Source partitioning of anthropogenic groundwater nitrogen in a mixed-use landscape,Tutuila, American Samoa

This study presents a modeling framework for quantifying human impacts and for partitioning the sources of contamination related to water quality in the mixed-use landscape of a small tropical volcanic island. On Tutuila, the main island of American Samoa, production wells in the most populated region (the Tafuna-Leone Plain) produce most of the island’s drinking water. However, much of this water has been deemed unsafe to drink since 2009. Tutuila has three predominant anthropogenic non-point-groundwater-pollution sources of concern: on-site disposal systems (OSDS), agricultural chemicals, and pig manure. These sources are broadly distributed throughout the landscape and are located near many drinking-water wells. Water quality analyses show a link between elevated levels of total dissolved groundwater nitrogen (TN) and areas with high non-point-source pollution density, suggesting that TN can be used as a tracer of groundwater contamination from these sources. The modeling framework used in this study integrates land-use information, hydrological data, and water quality analyses with nitrogen loading and transport models. The approach utilizes a numerical groundwater flow model, a nitrogen-loading model, and a multi-species contaminant transport model. Nitrogen from each source is modeled as an independent component in order to trace the impact from individual land-use activities. Model results are calibrated and validated with dissolved groundwater TN concentrations and inorganic δ¹⁵N values, respectively. Results indicate that OSDS contribute significantly more TN to Tutuila’s aquifers than other sources, and thus should be prioritized in future water-quality management efforts.     

Role of aeolian sediment accretion in the formation of heuweltjie earth mounds,western South Africa

The action of organisms in shaping landforms is increasingly recognized; the field of biogeomorphology and the conceptual framework of ecosystem engineering have arisen in response to the need for integrated studies of the interactions between biotic and abiotic components of landscapes. Pathways by which organisms influence landscape development may be complex. For example, primary change initiated by one biotic element may initiate a cascade of other changes that eventually produce a significant landscape modification. Mound‐like landforms in North America and southern Africa are widely cited examples of biogenic structures, yet there is considerable controversy regarding the processes responsible for their formation. Heuweltjies (Afrikaans for little hills) are circular mounds ranging from 10–30 m diameter and 0.5–2 m height and are widespread in western South Africa. Colonies of the termite (Microhodotermes viator) are typically associated with heuweltjies and some investigators have attributed heuweltjie formation to the direct action of termites in redistributing earthen materials. However, rather than being directly responsible in this way, termites simply create nutrient‐rich islands, which support denser vegetation, thereby inducing the localized accretion of aeolian sediments and upward growth of mounds. Contrasting soil features in heuweltjies in one locale indicate these processes have occurred throughout the late Quaternary. Geographic variation in sizes of mounds is explained in part by the local availability of sediments that can be mobilized and redistributed by the wind. Recognition of the operation of aeolian processes in the formation of heuweltjies has important implications for conservation. Any land use that diminishes the sediment‐trapping effect of vegetation on heuweltjies truncates the very process by which new aeolian materials can accrue and may promote irreversible erosion and landscape degradation. Copyright © 2014 John Wiley & Sons, Ltd.     

B and Li isotopes as intrinsic tracers for injection tests in aquifer storage and recovery systems

Boron and Li isotopes have been tested as environmental tracers of treated sewage injected into a sandy aquifer (Shafdan reclamation project, Israel). During a 38 days injection test in a newly dug injection well, a conservative artificial tracer (Br⁻) was monitored together with δ¹¹B and δ⁷Li in the injectate, in the unsaturated soil zone (porous cup) and an observation well in the aquifer. In spite of B and Li concentrations in the injectate close to background values, significant shifts of the isotope signatures could be observed over the duration of the injection test. Boron isotope ratios show a breakthrough curve delayed with respect to Br⁻ breakthrough due to some reversible sorption on the aquifer material. No isotope fractionation was observed in the unsaturated or the saturated zone so that B isotopes can be considered as conservative in the investigated part of the aquifer system. Lithium isotopes are strongly fractionated, probably due to sorption processes. Lithium concentrations point to a Li sink in the system, δ⁷Li values vary strongly with a tendency of ⁷Li depletion in the liquid phase over the duration of the experiment. This is opposite to the expected preferential sorption of ⁶Li onto clay minerals. Boron isotopes reveals a valuable tracer of artificial recharge of freshwaters derived from treated sewage, both for short term tracer tests and for long-term monitoring of artificial recharge, even if in aquifers with higher clay contents, sorption-linked isotope fractionation cannot be excluded. More data are needed on Li isotope fractionation in natural groundwater systems to assess the potential of this tracer as monitoring tool.     

