Nonlinear Least-Squares Analysis of Stokes Profiles

We describe improvements to the calibration and analysis of Fe i 6302.5 Å data from the San Fernando Observatory Video Spectra-Spectroheliograph (SFO-VSSHG). A more effective flat field is generated and the scales of the simultaneous Stokes measurements are made equal. Analysis of Stokes profiles is carried out using a moments technique but applied to nonlinear least-squares fits to the data. Typical spectropolarimetric results from the old and new methods are compared and discussed. Finally, we present asymmetry maps, a zero-crossing map, and a relative-split map extracted from the fits to the Stokes V profiles.     

Recharge sources and hydrogeochemical evolution of groundwater in semiarid and karstic environments: A field study in the Granada Basin (Southern Spain)

The objective of this study is to refine the understanding of recharge processes in watersheds representative for karstic semiarid areas by means of stable isotope analysis and hydrogeochemistry. The study focuses on the Granada aquifer system which is located in an intramontane basin bounded by high mountain ranges providing elevation differences of almost 2900 m. These altitude gradients lead to important temperature and precipitation gradients and provide excellent conditions for the application of stable isotopes of water whose composition depends mainly on temperature. Samples of rain, snow, surface water and groundwater were collected at 154 locations for stable isotope studies (δ¹⁸O, D) and, in the case of ground- and surface waters, also for major and minor ion analysis. Thirty-seven springs were sampled between 2 and 5 times from October 2004 to March 2005 along an altitudinal gradient from 552 masl in the Granada basin to 2156 masl in Sierra Nevada. Nine groundwater samples were taken from the discharge of operating wells in the Granada basin which are all located between 540 and 728 masl. The two main rivers were monitored every 2–3 weeks at three different altitudes. Rainfall being scarce during the sampling period, precipitation could only be sampled during four rainfall events. Calculated recharge altitudes of springs showed that source areas of mainly snowmelt recharge are generally located between 1600 and 2000 masl. The isotope compositions of spring water indicate water sources from the western Mediterranean as well as from the Atlantic without indicating a seasonal trend. The isotope pattern of the Quaternary aquifer reflects the spatial separation of different sources of recharge which occur mainly by bankfiltration of the main rivers. Isotopic signatures in the southeastern part of the aquifer indicate a considerable recharge contribution by subsurface flow discharged from the adjacent carbonate aquifer. No evaporation effects due to agricultural irrigation were detected.     

Carbon fluxes resulting from land-use changes in the Tamaulipan thornscrub of northeastern Mexico

Information on carbon stock and flux resulting from land-use changes in subtropical, semi-arid ecosystems are important to understand global carbon flux, yet little data is available. In the Tamaulipan thornscrub forests of northeastern Mexico, biomass components of standing vegetation were estimated from 56 quadrats (200 m² each). Regional land-use changes and present forest cover, as well as estimates of soil organic carbon from chronosequences, were used to predict carbon stocks and fluxes in this ecosystem.     

Spatial variability of the surf zone fish and macroinvertebrate community within dissipative sandy beaches in Oregon,USA

Habitat heterogeneity can influence biological communities by providing a diversity of areas that can be occupied by different species. Sandy beach surf zones are often considered homogenous environments; however, sand bars moved by currents and waves can produce trench‐like shapes or troughs that provide heterogeneity. The influence of habitat heterogeneity produced by sand movement is unclear despite the fact that surf zones are an important habitat for larval and juvenile fish and macrocrustaceans. To determine if, and how, the fish and macroinvertebrate communities present in trough and non‐trough or flat areas of Oregon surf zones differ, we compared species assemblages in both areas at three beaches adjacent to estuary mouths over 2 years. Troughs had different communities compared with flat areas, with higher total catch (mean ± SD = 123.2 ± 122.1 versus 43.6 ± 44.5 individuals × 100 m^?2) and taxon richness (6.7 ± 2.7 versus 4.0 ± 2.3 taxa); these differences were potentially due to water movement, prey availability and sediment size. The fish and macroinvertebrate communities did not vary between years but there were significant differences among beaches, with the most distinct community present at the only beach adjacent to an estuary without a jetty at its mouth, which was possibly due to higher species movement between the surf zones and estuary. Fish and macrocrustacean surf zone communities varied spatially within and among beaches in relation to habitat heterogeneity provided by sand movement and, potentially, the influence of adjacent habitats.     

