Evidence for Co-Propagation of 4765- and 1720-MHz OH Masers in Star-Forming Regions

Two star-forming regions Cepheus A and W75N, were searched for the 4765-MHz OH maser emission using the multi-element radio linked interferometer network (MERLIN). The excited OH emission has an arc-like structure of 40 mas in Cep A and a linear structure of size 45 mas in W75N. We also found the 1720-MHz line in Cep A and Hutawarakorn [MNRAS 330 (2002) 349] reported the 1720-MHz emission in W75N. The 1720- and 4765-MHz OH spots coincided in space within 60 mas and in velocity within 0.3 km s^–1 in both targets implying that both maser transitions arise from the same region. According to the modelling by Gray [MNRAS 252 (1991) 30] the 1720/4765-MHz co-propagation requires a low density, warm environment. The masers lie at the edges of H II regions where such conditions are expected.     

A MERLIN survey of 4.7-GHz excited OH masers in star-forming regions

Phase-referenced observations of 13 star-forming regions in the  ²Π_1/2, J = 1/2  transition of rotationally excited OH at 4765 MHz have been carried out using MERLIN. Two of the regions were also observed at 4750 MHz and one at 4660 MHz. There were 10 maser detections at 4765 MHz and three non-detections. There were no detections at 4750 and 4660 MHz. The 4765-MHz masers have brightness temperatures of  ∼10⁷ K  at MERLIN resolution (∼50 mas). Several cases of 4765-MHz masers overlapping in position and velocity with 1720- and 1665-MHz masers are reported. There are also isolated 4765-MHz masers with peak flux densities ≥30 times that of any ground-state counterpart. Most of the 4.7-GHz maser spots are unresolved at 50-mas angular resolution, but in four of the nearest sources the maser spots are resolved, indicating a characteristic size for 4765-MHz maser regions of ∼100 au. In W3(OH) we discovered that 20 per cent of the 4765-MHz emission comes from a narrow low-brightness filament that stretches north–south for ∼1.0 arcec (∼2200 au) between two previously known 4765-MHz maser spots. The filament appears in projection against the H  ii region and has a brightness temperature of  ∼4 × 10⁵ K  . There are matching absorption features in mainline transitions of highly excited OH. The filament may trace a shock front in a rotating disc.     

Kinetic isotope effect during reduction of iron from a silicate melt

Iron isotopic compositions measured in chondrules from various chondrites vary between δ⁵⁷Fe/⁵⁴Fe = +0.9‰ and −2.0‰, a larger range than for igneous rocks. Whether these compositions were inherited from chondrule precursors, resulted from the chondrule-forming process itself or were produced by later parent body alteration is as yet unclear. Since iron metal is a common phase in some chondrules, it is important to explore a possible link between the metal formation process and the observed iron isotope mass fractionation. In this experimental study we have heated a fayalite-rich composition under reducing conditions for heating times ranging from 2 min to 6 h. We performed chemical and iron isotope analyses of the product phases, iron metal and silicate glass. We demonstrated a lack of evaporation of Fe from the silicate melt in similar isothermal experiments performed under non-reducing conditions. Therefore, the measured isotopic mass fractionation in the glass, ranging between −0.32‰ and +3.0‰, is attributed to the reduction process. It is explained by the faster transport of lighter iron isotopes to the surface where reduction occurs, and is analogous to kinetic isotope fractionation observed in diffusion couples [Richter, F.M., Davis, A.M., Depaolo, D.J., Watson, E.B., 2003. Isotope fractionation by chemical diffusion between molten basalt and rhyolite. Geochim. Cosmochim. Acta67, 3905-3923]. The metal phase contains 90-99.8% of the Fe in the system and lacks significant isotopic mass fractionation, with values remaining similar to that of the starting material throughout. The maximum iron isotope mass fractionation in the glass was achieved within 1 h and was followed by an isotopic exchange and re-equilibration with the metal phase (incomplete at ∼6 h). This study demonstrates that reduction of silicates at high temperatures can trigger iron isotopic fractionation comparable in its bulk range to that observed in chondrules. Furthermore, if metal in Type I chondrules was formed by reduction of Fe silicate, our observed isotopic fractionations constrain chondrule formation times to approximately 60 min, consistent with previous work.     

