Mapping of benthic enrichment patterns in Narragansett Bay,Rhode Island

A synoptic reconnaissance survey was performed over a five-day period in August 1988 to assess benthic habitat quality throughout Narragansett Bay, Rhode Island, using REMOTS^® sediment-profile photography and analysis in combination with measurements of the levels ofClostridium perfringens spores (a fecal indicator) in sediments. Three main areas of degraded benthic habitat quality related to either excessive organic enrichment or physical disturbance were identified based solely on the REMOTS^® analysis: the Providence River Reach, Greenwich Bay and its associated coves and harbors, and an area located along the southwest side of Prudence Island. Sediments at many stations in these areas exhibited shallow apparent redox-potential discontinuity (RPD) depths, high apparent oxygen demand, and low-order benthic successional stages. ElevatedClostridium perfringens spore counts in surface sediments were attributed to inputs from wastewater treatment facilities. The highest spore counts occurred at the head of the bay, where wastewater treatment discharges and associated combined sewer overflows are numerous. Using data from the REMOTS^® analysis and the sediment inventory ofC. perfringens spores, a distinction was made between organic enrichment of the bottom from sewage, versus nonsewage enrichment or physical disturbance. The combination of techniques employed in this investigation could be used to design more efficient monitoring programs to assess eutrophication effects in estuaries and determine the effectiveness of regulatory or management initiatives to reduce organic overenrichment of benthic habitats.     

Correlation between petrography,NAA, and ICP analyses: Application to early bronze Egyptian pottery from Canaan

Under favorable circumstances petrographic studies supported by chemical analysis using inductively coupled plasma (ICP) suffice to establish the provenience of pottery. A case in point is Egyptian-style pottery of Early Bronze Age found in Canaan. The pottery was divided into three groups according to four criteria determined by thin section analysis supplemented by X-ray diffraction: sorting and volume of silt-sized quartz, heavy minerals, the amount of carbonates in the matrix, and the firing temperature. Chemical analyses confirmed the classification. The source materials inferred for the three groups are Nile muds, Egyptian marly sediments, and local loess. Although the chemical analyses obtained by ICP and neutron activation analysis (NAA) were compatible, the existing database for NAA cannot be used indiscriminately. However, for provenience studies based on mineralogical and petrographic data, knowledge of the geology of the potential source areas can replace an extensive database.     

Modeling the natural degradation of earthworks

Stratigraphic, topographic, and ground‐penetrating radar data obtained from a ca. 1800‐year‐old embankment and adjacent ditch at the Hopewell Mound Group (Chillicothe, Ohio) are used to validate the archaeological application of a simple finite‐differences diffusion model employed frequently to assess geomorphic change in natural landscapes. Although diffusion models have been used to describe the topographic degradation of landforms in a variety of geomorphic terrains, the approach has not been applied to ancient earthworks in an archaeological context. The results of this study indicate that a variety of initial earthwork forms can result in the sinusoidal profile apparent on the current landscape. Using the model results to interpret the field data, we suggest that the initial embankment form was steeper and the adjacent ditch was deeper. As a result of natural degradation processes, the earthwork widened and flattened over time. These results have broad implications for any study aimed at: (1) assessing the function of original earthwork forms, (2) determining the formation processes of complicated stratigraphies or artifact assemblages, (3) estimating the time and labor investment required for construction, or (4) identifying the socio‐political structures necessary to build earthworks. © 2005 Wiley Periodicals, Inc.     

Geochemistry and petrogenesis of the Proterozoic dykes in Tamil nadu, southern India: another example of the Archaean lithospheric mantle source

