Cathodoluminescence as a tool to discriminate impact melt,shocked and unshocked volcanics: A case study of samples from the El'gygytgyn impact structure

El'gygytgyn (Chukotka, Arctic Russia) is a well‐preserved impact structure, mostly excavated in siliceous volcanic rocks. For this reason, the El'gygytgyn structure has been investigated in recent years and drilled in 2009 in the framework of an ICDP (International Continental Scientific Drilling Program) project. The target rocks mostly consist of rhyodacitic ignimbrites and tuffs, which make it difficult to distinguish impact melt clasts from fragments of unshocked target rock within the impact breccia. Several chemical and petrologic attempts, other than dating individual clasts, have been considered to distinguish impact melt from unshocked volcanic rock of the targets, but none has proven reliable. Here, we propose to use cathodoluminescence (imaging and spectrometry), whose intensity is inversely correlated with the degree of shock metamorphism experienced by the investigated lithology, to aid in such a distinction. Specifically, impact melt rocks display low cathodoluminescence intensity, whereas unshocked volcanic rocks from the area typically show high luminescence. This high luminescence decreases with the degree of shock experienced by the individual clasts in the impact breccia, down to almost undetectable when the groundmass is completely molten. This might apply only to El'gygytgyn, because the luminescence in volcanic rocks might be due to devitrification and recrystallization processes of the relatively old (Cretaceous) target rock with respect to the young impactites (3.58 Ma). The alteration that affects most samples from the drill core does not have a significant effect on the cathodoluminescence response. In conclusion, cathodoluminescence imaging and spectra, supported by Raman spectroscopy, potentially provide a useful tool for in situ characterization of siliceous impactites formed in volcanic target.     

Deep 610-MHz Giant Metrewave Radio Telescope observations of the Spitzer extragalactic First Look Survey field – I. Observations, data analysis and source catalogue

Observations of the Spitzer extragalactic First Look Survey field taken at 610 MHz with the Giant Metrewave Radio Telescope are presented. Seven individual pointings were observed, covering a total area of ∼4 deg² with a resolution of 5.8 × 4.7 arcsec², PA 60°. The rms noise at the centre of the pointings is between 27 and 30 μJy before correction for the Giant Metrewave Radio Telescope (GMRT) primary beam. The techniques used for data reduction and production of a mosaicked image of the region are described, and the final mosaic, along with a catalogue of 3944 sources detected above ∼5σ, are presented. The survey complements existing radio and infrared data available for this region.     

The role of burrowing beds and burrows of the SW Atlantic intertidal crab Chasmagnathus granulata in trapping organochlorine pesticides

The effect of crab beds and bioturbation activity of the SW Atlantic intertidal crab Chasmagnathus granulata on the organochlorine pesticide (OCP) concentrations in Bahía Blanca estuary, Argentina were studied. Total OCP concentration was significantly lower inside than outside the crab burrows. Nevertheless, the concentrations from outside the crab beds were lower than from outside crab burrows, which indicated that crab beds act as sinks of sediment-bound OCP due to the bioturbation activities of the crabs. The same distribution patterns were found in all sediments as well as in crabs, being cyclodienes>HCHs>DDTs, although large amounts of metabolites rather than the respective parental were found in the organism showing the capacity of C. granulata for metabolising parental compounds. These more water-soluble compounds are excreted by the faeces and finally removed by tidal flushing to the sea. Our results suggest that crabs when present play a role in the distribution of sediment-bound OCP and the crab beds are modifiers of the dynamic of organic pollutants in estuarine areas.     

Structures et cinématique liées á la mise en place des péridotites de Ronda (Cordilléres Bétiques,Espagne)

The interaction of the Mid-Atlantic Ridge with the North Atlantic Mantle Plume has produced a magmatic plateau centred about Iceland. The crust of this plateau is 30 km thick on average. This abnormal thickness implies that, unlike other slow-spreading ridges, addition of magmatic material to the crust is not balanced by crustal stretching. The thermal effect of the plume also reduces the strength of the lithosphere. Both mechanisms affect the rifting process in Iceland. A structural review, including new field observations, demonstrates that the structure of the Iceland plateau differs from that of other slow-spreading oceanic ridges. Lithospheric spreading is currently accommodated in a 200 km wide deformation strip, by the development of a system of half-grabens controlled by growth faults. Similar extinct structures, with various polarities, are preserved in the lava pile of the Iceland plateau. These structures are identified as lithospheric rollover anticlines that developed in hanging walls of listric faults. We introduce a new tectonic model of accretion, whereby the development of the magmatic plateau involved activation, growth and decay of a system of growth fault/rollover systems underlain by shallow magma chambers. Deactivation of a given extensional system, after a lifetime of a few My, was at the expense of the activation of a new, laterally offset, one. Correspondingly, such systems formed successively at different places within a 200 km wide diffuse plate boundary. Unlike previous ones, this new model explains the lack of an axial valley in Iceland, the dip pattern of the lava pile, the complex geographical distribution of ages of extinct volcanic systems and the outcrops of extinct magma chambers.     

