Wetland place names as indicators of manifestations of recent climate change in SW Spain (Doñana Natural Park)

Recent studies have shown the value of place names as environmental indicators. Until now they have not been applied to the effects of climate change, because verifying such relationship by this approach requires a multidisciplinary analysis and a study area where the anthropic impact has been recent. This study aims to test the possibility in a study area little altered by man until the second half of the twentieth century (Doñana Natural Park, SW Spain), and with a heritage very rich in wetlands. The results show that the desiccation of these wetlands is reflected in the local toponymy, and that in turn this regression is related with the end of the Little Ice Age and with the beginning of warming in southern Europe during the twentieth century. The coincidence of these results with data published for Arctic latitudes reveals—in our opinion—the possibility that certain place names can be used as indicators of recent climate changes, at least in some ecosystems.     

Occurrence of low-Ca clinopyroxene and the role of deformation in the formation of pyroxene-Fe−Ti oxide symplectites

Pyroxene-Fe−Ti oxide symplectites in a norite from the leuconoritic phase of the Bjerkreim-Sokndal lopolith, SW Norway, have been studied using EMPA (electron microprobe analysis) and TEM (transmission electron microscopy) techniques. Textural and mineralchemical data indicate that the symplectites formed under subsolidus conditions at T=720–736°C and f_{o 2}=10^-17 bars. Solidus temperatures are estimated as 981–1060° C. Two models of formation are proposed: non-isochemical replacement of olivine, and growth at boundaries between exsolving grains of orthomagmatic high-Ca pyroxene and Fe−Ti oxide. TEM reveals the presence of low-Ca clinopyroxene and this formed in response to strain and/or shear stress. Comparison with published experimental data indicates that strain rates of up to 10^-12 s^-1 are necessary to explain the occurrence of low-Ca clinopyroxene. The transition from orthopyroxene to low-Ca clinopyroxene may be related to deformation which accompanied intrusion of the leuconoritic phase of the Bjerkreim-Sokndal lopolith or to local post-intrusive faulting and/or shearing. Selected-area diffraction shows that the Fe−Ti oxide lamellae are oriented with respect to the pyroxene such that (111)_oxide/(100)_pyroxene. the planes of closest oxygen packing in the constituent phases are thus adjacent to one another which leads to minimal misfit between the structures and to low interfacial strain energy. The same topotactic relationship exists in both lamellar and vermicular parts of symplectites (but is not continuous along the total length of the interface), indicating that the form of the intergrowths is a primary growth feature that to some extent can be explained in terms of growth models for duplex cells. Deformation during growth is probably necessary to account for the lattice distortion observed in the symplectites. Supercooling is necessary for nucleation and growth of the symplectites. A period of cooling under static, fluid-absent conditions allows substantial overstepping of equilibrium reaction boundaries. Nucleation and growth is triggered by local deformation accompanied by influx of fluid or, possibly, melt. Under these conditions growth can be rapid (≈1 year), and low-Ca clinopyroxene forms during or after growth. The proportions of pyroxene and Fe−Ti oxide in symplectites from a variety of rocks fall in a narrow range (70.5:29.5–74.8:25.3) which suggests a common growth mechanism. The interlamellar spacing is related to the amount of supercooling prior to growth, but the effects of fluid on growth rate must be studied before this relationship can be quqntified. Symplectites provide evidence for the development of retrograde mineral assemblages in relatively short time intervals under transitory fluid-present conditions. The models for symplectite formation in the intrusives of southwestern Norway may be applicable to pyroxene-Fe−Ti oxide intergrowths in other slowly cooled basic igneous rocks.     