Approximately 1650-Ma-old NW/SE and NE/SW-trending dolerite dykes in the Tiruvannamalai (TNM) area and approximately 1800-Ma-old NW/SE-trending dolerite dykes in the Dharmapuri (DP) area constitute major Proterozoic dyke swarms in the high-grade granulite region of Tamil nadu, southern India. The NW- and NE-trending TNM dykes are compositionally very similar and can be regarded as having been formed during a single magmatic episode. The DP dykes may relate to an earlier similar magmatic episode. The dolerites are Fe-rich tholeiites and most of the elemental variations can be explained in terms of fractional crystallisation. Clinopyroxene and olivine are the inferred ferromagnesian fractionation phases followed by plagioclase during the late fractionation stages. All the studied dykes have, similar to many continental flood basalts (CFB), large-ion lithophile element (LILE) and light rare-earth element (LREE) enrichment and Nb and Ta depletion. The incompatible element abundance patterns are comparable to the patterns of many other Proterozoic dykes in India and Antarctica, to the late Archaean (～2.72 Ga) Dominion volcanics in South Africa and to the early Proterozoic (～2.0 Ga) Scourie dykes of Scotland. The geochemical characteristics of the TNM and DP dykes cannot be explained by crustal contamination alone. Instead, they are consistent with derivation from an enriched lithospheric mantle source which appears to have been developed much earlier than the dyke intrusions during a major crustal building event in the Archaean. The dyke magmas may have been formed by dehydration melting induced by decompression and lithospheric attenuation or plume impingement at the base of the lithosphere. These magmas, compared with CFB, appear to be the minor partial melts from plume heads of smaller diameter and of shallow origin (650 km). Therefore, the Proterozoic thermal events could induce crustal attenuation and dyke intrusions in contrast to the extensive CFB volcanism and continental rifting generally associated with the Phanerozoic plumes of larger head diameter (>1000 km) and of deeper origin (at crust mantle boundary).     

Distribution, characterization, and geochemical controls of elements of concern in uranium mine tailings, Key Lake, Saskatchewan, Canada

The distribution of As, Mo, Ni and Se in the aqueous and solid phases of U mine tailings in the Deilmann Tailings Management Facility (DTMF), located at the Key Lake mine in northern Saskatchewan, Canada, was defined using as-discharged tailings samples collected monthly starting in 1996 and core samples collected from the DTMF from 3 locations on 3 occasions between 2004 and 2009. These data indicated that the DTMF can be divided into two geochemical zones; tailings generated from the Deilmann ore body between 1996 and 2000 and tailings from the McArthur River ore body, mined after July 2000. The Deilmann tailings solids are generally characterized by greater elemental concentrations than those in the McArthur River tailings, particularly for As, Co and Ni. These elevated concentrations are attributed to the abundance of Ni–Co–As–S minerals in this ore. The mean aqueous concentrations of As, Mo, Ni, and Se are 3.7, 23.2, 0.14, and 0.02 mg L⁻¹, respectively, in the Deilmann porewaters and 0.20, 4.16, 0.06, and 0.03 mg L⁻¹, respectively, in the McArthur River porewaters. Similarly, the mean As, Mo, Ni, and Se solid phase concentrations are 5.89 × 10³, 69.9, 3.20 × 10³, and 17.4 μg g⁻¹, respectively, for the Deilmann tailings and 440, 13.6, 551, and 3.03 μg g⁻¹ in the McArthur River tailings. Statistically, pH remained unchanged from the time of discharge while Eh values have remained oxic with no significant change between the two tailings types over 15 a of residence time. Results from sequential extractions, thermodynamic modeling, and results of complimentary research indicated that ferrihydrite solubility is the dominant control on aqueous As concentrations and also plays a role in controlling dissolved Mo, Ni and Se.     

A coupling of mixed and discontinuous Galerkin finite-element methods for poroelasticity

In this paper, we formulate a finite-element procedure for approximating the coupled fluid and mechanics in Biot’s consolidation model of poroelasticity. We approximate the flow variables by a mixed finite-element space and the displacement by a family of discontinuous Galerkin methods. Theoretical convergence error estimates are derived and, in particular, are shown to be independent of the constrained specific storage coefficient, c _o . This suggests that our proposed algorithm is a potentially effective way to combat locking, or the nonphysical pressure oscillations, which sometimes arise in numerical algorithms for poroelasticity.     

Limitations of the ferrozine method for quantitative assay of mineral systems for ferrous and total iron

The quantitative assay of clay minerals, soils, and sediments for Fe(II) and total Fe is fundamental to understanding biogeochemical cycles occurring therein. The commonly used ferrozine method was originally designed to assay extracted forms of Fe(II) from non-silicate aqueous systems. It is becoming, however, increasingly the method of choice to report the total reduced state of Fe in soils and sediments. Because Fe in soils and sediments commonly exists in the structural framework of silicates, extraction by HCl, as used in the ferrozine method, fails to dissolve all of the Fe. The phenanthroline (phen) method, on the other hand, was designed to assay silicate minerals for Fe(II) and total Fe and has been proven to be highly reliable. In the present study potential sources of error in the ferrozine method were evaluated by comparing its results to those obtained by the phen method. Both methods were used to analyze clay mineral and soil samples for Fe(II) and total Fe. Results revealed that the conventional ferrozine method under reports total Fe in samples containing Fe in silicates and gives erratic results for Fe(II). The sources of error in the ferrozine method are: (1) HCl fails to dissolve silicates and (2) if the analyte solution contains Fe³⁺, the analysis for Fe²⁺ will be photosensitive, and reported Fe(II) values will likely be greater than the actual amount in solution. Another difficulty with the ferrozine method is that it is tedious and much more labor intensive than the phen method. For these reasons, the phen method is preferred and recommended. Its procedure is simpler, takes less time, and avoids the errors found in the ferrozine method.     