Late Holocene flood magnitudes in the Lower Rhine river valley and upper delta resolved by a two-dimensional hydraulic modelling approach

Palaeoflood hydraulic modelling is essential for quantifying ‘millennial flood’ events not covered in the instrumental record. Palaeoflood modelling research has largely focused on one-dimensional analysis for geomorphologically stable fluvial settings because two-dimensional analysis for dynamic alluvial settings is time consuming and requires a detailed representation of the past landscape. In this study, we make the step to spatially continuous palaeoflood modelling for a large and dynamic lowland area. We applied advanced hydraulic model simulations (1D–2D coupled set-up in HEC-RAS with 950 channel sections and 108 × 10³ floodplain grid cells) to quantify the extent and magnitude of past floods in the Lower Rhine river valley and upper delta. As input, we used a high-resolution terrain reconstruction (palaeo-DEM) of the area in early mediaeval times, complemented with hydraulic roughness values. After conducting a series of model runs with increasing discharge magnitudes at the upstream boundary, we compared the simulated flood water levels with an inventory of exceeded and non-exceeded elevations extracted from various geological, archaeological and historical sources. This comparison demonstrated a Lower Rhine millennial flood magnitude of approximately 14,000 m³/s for the Late Holocene period before late mediaeval times. This value exceeds the largest measured discharges in the instrumental record, but not the design discharges currently accounted for in flood risk management.     

Late Holocene linkages between decade–century scale climate variability and productivity at Lake Tanganyika, Africa

Microlaminated sediment cores from the Kalya slope region of Lake Tanganyika provide a near-annually resolved paleoclimate record between ∼∼2,840 and 1,420 cal. yr B.P. demonstrating strong linkages between climate variability and lacustrine productivity. Laminae couplets comprise dark, terrigenous-dominated half couplets, interpreted as low density underflows deposited from riverine sources during the rainy season, alternating with light, planktonic diatomaceous ooze, with little terrigenous component, interpreted as windy/dry season deposits. Laminated portions of the studied cores consist of conspicuous dark and light colored bundles of laminae couplets. Light and dark bundles alternate at decadal time scales. Within dark bundles, both light and dark half couplets are significantly thinner than within light bundles, implying slower sediment accumulation rates during both seasons over those intervals.Time series analyses of laminae thickness patterns demonstrate significant periodicities at interannual–centennial time scales. Longer time scale periodicities (multidecadal to centennial scale) of light and dark half couplet thicknesses are coherent and in some cases are similar to solar cycle periods on these time scales. Although laminae thickness cycles do not strongly covary with the actual Δ¹⁴C record for this same time period, two large Δ¹⁴C anomalies are associated with substantial decreases in both light and dark laminae thickness. In contrast to the multidecadal– centennial time scale, significant annual to decadal periodicities, which are broadly consistent with ENSO/PDO forcing and their impact on East African climate, are not coherent between light and dark half couplets. The coherency of light–dark couplets at decadal–centennial time scales, but not at shorter time scales, is consistent with a model of a long-term relationship between precipitation (recorded in wet season dark laminae thickness) and productivity (light laminae thickness), which is not manifest at shorter time scales. We hypothesize that this coupling results from long-term recharging of internal nutrient loading during wet periods (higher erosion of soil P) and reduced loading during drought intervals. The relationship is not expressed on short time scales during which the dominant control on productivity is wind-driven, dry season upwelling, which is uncorrelated with wet-season precipitation. Our record greatly extends the temporal record of this quasi-periodic behavior throughout the late Holocene and provides the first evidence linking decade- to century-scale episodes of enhanced productivity to enhanced precipitation levels and nutrient recharge in a productive tropical lake.