Geochemical characteristics of basalts related to incipient oceanization: The example from the Alpine‐Tethys OCTs

Basalts exposed in the Platta and Tasna nappes (SE Switzerland) derive from the Alpine‐Tethys ocean–continent transitions (OCT) and overlie subcontinental lithospheric mantle (SCLM). We show that the trace element signatures of these basalts differ from mid‐ocean ridge basalts (MORB). Two types of basalts occur in the OCT: a type‐1 showing a ‘garnet signature’ that can be modelled by the partial melting of the SCLM in the spinel stability field and a type‐2 characterized by an enrichment in incompatible elements that can be explained by the mixing between garnet‐pyroxenite‐derived melts and the melting of either a depleted MORB mantle or a refertilized SCLM. Based on the geological and geochemical observations, we propose that the basalts from the Alpine‐Tethys OCTs result from a poly‐phase magmatic system that carries an inherited SCLM signature. These basalts should therefore be referred to as OCT‐basalts rather than as MOR‐basalts.     

Forests and water in South America

South America is experiencing rapid change in forest cover, of both native and planted forest. Forest cover loss is primarily attributable to fire, logging, and conversion of native forest to agriculture, pasture, and forest plantations, and types of change vary within and among the many diverse types of forests in South America. Major changes in forest cover and growing policy concerns underscore an urgent need for research on sustainable forest management and water ecosystem services in South America. Differences in land ownership and management objectives create trade‐offs between wood production and water ecosystem services from forests. Work is needed to quantify how forest change and management affect ecosystem services, such as wood production versus water provision. Current scientific understanding of forest management effects on water ecosystem services in South America has important limitations, including a scarcity of long‐term records and few long‐term integrated watershed studies. Industry, government, universities, and local communities should collaborate on integrated applied studies of forests and water. Data archiving and publically available data are required. The creation of national networks and a multi‐country South America network to identify and implement common water research protocols, share results, and explore their implications would promote common and well‐supported policies. Hydrologists working in South America are well placed to tackle the challenges and opportunities for collaborative research that will maintain the intrinsic values and water ecosystem services provided by South America's forests.     

Diverse patterns of ascent,degassing, and eruption of rhyolite magma during the 1.8 ka Taupo eruption,New Zealand: Evidence from clast vesicularity

The 22 km³ (DRE) 1.8 ka Taupo eruption ejected chemically uniform rhyolite in a wide range of eruptive styles and intensities. The 7 eruptive units include the ‘type examples’ of phreatoplinian (units 3 and 4) and ultraplinian fall (unit 5) deposits, and low-aspect-ratio ignimbrite (unit 6). Contrasts in bulk vesicularity, vesicle (and microlite) number densities and the size distributions of bubbles (and crystals) in the Taupo ejecta can be linked to the influence of shallow conduit processes on volatile exsolution and gas escape, before and during eruption, rather than changes in pre-eruptive chemistry. Existing work has modeled the individual phases of this complex eruption but not fully explained the abrupt shifts in style/intensity that occur between phases. We link these rapid transitions to changes in vent position, which permitted contrasts in storage, conduit geometry, and magma ascent history.     

Application of a textural geospeedometer to the late‐stage magmatic history of MIL 03346

Abstract— Dynamic crystallization experiments performed on Fe‐rich, Al‐poor basalt are employed as a textural calibration set to quantify the late‐stage igneous history of nakhlite Miller Range (MIL) 03346. The ratio of crystal‐melt surface area to volume typifying morphologically distinct populations of Ca‐pyroxene has been shown to vary as a strong function of cooling rate (Hammer 2006). Furthermore, a texture of phenocrysts surrounded by finer‐grained groundmass crystals arises by sequential nucleation events during constant‐rate cooling, but multiple populations nucleate only if the cooling rate is 72 °C h^?1. Textural analysis of meteorite MIL 03346 reveals at least two distinct populations. The Ca‐pyroxene phenocryst and microphenocryst three dimensional (3D) aspect ratios are 112 ± 8.3 and 1530 ± 160 mm^?1, respectively. By comparison with the calibration set, the range of cooling rates consistent with 3D aspect ratios of both populations in MIL 03346 is ?20 °C h^?1An additional experiment was performed approximating a conductive heat transfer profile in order to interpret and apply results of constant‐rate cooling experiments to the natural cooling of magma. Results suggest that the textures of constant‐rate experiments parallel the initial period of rapid cooling in natural magma. Initial cooling rates of ?20 °C h^?1in the lava hosting MIL 03346 occur in conductively solidifying lava at depths of?0.4 m, constraining the minimum total thickness to 0.8 m. Crystal accumulation beginning in a subsurface reservoir and continuing after lava emplacement as an inflated pahoehoe sheet satisfies all textural constraints on the late‐stage igneous history of MIL 03346.