Satellite-Based Assessment of the Extent and Changes in the Mangrove Ecosystem of the Niger Delta

This study was carried out with the primary aim of understanding how the mangrove ecosystem in the Niger Delta has been altered recently. Specifically, we determined the spatial extent of the mangrove forest in the Niger Delta using remotely sensed satellite data and estimated changes in the spatial extent of the forest from the mid-1980s through 2003. Overall, about 21,340 hectares of Mangrove forest was lost over the study period. Fieldwork confirmed that these losses were primarily due to urbanization, dredging activities, activities of the oil and gas industries, and the spread of Nypa Palm (Nypa frutican) plant species.     

Species loss in the brown world: are heterotrophic systems inherently stable?

Determining the effects of species loss on ecosystems has received considerable attention given the current threats many ecosystems are facing. A significant body of research has yielded many insights to this question, but this work has been limited by a focus on ecosystems where primary production plays a significant role in energy transfer. As many ecosystems rely on energy sources that are not derived from in situ production, there is a need to better understand how species loss will affect ecosystems of varying trophic states. To examine the effects of species loss on an ecosystem that is not reliant on in situ primary production, we manipulated the larval amphibian community of temporary forest ponds. These ponds are heterotrophic systems that rely on allochthonous inputs of detritus as a basal energy source. The larvae of two amphibian species that are prone to local extinction, wood frogs (Lithobates sylvatica) and spotted salamanders (Ambystoma maculatum), were removed from ponds and net ecosystem production was monitored. We found no effects of the removal of these top consumers on ecosystem functioning or on lower trophic groups (i.e., zooplankton, algae, bacteria). While amphibians can influence food web dynamics in other systems, their influence on system processes in temporary forest ponds appears to be limited. We hypothesize that the lack of any effects is due to the microbial degradation of detritus ??swamping?? the system, providing more than enough energy to maintain the food web, and/or due to omnivory dampening species interactions. These data indicate that the functioning of heterotrophic systems may be inherently stable due to internal dynamics that minimize interaction strengths among trophic groups.     

Storm rainfall conditions for floods and debris flows from recently burned areas in southwestern Colorado and southern California

Debris flows generated during rain storms on recently burned areas have destroyed lives and property throughout the Western U.S. Field evidence indicate that unlike landslide-triggered debris flows, these events have no identifiable initiation source and can occur with little or no antecedent moisture. Using rain gage and response data from five fires in Colorado and southern California, we document the rainfall conditions that have triggered post-fire debris flows and develop empirical rainfall intensity–duration thresholds for the occurrence of debris flows and floods following wildfires in these settings. This information can provide guidance for warning systems and planning for emergency response in similar settings.Debris flows were produced from 25 recently burned basins in Colorado in response to 13 short-duration, high-intensity convective storms. Debris flows were triggered after as little as six to 10 min of storm rainfall. About 80% of the storms that generated debris flows lasted less than 3 h, with most of the rain falling in less than 1 h. The storms triggering debris flows ranged in average intensity between 1.0 and 32.0 mm/h, and had recurrence intervals of two years or less. Threshold rainfall conditions for floods and debris flows sufficiently large to pose threats to life and property from recently burned areas in south-central, and southwestern, Colorado are defined by: I = 6.5D^− 0.7 and I = 9.5D^− 0.7, respectively, where I = rainfall intensity (in mm/h) and D = duration (in hours).Debris flows were generated from 68 recently burned areas in southern California in response to long-duration frontal storms. The flows occurred after as little as two hours, and up to 16 h, of low-intensity (2–10 mm/h) rainfall. The storms lasted between 5.5 and 33 h, with average intensities between 1.3 and 20.4 mm/h, and had recurrence intervals of two years or less. Threshold rainfall conditions for life- and property-threatening floods and debris flows during the first winter season following fires in Ventura County, and in the San Bernardino, San Gabriel and San Jacinto Mountains of southern California are defined by I = 12.5D^−0.4, and I = 7.2D^−0.4, respectively. A threshold defined for flood and debris-flow conditions following a year of vegetative recovery and sediment removal for the San Bernardino, San Gabriel and San Jacinto Mountains of I = 14.0D^−0.5 is approximately 25 mm/h higher than that developed for the first year following fires.The thresholds defined here are significantly lower than most identified for unburned settings, perhaps because of the difference between extremely rapid, runoff-dominated processes acting in burned areas and longer-term, infiltration-dominated processes on unburned hillslopes.     

