Binding of thorium(IV) to carboxylate, phosphate and sulfate functional groups from marine exopolymeric substances (EPS)

Th(IV) isotopes are important proxies in oceanographic investigations, and are used as tracers of particle dynamics and particulate organic matter (POC) fluxes out of the euphotic zone through the use of ²³⁴Th/POC ratios. These approaches rely on empirically determined and variable POC to ²³⁴Th ratios, which might be controlled, in parts, by the abundance of exopolymeric substances (EPS). EPS contain acidic polysaccharides (APS) and are excreted by both phytoplankton and bacteria. To this end, radiotracer experiments with EPS from microbial cultures were conducted to determine the binding environment of ²³⁴Th(IV)-binding ligands in colloids and suspended particles in marine systems. In these experiments, the ²³⁴Th distribution during isoelectric focusing (IEF) and polyacrylamide gel electrophoresis (PAGE) was related to the functional group composition of EPS and of colloidal organic matter (COM) isolated from the Gulf of Mexico (GOM) using cross-flow ultrafiltration. EPS was extracted from phytoplankton (Emiliania huxleyi and Synechococcus elongatus) and bacteria (Sagittula stellata and Roseobacter gallaeciensis) cultures by repeated alcohol precipitation. Phosphate and sulfate concentrations were determined using ion chromatography (IC). IEF profiles indicated that 49% to 65% of the ²³⁴Th-labeled EPS from plankton and bacteria as well as COM samples from the GOM was found concentrated below pH of 4, near an isoelectric point, pH_IEP, of about 2. The carboxylic acid maxima for extracted EPS and COM samples appeared close to the pH_IEF of ²³⁴Th(IV). The phosphate maximum appeared at the same pH_IEF as ²³⁴Th(IV) for EPS from R. gallaeciensis and S. elongatus. The sulfate maximum was found at the same pH_IEF as ²³⁴Th(IV) for EPS from S. elongatus and COM. The molecular weight (MW) of the strongly Th(IV)-binding ligand varied from 1 to 14 kDa, depending on the species, but was about 10 kDa in COM. Thus, depending on the species of plankton or bacteria, the MW and specific functional group composition of the strongly ²³⁴Th(IV)-binding amphiphilic biomolecule can vary. Therefore, different acidic functional groups can, at times, contribute to the binding of Th(IV) to the EPS chelating ligand, which can also have different MWs. This implies that the binding environment for Th(IV), which is present at total concentrations at least a million times lower than the acid functional groups, consists of strong polydentate chelate complexes in clustered structures of carboxylate, sulfates and/or phosphates. The combination of strongly chelating groups and amphiphilicity gives this biomolecule the unique properties of a “sticky” ligand.     

Primary production in the Kuroshio current surrounding Taiwan

Primary production in the Kuroshio current flowing around Taiwan Island was measured by using the radiocarbon method. High values of the daily primary production were found in both the aquacultural area at the western coast and the polluted area with raw rubbish heaps at the Keelung-Patoutzu coast. In the upwelling region of southeastern coast, low values of the primary production were observed. In the eastern coast, the rate of photosynthesis for an unit amount of chlorophylla under the saturated light was in the range of 1.2±0.2 mg C/mg chlorophylla/hr. Some discussions are made on the observed results.     

Shear wave velocity measurements and soil–pile system identifications in dynamic centrifuge tests

This paper presents a pre-shaking technique for measuring the $V_{s}$ profile of sand deposits and determining the natural frequencies of the sand bed and soil-structure system in a centrifuge model at an acceleration of 80 g. The pre-shaking technique is a non-destructive test. It uses a shaker as a wave generation source and a vertical array of accelerometers embedded in the sand bed and the accelerometers attached to the pile head as receivers. The pre-shaking method can be easily used for in-flight subsurface exploration ( $V_{s}$ profile measurements) and in-flight system identification of soil-structure systems (natural frequency measurements). A soil–pile centrifuge model is used to demonstrate the versatility of pre-shaking during a routine centrifuge shaking table test. This paper discusses the testing setup, testing procedures, related SI techniques, and signal processing for the soil–pile system. The natural frequencies measured by the pre-shaking tests are consistent with theory-based results. This technique can be conducted at any time before and after major earthquake events occur in a test.     

东南亚断裂构造的演化

本研究项目是采用诸如地质学解释、影像判读和地球物理探测等多种方法相结合进行的。在所得结果的基础上参考了越南国内外同行的一些资料编制了东南亚、越南及邻区的断裂构造图．其比例尺分别为1：4百万和1：1百万。分析所得结果显示出东南亚断裂构造演化的下列情况：1)在现今地质结构方面东南亚是欧亚岩石圈板块的东南部分．由一条消减带围绕．这条消减带的伸展从Myanmer开始,通过Nicobar,Java Timor直到东菲律宾。东南亚被Song Hong(即红河)断裂,Three Pagodas断裂和Hainam-Natuna断裂等2级断裂系统分成3个微板块。2)在早新生代．东南亚是分为5个微板块的。它们的分界断裂中有2个一级断裂(中央东海扩张带和Lupar-Kuching消减带)和3个二级断裂(即上述3个)。3)上述绝大多数二和三级断裂从晚新生代起活化且继承了从早新生代即已发生和发展了的二、三级断裂,但在某些条件下．运动方向却完全变成了相反,尤其是走滑运动的方向。我们的研究结果表明：在这一地区内,盆地、隆起、岩浆侵入、褶皱和局部断裂等构造的形成都取决于这些沿着一、二级走滑断裂的微板块运动。     

Features of the Distribution of Abnormal Gasgeochemical Fields in the Red River Rift (Gulf of Tonkin,South China Sea)

Doklady Earth Sciences - This paper reports the results of the third Russian–Vietnamese expedition (V.I. Il'ichev Pacific Oceanological Institute, Far East Branch, Russian Academy of...     

