The origin of space group violations in a lunar orthopyroxene

The space group of an orthopyroxene (En₈₆) from a deep crustal lunar rock (sample 76535) that was previously reported as having space group P2₁ ca has been re-examined on an automated X-ray diffractometer. In addition to diffractions violating the b-glide of the conventional space group, Pbca (0kl,k-odd) reported in the earlier study, diffractions violating the a-glide of Pbca are also present. Careful examination of both the a-glide- and b-glide-violations shows them to be sharp, with no evidence of diffuse streaks parallel to a ^*, and with consistent intensities at several rotations about ψ. Diffractions violating the b-glide are in registry with the host, however, those violating the a-glide appear to be out of registry and result from a cell with a slightly longer a of about 18.4 Å, consistent with previous electron diffraction studies. The most reasonable explanation for the observed space group violations is that both the a- and b-glide violations result from ordering of Ca into (100) Guinier-Preston (G-P) zones that possess orthopyroxene topology, but have space group P2₁/c and a cell of a=18.4 Å, b=8.83 Å, c=5.18 Å, and β=90.0°; whereas the Cadepleted host has space group Pbca and a cell of a= 18.230(6) Å, b = 8.828(2) Å, and c=5.1946(9) Å. In addition to the G-P zones which may compose 12% or more of the sample, the crystal contains (100) lamellae of pigeonite, and other samples from the same rock contain lamellae of augite.     

Assessment of ERA5 and ERA-Interim in Reproducing Mean and Extreme Climates over West Africa

In situ data in West Africa are scarce, and reanalysis datasets could be an alternative source to alleviate the problem of data availability. Nevertheless, because of uncertainties in numerical prediction models and assimilation methods, among other things, existing reanalysis datasets can perform with various degrees of quality and accuracy. Therefore, a proper assessment of their shortcomings and strengths should be performed prior to their usage. In this study, we examine the performance of E...     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

Complexity theory, spatial simulation models, and land use dynamics in the Northern Ecuadorian Amazon

Our research questions and analytical approaches are used to examine coupled human-natural systems in the Northern Ecuadorian Amazon. They are based on complexity theory and extend from our earlier work in Cellular Automata (CA) in which land use/land cover (LULC) change patterns were spatially simulated to examine deforestation and agricultural extensification on household farms. The basic intent is to understand linkages between people and the environment by explicitly considering pattern-process relationships and the nature of feedback mechanisms among social, biophysical, and geographical factors that influence LULC dynamics within the study area. In this research, we describe how our CA modeling approach emphasizes the human dimensions of LULC change by including socio-economic and demographic characteristics at the household-level along with biophysical data that describe the resource endowments of farms, geographic accessibility of farms to roads and communities, and the evolving nature of human-environment interactions over time and space in response to exogenous and endogenous factors.A LULC change scenario is examined by comparing model outcomes generated for a base CA model and an alternative CA model to explore the effects of increases in household income on land use change patterns at the farm level, achieved as a consequence of improved geographic accessibility to roads and communities and increased off-farm employment as a household livelihood strategy. Growth or transitions rules in our CA model, as well as neighborhood associations are sensitive to socio-economic and demographic factors of households, resource endowments of farms, geographic accessibility, and the uncertainty associated with peasant farming in a frontier setting. Model outcomes indicate that increases in household income are associated with more land in pasture and more land being cultivated for crops as a result of greater access to agricultural markets. In addition, more land in secondary forest succession occurs as a consequence of greater access to roads and communities, thereby, affording a better opportunity for off-farm employment and greater levels of household income.     

The derivation of an Arctic sea ice normal through temporal mixture analysis of satellite imagery

The use of temporal mixture analysis (TMA) for creating a long-term baseline, or environmental “normal” is described. TMA is a promising analysis method derived from the hyperspectral image processing technique of spectral mixture analysis (SMA). TMA is algebraically identical to SMA, except that it is applied to temporal spectra rather than to electromagnetic spectra. TMA has particular potential to extract climate signals from long image sequences.     