Slant Column Measurements of O3 and NO2 During the NDSC Intercomparison of Zenith-Sky UV-Visible Spectrometers in June 1996

In June 1996, 16 UV-visible sensors from 11 institutes measured spectra of the zenith sky for more than 10 days. Spectra were analysed in real-time to determine slant column amounts of O3 and NO2. Spectra of Hg lamps and lasers were measured, and the amount of NO2 in a cell was determined by each spectrometer. Some spectra were re-analysed after obvious errors were found. Slant columns were compared in two ways: by examining regression analyses against comparison instruments over the whole range of solar zenith angles; and by taking fractional differences from a comparison instrument at solar zenith angles between 85° and 91°. Regression identified which pairs of instruments were most consistent, and so which could be used as universal comparison instruments. For O3, regression slopes for the whole campaign agreed within 5% for most instruments despite the use of different cross-sections and wavelength intervals, whereas similar agreement was only achieved for NO2 when the same cross-sections and wavelength intervals were used and only one half-day's data was analysed. Mean fractional differences in NO2 from a comparison instrument fall within ±7% (1-sigma) for most instruments, with standard deviations of the mean differences averaging 4.5%. Mean differences in O3 fall within ±2.5% (1- sigma) for most instruments, with standard deviations of the mean differences averaging 2%. Measurements of NO2 in the cell had similar agreement to measurements of NO2 in the atmosphere, but for some instruments measurements with cell and atmosphere relative to a comparison instrument disagreed by more than the error bars.     

Ice cover variability in the Caspian and Aral seas from active and passive microwave satellite data

The paper discusses time and space variations of ice extent in the Caspian and Aral seas during the last decade (1992-2002). It uses synergy of data from active (radar altimeter) and passive (radiometer) microwave nadir-looking instruments onboard the TOPEX/Poseidon satellite. The proposed approach is substantiated and validated using both in situ and satellite imagery data for the Caspian Sea. The results indicate significant spatial and temporal variability of ice conditions, with a significant decrease of both the duration of ice season and ice extent during the last four winters (1998-2002). The TOPEX/Poseidon-derived time series of sea ice extent are very valuable in view of the fragmentary and mostly unpublished data on ice conditions on the Caspian and Aral seas since the mid-1980s.     

The appraisal of surface orbital vibrators with buried geophone array for permanent reservoir monitoring

Time-lapse seismic is one of the main methods for monitoring changes in reservoir conditions caused by production or injection of fluids. One approach to time-lapse seismic is through permanent reservoir monitoring, whereby seismic sources and/or receivers are permanently deployed. Permanent reservoir monitoring can offer a more cost-effective and environmentally friendly solution than traditional campaign-based surveys that rely on temporarily deployed equipment while facilitating more frequent measurements. At the CO2CRC Otway Project, surface orbital vibrators were coupled to a buried geophone array to form a permanent reservoir monitoring system. These are fixed position seismic sources that provide both P and S waves using induction motor-driven eccentric masses. After an initial injection of CO₂ in February 2016, five months of continuous seismic data were acquired, and reflection imaging was used to assess the system performance. Analysis of the data showed the effects of weather variations on the near-surface conditions and the sweep signatures of surface orbital vibrators. Data processing flows of the continuous data was adapted from Vibroseis four-dimensional data processing flows. Ground roll proved a significant challenge to data processing. In addition, variations in the surface wave pattern were linked to major rainfall events. For the appraisal of surface orbital vibrators in imaging, a Vibroseis four-dimensional monitor survey data with similar geometry was also processed. Surface orbital vibrators are observed to be reliable sources with a potential to provide a repeatable signal, especially if the ground roll should fall outside the target window of interest. To guide future permanent reservoir monitoring applications, a repeatability analysis was performed for the various key data processing steps.     

The magnetic field in the solar atmosphere

This publication provides an overview of magnetic fields in the solar atmosphere with the focus lying on the corona. The solar magnetic field couples the solar interior with the visible surface of the Sun and with its atmosphere. It is also responsible for all solar activity in its numerous manifestations. Thus, dynamic phenomena such as coronal mass ejections and flares are magnetically driven. In addition, the field also plays a crucial role in heating the solar chromosphere and corona as well as in accelerating the solar wind. Our main emphasis is the magnetic field in the upper solar atmosphere so that photospheric and chromospheric magnetic structures are mainly discussed where relevant for higher solar layers. Also, the discussion of the solar atmosphere and activity is limited to those topics of direct relevance to the magnetic field. After giving a brief overview about the solar magnetic field in general and its global structure, we discuss in more detail the magnetic field in active regions, the quiet Sun and coronal holes.     