Seismic design and testing of the bottom vertical boundary elements in steel plate shear walls. Part 2: experimental studies

This paper describes an experiment to investigate the seismic design and responses of the bottom column, also called the bottom vertical boundary element (VBE), in steel plate shear walls (SPSWs). The main objectives of this experiment include validating the effectiveness of the design method developed in the companion paper, investigating the experimental performance of VBEs under large interstory drifts, and calibrating analytical models for earthquake engineering of SPSWs. Three full‐scale two‐story SPSWs were cyclically tested at the Taiwan National Center for Research on Earthquake Engineering in 2011. Test results and numerical simulations confirm that the proposed design procedures are effective in predicting the plastic zone forming elevation in the lower half of the bottom VBE and the occurrence of yielding at the VBE's top end. Test results show that the premature yielding occurring at the top end of a bottom VBE would result in a deformation concentration at the bottom of SPSWs. In addition, lateral torsional buckling could take place on the bottom VBE after significant plastic rotations have developed at the top end. Test results suggest that preventing the VBE's top end from yielding is the key issue in the seismic design of SPSWs, and the proposed method can be effectively adopted to achieve this objective. Furthermore, the inelastic responses of the SPSW specimens were satisfactorily simulated by using detailed finite shell elements or simplified frame response analysis models. Copyright © 2014 John Wiley & Sons, Ltd.     

Comparison of metal accumulation in the azooxanthellate scleractinian coral (Tubastraea coccinea) from different polluted environments

The response of metal accumulation in coral Tubastraea coccinea to various degrees of metal enrichment was investigated from the Yin-Yang Sea (YYS) receiving abandoned mining effluents, the Kueishan Islet (KI) hydrothermal vent field, and the nearshore area of remoted Green Island (GI). The concentrations of most dissolved metals were highest in seawater at YYS, followed by KI, and then GI, showing the effects of anthropogenic and venting inputs on metal levels. Five metals (Co, Fe, Mn, Ni, and Zn) yielded significant differences (p < 0.05) among the skeleton samples. We identified similar patterns in the metal–Ca ratios, indicating that the elevated metals in skeletons was a consequence of external inputs. The coral tissues were relatively sensitive in monitoring metal accumulation, showing significant differences among three locations for Cd, Co, Cu, Fe, Pb, Ni, and Zn. Specific bioconcentration factors provided strong support for the differential metal accumulation in skeletons and tissues.     

Sedimentation in the floodplains of the Mekong Delta,Vietnam. Part I: suspended sediment dynamics

Suspended sediment is the primary source for a sustainable agro‐ecosystem in the Mekong Delta by providing nutrient input for the subsequent cropping season. In addition, the suspended sediment concentration (SSC) plays an important role in the erosion and deposition processes in the Delta; that is, it influences the morphologic development and may counteract the deltaic subsidence and sea level rise. Despite this importance, little is known about the dynamics of suspended sediment in the floodplains of the Mekong Delta. In particular, quantitative analyses are lacking mainly because of data scarcity with respect to the inundation processes in the floodplains. In 2008, therefore, a comprehensive in situ system to monitor the dynamics of suspended sediment in a study area located in the Plain of Reeds was established, aiming at the characterization and quantification of suspended sediment dynamics in the deeply inundated parts of the Vietnamese part of the Mekong Delta. The monitoring system was equipped with seven water quality–monitoring stations. They have a robust design and autonomous power supply suitable for operation on inundated floodplains, enabling the collection of reliable data over a long period of time with a high temporal resolution. The data analysis shows that the general seasonal dynamics of suspended sediment transport in the Delta is controlled by two main mechanisms: the flood wave of the Mekong River and the tidal backwater influences from the coast. In the channel network, SSC decreases exponentially with distance from the Mekong River. The anthropogenic influence on SSC could also be identified for two periods: at the start of the floodplain inundation and at the end of the flood period, when subsequent paddy rice crops are prepared. Based on the results, we recommend an operation scheme for the sluice gates, which intends to distribute the sediment and thus the nutrients equally over the floodplain. Copyright © 2013 John Wiley & Sons, Ltd.     

Flood simulation using the gauge‐adjusted radar rainfall and physics‐based distributed hydrologic model

This paper reports the results of an investigation into flood simulation by areal rainfall estimated from the combination of gauged and radar rainfalls and a rainfall–runoff model on the Anseong‐cheon basin in the southern part of Korea. The spatial and temporal characteristics and behaviour of rainfall are analysed using various approaches combining radar and rain gauges: (1) using kriging of the rain gauge alone; (2) using radar data alone; (3) using mean field bias (MFB) of both radar and rain gauges; and (4) using conditional merging technique (CM) of both radar and rain gauges. To evaluate these methods, statistics and hyetograph for rain gauges and radar rainfalls were compared using hourly radar rainfall data from the Imjin‐river, Gangwha, rainfall radar site, Korea. Then, in order to evaluate the performance of flood estimates using different rainfall estimation methods, rainfall–runoff simulation was conducted using the physics‐based distributed hydrologic model, Vflo^?. The flood runoff hydrograph was used to compare the calculated hydrographs with the observed one. Results show that the rainfall field estimated by CM methods improved flood estimates, because it optimally combines rainfall fields representing actual spatial and temporal characteristics of rainfall. Copyright © 2008 John Wiley & Sons, Ltd.