Biofilm Detection in a Model Well‐Bore Environment Using Low‐Field NMR

This research addresses the challenges of the lack of non‐invasive methods and poor spatiotemporal resolution associated with monitoring biogeochemical activity central to bioremediation of subsurface contaminants. Remediation efforts often include growth of biofilm to contain or degrade chemical contaminants, such as nitrates, hydrocarbons, heavy metals, and some chlorinated solvents. Previous research indicates that nuclear magnetic resonance (NMR) is sensitive to the biogeochemical processes of biofilm accumulation. The current research focuses on developing methods to use low‐cost NMR technology to support in situ monitoring of biofilm growth and geochemical remediation processes in the subsurface. Biofilm was grown in a lab‐scale radial flow bioreactor designed to model the near wellbore subsurface environment. The Vista Clara Javelin NMR logging device, a slim down‐the‐borehole probe, collected NMR measurements over the course of eight days while biofilm was cultivated in the sand‐packed reactor. Measured NMR mean log T₂ relaxation times decreased from approximately 710 to 389 ms, indicating that the pore environment and bulk fluid properties were changing due to biofilm growth. Destructive sampling employing drop plate microbial population analysis and scanning electron and stereoscopic microscopy confirmed biofilm formation. Our findings demonstrate that the NMR logging tool can detect small to moderate changes in T₂ distribution associated with environmentally relevant quantities of biofilm in quartz sand.     

Supporting farmer-managed irrigation systems in the Shigar valley,Karakorum: Role of the government and Aga Khan Rural Support Programme

Farmer-managed irrigation systems(FMIS) in the high altitude valleys of the Karakorum,Pakistan, continue to be managed effectively despite increased pressure on the social arrangements that sustain them. Colonial era records shows that over a century ago government agencies undertook irrigation support projects. In the past three decades,government agencies and the non-government agency Aga Khan Rural Support Programme(AKRSP), which channels foreign funds into the region, have actively engaged in the provision of irrigation support. This article seeks to explore whether such projects support or undermine farmer-managed irrigation systems and the complex institutional arrangements that underpin them. Field research using ethnographic and participatory methods was conducted in spring 2013 in the upper Shigar valley, Skardu district, GilgitBaltistan. The findings show that irrigation development is a political activity that involves village-based actors, religious leaders, local politicians,and government and non-government agencies.Government agencies operate in a largely top-down,engineering mode, their larger projects limited to villages suffering water scarcity. The local government provides small funds for renovation work of FMIS,though allocation of funds is highly politicized. Nongovernment agencies, for a variety of reasons including donor-funding cycles, apply a one-size-fitsall ‘participatory' model in an attempt to socially engineer rules and institutions. In communities divided by factionalism the use of such external models that stress formation of committees are unlikely to yield positive results, and could instead contribute to undermining the very systems they seek to support. This research argues that irrigation interventions should take care to build upon the rich and complex social arrangements that have sustained FMIS through the centuries.     

MTBE, TBA, and TAME Attenuation in Diverse Hyporheic Zones

Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert -butyl ether (MTBE), tert -butyl alcohol (TBA), and tert -amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four sites were investigated on Long Island, New York, characterized by groundwater contaminated with gasoline and fuel oxygenates that ultimately discharge to fresh, brackish, or saline surface water. For each site, contaminated groundwater discharge zones were delineated using pore water geochemistry data from 15 feet (4.5 m) beneath the bottom of the surface water body in the hyporheic zone and seepage-meter tests were conducted to measure discharge rates. These data when combined indicate that MTBE, TBA, and TAME concentrations in groundwater discharge in a 5-foot (1.5-m) thick section of the hyporheic zone were attenuated between 34% and 95%, in contrast to immeasurable attenuation in the shallow aquifer during contaminant transport between 0.1 and 1.5 miles (0.1 to 2.4 km). The attenuation observed in the hyporheic zone occurred primarily by physical processes such as mixing of groundwater and surface water. Biodegradation also occurred as confirmed in laboratory microcosms by the mineralization of U- ¹⁴C-MTBE and U-¹⁴C-TBA to ¹⁴CO₂ and the novel biodegradation of U- ¹⁴C-TAME to ¹⁴CO₂ under oxic and anoxic conditions. The implication of fuel oxygenate attenuation observed in diverse hyporheic zones suggests an assessment of the hyporheic zone attenuation potential (HZAP) merits inclusion as part of site assessment strategies associated with monitored or engineered attenuation.     

Investigation of OMA formation and the effect of minerals

Oil-mineral-aggregates (OMA) have been shown to be effective in oil spills cleanup. Experimental work was carried out to study the effects of physical-chemical properties of natural minerals and chemically modified minerals on OMA formation and oil removal. The results showed that the hydrophobicity, particle sizes and specific surface of minerals played an important role in OMA formation. Appropriate hydrophobicity of minerals can enhance the formation of OMA. The surface property of minerals can also influence the shape of OMA. Spherical mineral-oil aggregates were frequently formed with hydrophilic minerals while irregular shaped OMA were observed with hydrophobic minerals. The sizes of OMA also increased when the minerals changed from hydrophilic to hydrophobic. The effects of dispersant and mixing energy were also carefully studied. The results showed that dispersant were a dominant factor. When dispersant was applied, effects of other factors became minimal.