Igneous cooling history of olivine‐phyric shergottite Yamato 980459 constrained by dynamic crystallization experiments

Dynamic crystallization experiments were performed on a liquid having the bulk composition of olivine‐phyric shergottite Yamato 980459, to constrain the igneous thermal history of this meteorite. Key characteristics of the meteorite's mineralogy and texture, including several morphologically distinct olivine and pyroxene crystal populations and a glassy mesostasis devoid of plagioclase, were replicated upon cooling from 1435 to 909 °C at 1 atmosphere under reducing conditions. Three sequential cooling ramps are required to produce synthetic samples with textures and compositions matching Yamato 980459. Olivine phenocrysts formed at <1 °C h^?1, presumably at depth in the Martian crust. Pyroxene phenocrysts formed mainly at ~10 °C h^?1, consistent with crystallization within a lava flow at depths of 25–45 cm. Increased cooling rate (~100 °C h^?1) in a third stage suppressed the formation of plagioclase and produced groundmass crystals, consistent with crystallization at lava flow depths of 5–7 cm. Although Y 980459 is unique among Martian meteorites (i.e., preserving a primary glassy mesostasis), its emplacement did not require unique physical conditions. Rather, the second and third cooling stages may reflect cooling within the core of a pāhoehoe‐like flow and subsequent breakout on the surface of Mars.     

Arsenic in sediments, groundwater, and streamwater of a glauconitic Coastal Plain terrain, New Jersey, USA—Chemical “fingerprints” for geogenic and anthropogenic sources

Glauconite-bearing deposits are found worldwide, but As levels have been determined for relatively few. The As content of glauconites in sediments of the Inner Coastal Plain of New Jersey can exceed 100 mg/kg, and total As concentrations (up to 5.95 μg/L) found historically and recently in streamwaters exceed the State standard. In a major watershed of the Inner Coastal Plain, chemical “fingerprints” were developed for streambed sediments and groundwater to identify contributions of As to the watershed from geologic and anthropogenic sources. The fingerprint for streambed sediments, which included Be, Cr, Fe and V, indicated that As was predominantly of geologic origin. High concentrations of dissolved organic C, nutrients (and Cl⁻) in shallow groundwater indicated anthropogenic inputs that provided an environment where microbial activity released As from minerals to groundwater discharging to the stream. Particulates in streamwater during high flow constituted most of the As load; the chemical patterns for these particulates resembled the geologic fingerprint of the streambed sediments. The As/Cr ratio of these suspended particles likely indicates they derived not only from runoff, but from groundwater inputs, because As contributed by groundwater is sequestered on streambed sediments. Agricultural inputs of As were not clearly identified, although chemical characteristics of some sediments indicated vehicle-related inputs of metals. Sediment sampling during dry and wet years showed that, under differing hydrologic conditions, local anthropogenic fingerprints could be obscured but the geologic fingerprint, indicating glauconitic sediments as an As source, was robust.     

Holocene landscape reconstruction in the surroundings of the Temple of Pepi I at ancient Bubastis,southeastern Nile Delta (Egypt)

In ancient Egypt, lakes, canals, and other water bodies were an essential part of the sacred landscape in which temples were embedded. In recent years, geoarchaeological research at the site of the Temple of Bastet at Bubastis in the southeastern Nile Delta has proven the existence of two water canals surrounding the temple. It has now been investigated whether these canals were connected to the Temple of Pepi I (2300–2250 B.C.E.), located approximately 100 m to the west of the Temple of Bastet. To explore the Holocene landscape genesis of the Temple of Pepi I, 15 drillings and six geoelectrical profile lines were performed in the surroundings of the temple in spring 2022. The results show loamy to clayey sediments in deeper sections of all drillings with a maximum thickness of 1.70 m, indicating a marshy or swampy depositional environment. Based on the recovered sediment sequences and archaeological remains in the vicinity of the Temple of Pepi I, the marshy or swampy area existed before the Fourth Dynasty. During the Old Kingdom (ca. 2850–2180 B.C.E.), the former marshland either dried up through natural processes or was intentionally drained and filled with sediments for subsequent use for occupation. Regarding the original research question, there is as yet no evidence for a direct connection to the canals of the Temple of Bastet.