SHRIMP U-Pb Zircon Dating of the Tula Granite Pluton on the South Side of the Altun Fault and Its Geological Implications

The Tula A2-subtype granite pluton is located between the Altun fault and its branching fault. According to the geological, geochemical, REE and trace elements characteristics, it belongs to the A2 （PA） subtype granite. The SHRIMP U-Pb zircon dating gives a result of 385.2±8.1 Ma, which is located between the Middle and Late Devonian in the international stratigraphic chart, and can be regarded as the crystallization age of the Tula granite. The study indicates that the Tula area was in a local extensional environment in the end of the Middle Devonian, and that environment was probably related to the synchronized strike-slip activity of the Altun fault.     

Recovery of Bennu’s orientation for the OSIRIS-REx mission: implications for the spin state accuracy and geolocation errors

The goal of the OSIRIS-REx mission is to return a sample of asteroid material from near-Earth asteroid (101955) Bennu. The role of the navigation and flight dynamics team is critical for the spacecraft to execute a precisely planned sampling maneuver over a specifically selected landing site. In particular, the orientation of Bennu needs to be recovered with good accuracy during orbital operations to contribute as small an error as possible to the landing error budget. Although Bennu is well characterized from Earth-based radar observations, its orientation dynamics are not sufficiently known to exclude the presence of a small wobble. To better understand this contingency and evaluate how well the orientation can be recovered in the presence of a large 1\(^{\circ }\) wobble, we conduct a comprehensive simulation with the NASA GSFC GEODYN orbit determination and geodetic parameter estimation software. We describe the dynamic orientation modeling implemented in GEODYN in support of OSIRIS-REx operations and show how both altimetry and imagery data can be used as either undifferenced (landmark, direct altimetry) or differenced (image crossover, altimetry crossover) measurements. We find that these two different types of data contribute differently to the recovery of instrument pointing or planetary orientation. When upweighted, the absolute measurements help reduce the geolocation errors, despite poorer astrometric (inertial) performance. We find that with no wobble present, all the geolocation requirements are met. While the presence of a large wobble is detrimental, the recovery is still reliable thanks to the combined use of altimetry and imagery data.     

Crescentic dune migration and stabilization: Implications for interpreting paleo-dune deposits as paleoenvironmental records

Paleo-dune deposits have been widely used as a proxy indicator of past dune activity, which is further used to reconstruct paleoclimates. However, recent studies have critically examined the reproducibility of dune chronologies and the complexity of paleo-dune deposits as paleoenvironmental records. This paper addresses questions on the paleoenvironmental implications of dune chronostratigraphies that have been raised by those reviews, in the specific case of crescentic dunes, using a case study from the Mu Us dune field, north-central China. The processes of turn-over and stabilization of relatively small crescentic dunes are first investigated by observational evidence. In combination with the analysis of a simplified sand preservation model and stratigraphic records, the effect of dune morphodynamics on sand preservation is demonstrated. It is especially evident that thick, nearly instantaneously deposited sand units record dune stabilization near the very end of a dune activity episode, while thin sand units may signal the preservation of sand deposited earlier in episodes of activity. Interpreting the distribution of luminescence ages that indicate sand deposition over time is not as simple as assumed in some previous work. Low frequency of sand ages could indicate an interval of either dune field stabilization or extensive dune activity but poor sand preservation. A peak of sand age frequency likely represents a shift in dune field activity towards stabilization, not a peak of active dune extent, especially if it partially overlaps with an independently identified interval of stabilization (e.g. one recorded by paleosols). The nature and magnitude of these biases in the distribution of sand ages over time are strongly affected by the magnitude of net sand accumulation, which is in turn related to sand supply, transport capacity and sand availability, and ultimately climate change. Relatively short dune stabilization and turn-over time (10¹ to 10² yrs) indicate that dune geomorphic processes can quickly respond to short-term disturbance, but the chronology of that response must be interpreted in light of how those processes influence age distributions.