A note on the thermal component of the equation of state in solids

A simple method for determining the thermal component of the EOS of solids under high pressure is proposed. Application to the interior of the Earth gives results in agreement with recent geophysical data.     

Properties of Knots in Cooling Stellar Jets

Modelling the formation of the maximal emission regions in Herbig-Haro flows, the so-called ‘knots,’ remains a main challenge in the investigation of the YSO's outflows. Recent HST images of optical regions reveal their wide morphological variety. Knotty structures and arc-like regions coexist, suggesting that several mechanisms could be responsible for the global scenario. Arc-like emissions are probably due to other mini-working surfaces or non-axially symmetric interaction of the kinking jet matter with the external medium, while knots seen in [SII] are mostly axially symmetric objects and may have a different origin. In this paper we show that a pattern of regularly spaced, knotty emission regions forms in stationary jets, with emissivity and kinematic features consistent with observations. To this purpose, numerical simulations of non-equilibrium, radiative, hydrodynamical jets in axial symmetric geometry have been performed.     

A model of neptune according to the Savić-Kašanin theory

A model of the internal structure of Neptune has been calculated according to the Savi?-Ka?anin theory of behaviour of materials under high pressure.     

High-pressure phase transitions — examples of classical predictability

We present 19 examples of materials whose high pressure phase transition points can be determined within a particular classical theory of dense matter. Theoretical predictions are compared with experimental results, and some possible causes of discrepancies are discussed.     

Evaluation of the Mytilus galloprovincialis Lam. digestive gland metallothionein as a biomarker in a long-term field study: seasonal and spatial variability

A study was made of seasonal and spatial variability of metallothionein (MT) concentrations, determined spectrophotometrically in the soluble fraction of the digestive gland of mussels Mytilus galloprovincialis, collected between 1999 and 2001 from several coastal and estuarine locations along the central Eastern Adriatic coast (Croatia). The seasonal influence on the MT and metal concentrations (higher values in winter-spring season, than in summer-autumn season) is more pronounced than the local site-specific influence. Furthermore, within each season a significant site-specific dependence on the MT and trace metal variations can be detected. An inverse relationship of mussel condition index (CI) and temperature with MT and trace metals levels indicates the influence of food abundance and mussel annual reproductive cycle. Substantially higher concentrations of both MT and Cd were recorded in mussels inhabiting estuarine locations, possibly indicating a markedly higher Cd bioavailability at these locations. The positive correlations obtained between MT and Cd in all seasons except autumn support an argument for application of digestive gland MT as a biomarker of Cd exposure, providing evidence for assessing the most appropriate season for mussel sampling.     

Identification of heterogeneous aquifer transmissivity using an AE-based method

Determination of hydraulic head, H, as a function of spatial coordinates and time, in ground water flow is the basis for aquifer management and for prediction of contaminant transport. Several computer codes are available for this purpose. Spatial distribution of the transmissivity, T(x,y), is a required input to these codes. In most aquifers, T varies in an erratic manner, and it can be characterized statistically in terms of a few moments: the expected value, the variance, and the variogram. Knowledge of these moments, combined with a few measurements, permits one to estimate T at any point using geostatistical methods. In a review of transmissivity data from 19 unconsolidated aquifers, Hoeksema and Kitanidis (1985) identified two types of the logtransmissivity Y= ln(T) variations: correlated variations with variance sigma2Yc and correlation scale, I(Y), on the order of kilometers, and uncorrelated variations with variance sigma2Yn. Direct identification of the logtransmissivity variogram, Gamma(Y), from measurements is difficult because T data are generally scarce. However, many head measurements are commonly available. The aim of the paper is to introduce a methodology to identify the transmissivity variogram parameters (sigma2Yc, I(Y), and sigma2Yn) using head data in formations characterized by large logtransmissivity variance. The identification methodology uses a combination of precise numerical simulations (carried out using analytic element method) and a theoretical model. The main objective is to demonstrate the application of the methodology to a regional ground water flow in Eagle Valley basin in west-central Nevada for which abundant transmissivity and head measurements are available.     

Characterization of atmospheric surfactants in the bulk precipitation by electrochemical tools

Characterization of atmospheric surfactants in bulk precipitations was carried out by adsorption study at the mercury electrode/solution interface using phase sensitive AC voltammetry. The structure and permeability of the adsorbed organic films at the mercury electrode was tested using the redox processes of lead and cadmium ions as electrochemical tools. The effects of organic matter from the bulk precipitations (rainwater and melted snow) were compared to those obtained for aqueous solutions of model substances: aromatic hydrocarbon (naphtalene), anionic surfactant (sodium dodecylbenzene sulfonate, NDBS), protein (albumine) and selected model substances suggested to be representative of water soluble organic compounds (WSOC) in atmospheric water (monocarboxylic, dicarboxylic, and polyacidic compounds and levoglucosan). It was found that substances like humic acid and 3-hydroxybutanoic acid may play an important role in atmospheric heterogeneous chemistry because of their surface active potential.