly materials diminishes topograhic expression of the mound. In time, gravel armors remain as the only evidence of past uprooting events.     

Magma storage prior to the 1912 eruption at Novarupta, Alaska

New analytical and experimental data constrain the storage and equilibration conditions of the magmas erupted in 1912 from Novarupta in the 20th century's largest volcanic event. Phase relations at H₂O+CO₂ fluid saturation were determined for an andesite (58.7 wt% SiO₂) and a dacite (67.7 wt%) from the compositional extremes of intermediate magmas erupted. The phase assemblages, matrix melt composition and modes of natural andesite were reproduced experimentally under H₂O-saturated conditions (i.e., P_H2O=P_TOT) in a negatively sloping region in T-P space from 930 °C/100 MPa to 960 °C/75 MPa with fO₂~NNO+1. The H₂O-saturated equilibration conditions of the dacite are constrained to a T-P region from 850 °C/50 MPa to 880 °C/25 MPa. If H₂O-saturated, these magmas equilibrated at (and above) the level where co-erupted rhyolite equilibrated (~100 MPa), suggesting that the andesite-dacite magma reservoir was displaced laterally rather than vertically from the rhyolite magma body. Natural mineral and melt compositions of intermediate magmas were also reproduced experimentally under saturation conditions with a mixed (H₂O + CO₂) fluid for the same range in P_H2O. Thus, a storage model in which vertically stratified mafic to silicic intermediate magmas underlay H₂O-saturated rhyolite is consistent with experimental findings only if the intermediates have X_H2O^fl=0.7 and 0.9 for the extreme compositions, respectively. Disequilibrium features in natural pumice and scoria include pristine minerals existing outside their stability fields, and compositional zoning of titanomagnetite in contact with ilmenite. Variable rates of chemical equilibration which would eliminate these features constrain the apparent thermal excursion and re-distribution of minerals to the time scale of days.     

Holocene variations in the Asian monsoon inferred from the geochemistry of lake sediments in central Tibet

We present a record of monsoon variations for the early and middle Holocene that is inferred from the geochemistry of sediment cores from Ahung Co, a lake in central Tibet. The resolution of this record is better than 50 yr and the age model is derived from radiocarbon ages of terrestrial charcoal, which eliminates errors associated with the lake hard-water effect. We made down-core geochemical measurements of % carbonate, % organic carbon, C/N and δ¹³C of bulk organic matter, δ¹³C and δ¹⁸O of carbonate, and % dolomite. Proxy calibration and modern water-balance reconstruction show that these are proxies for lake depth and the amount of monsoon precipitation. We find that lake level and monsoon precipitation have been decreasing at Ahung Co since the early Holocene (∼7500 cal yr B.P.). Superimposed on this trend are rapid declines in monsoon rainfall at 7000-7500 and 4700 cal yr B.P. and seven century-scale wet-dry oscillations. The cores do not contain sediment from the last ∼4000 yr. Surface sediments from the lake accumulated during the 20th century, however. From this, we argue that lake levels have risen again recently following a late Holocene dry period.     

Transport and thermodynamics constrain belowground carbon turnover in a northern peatland

Rates of anaerobic respiration are of central importance for the long-term burial of carbon (C) in peatlands, which are a relevant sink in the global C cycle. To identify constraints on anaerobic peat decomposition, we determined detailed concentration depth profiles of decomposition end-products, i.e. methane (CH₄) and dissolved inorganic carbon (DIC), along with concentrations of relevant decomposition intermediates at an ombrotrophic Canadian peat bog. The magnitude of in situ net production rates of DIC and CH₄ was estimated by inverse pore-water modeling. Vertical transport in the peat was slow and dominated by diffusion leading to the buildup of DIC and CH₄ with depth (5500 μmol L⁻¹ DIC, 500 μmol L⁻¹ CH₄). Highest DIC and CH₄ production rates occurred close to the water table (decomposition constant k_d ∼ 10⁻³-10⁻⁴ a⁻¹) or in some distinct zones at depth (k_d ∼ 10⁻⁴ a⁻¹). Deeper into the peat, decomposition proceeded very slowly at about k_d = 10⁻⁷ a⁻¹. This pattern could be related to thermodynamic and transport constraints. The accumulation of metabolic end-products diminished in situ energy yields of acetoclastic methanogenesis to the threshold for microbially mediated processes (−20 to −25 kJ mol⁻¹ CH₄). The methanogenic precursor acetate also accumulated (150 μmol L⁻¹). In line with these findings, CH₄ was formed by hydrogenotrophic methanogenesis at Gibbs free energies of −35 to −40 kJ mol⁻¹ CH₄. This was indicated by an isotopic fractionation α_CO2-CH4 of 1.069-1.079. Fermentative degradation of acetate, propionate and butyrate attained Gibbs free energies close to 0 kJ mol⁻¹ substrate. Although methanogenesis was apparently limited by some other factor in some peat layers, transport and thermodynamic constraints likely impeded respiratory processes in the deeper peat. Constraints on the removal of DIC and CH₄ may thus slow decomposition and contribute to the sustained burial of C in northern peatlands.