A micromorphological analysis of stratigraphic integrity and site formation at Cactus Hill,an Early Paleoindian and hypothesized pre‐Clovis occupation in south‐central Virginia,USA

Twenty thin sections were studied from Cactus Hill, a ca. 20 ka stratified sand dune site in Virginia, USA, with a Clovis and hypothesized pre‐Clovis component. The high‐resolution soil micromorphology investigation focused on testing the integrity of Clovis and pre‐Clovis stratigraphy from one location where there is a high density of artifacts. Site formation processes were dominated by eolian (dune) sand formation. There was also ephemeral topsoil development and associated occupation, along with their penecontemporaneous disturbance and dispersal by scavenging animals (assumed) and localized down‐working by small invertebrate mesofauna (as evidenced by aggregates of fine phytolith‐rich humic soil and fine soil‐coated charcoal fragments). Partial erosion of these occupation soils (deflation?) was followed by successive sand burial. Post‐depositional processes affecting these sand‐buried occupations involved only small‐scale bioturbation and overprinting of clay lamellae, suggesting site stratigraphy has been stable for a long time. Soil micromorphological analysis has defined a difference between occupational units (pre‐Clovis and Clovis) and sterile units found between these units as well as above and below. In summary, according to this analysis, the site appears intact with only minor disturbances affecting the long‐term integrity of the stratigraphy. © 2008 Wiley Periodicals, Inc.     

Tumbi Landslide, Papua New Guinea: rainfall induced?

On 24 January 2012, a fatal landslide with an estimated volume of 3 Mm³ hit villagers and infrastructure in the Tagali Valley, Southern Highlands Province, Papua New Guinea (PNG). Although a moderate event by PNG standards, the associated human casualties and infrastructure destruction give a human as well as a scientific need to review the potential causes for the event. PNG experiences numerous landslides annually, most of which are trigged either by rainfall events or seismic activity. Here, we review the short-term rainfall patterns leading up to the slope failure at Tumbi Quarry and compare the rainfall accumulations obtained over durations of 30, 60 and 90 days prior to the landslide, with comparable rainfall accumulations obtained for other failures observed in PNG over a 12-year period. Additionally, a review of long-term rainfall over a period of 6 months prior to the failure is completed as well as an assessment of seismic activity. Based on our analysis, we believe a seismic trigger to be very unlikely, while the increase in rainfall in the 2 weeks prior to the failure in conjunction with a high-intensity rainfall event at the end of October 2011 could have had a greater influence in enhancing rather than restraining slope failure. This, in addition to natural denudational processes, geological structure and the anthropogenic activity in the vicinity of the landslide, could all have served to affect slope stability.     

Determining the trophic guilds of fishes and macroinvertebrates in a seagrass food web

We established trophic guilds of macroinvertebrate and fish taxa using correspondence analysis and a hierarchical clustering strategy for a seagrass food web in winter in the northeastern Gulf of Mexico. To create the diet matrix, we characterized the trophic linkages of macroinvertebrate and fish taxa present inHalodule wrightii seagrass habitat areas within the St. Marks National Wildlife Refuge (Florida) using binary data, combining dietary links obtained from relevant literature for macroinvertebrates with stomach analysis of common fishes collected during January and February of 1994. Heirarchical average-linkage cluster analysis of the 73 taxa of fishes and macroinvertebrates in the diet matrix yielded 14 clusters with diet similarity ≥ 0.60. We then used correspondence analysis with three factors to jointly plot the coordinates of the consumers (identified by cluster membership) and of the 33 food sources. Correspondence analysis served as a visualization tool for assigning each taxon to one of eight trophic guilds: herbivores, detritivores, suspension feeders, omnivores, molluscivores, meiobenthos consumers, macrobenthos consumers and piscivores. These trophic groups, corss-classified with major taxonomic groups, were further used to develop consumer compartments in a network analysis model of carbon flow in this seagrass ecosystem. The method presented here should greatly improve the development of future network models of food webs by providing an objective procedure for aggregating trophic groups.