Measurements and modelling of the advection of suspended sediment in the swash zone by solitary waves

Novel laboratory experiments and numerical modelling have been performed to study the advection scales of suspended sediment in the swash zone. An experiment was designed specifically to measure only the sediment picked up seaward of the swash zone and during bore collapse. The advection scales and settling of this sediment were measured during the uprush along a rigid sediment-free beach face by a sediment trap located at varying cross-shore positions. Measurements were made using a number of repeated solitary broken waves or bores. Approximately 25% of the pre-suspended sediment picked up by the bores reaches the mid-swash zone (50% of the horizontal run-up distance), indicating the importance of the sediment advection in the lower swash zone. The pre-suspended sediment is sourced from a region seaward of the shoreline (still water line) which has a width of about 20% of the run-up distance. An Eulerian–Lagrangian numerical model is used to model the advection scales of the suspended sediment. The model resolves the hydrodynamics by solving the non-linear shallow water equations in an Eulerian framework and then solves the advection–diffusion equation for turbulence and suspended sediment in a Lagrangian framework. The model provides good estimates of the measured mass and distribution of sediment advected up the beach face. The results suggest that the correct modelling of turbulence generation prior to and during bore collapse and the advection of the turbulent kinetic energy into the lower swash is important in resolving the contribution of pre-suspended sediment to the net sediment transport in the swash zone.     

MHYDAS‐Erosion: a distributed single‐storm water erosion model for agricultural catchments

In this paper, we present MHYDAS‐Erosion, a dynamic and distributed single‐storm water erosion model developed as a module of the existing hydrological MHYDAS model. As with many catchment erosion models, MHYDAS‐Erosion is able to simulate sediment transport, erosion and deposition by rill and interrill processes. Its originality stems from its capacity to integrate the impact of land management practices (LMP) as key elements controlling the sedimentological connectivity in agricultural catchments. To this end, the water‐sediment pathways are first determined by a specific process‐oriented procedure defined and controlled by the user, which makes the integration of LMP easier. The LMP dynamic behaviours are then integrated into the model as a time‐dependent function of hydrological variables and LMP characteristics. The first version of the model was implemented for vegetative filters and tested using water and sediment discharge measurements at three nested scales of a densely instrumented catchment (Roujan, OMERE Observatory, southern France). The results of discharge and soil loss for simulated rainfall events have been found to acceptably compare with available data. The average R² values for water and sediment discharge are 0·82 and 0·83, respectively. The sensitivity of the model to changes in the proportion of LMP was assessed for a single rain event by considering three scenarios of the Roujan catchment management with vegetative filters: 0% (Scenario 1), 18% (Scenario 2, real case) and 100% (Scenario 3). Compared to Scenario 2 (real case), soil losses decreased for Scenario 3 by 65% on the agricultural plot scale, 62% on the sub‐catchment scale and 45% at the outlet of the catchment and increased for Scenario 1 by 0% on the plot scale, 26% on the sub‐catchment scale and 18% at the outlet of the catchment. Copyright © 2010 John Wiley & Sons, Ltd.     

Biomarkers and compound-specific stable carbon isotope of n-alkanes in crude oils from Eastern Llanos Basin,Colombia

Representative samples of crude oils from Cusiana, Cupiagua, Apiay, Castilla and Chichimene fields in the Eastern Llanos Basin of Colombia were analyzed to determine its compound-specific stable carbon isotope composition (CSIA) using gas chromatography–isotopic ratio–mass spectrometry (GC–IRMS). GC–IRMS analyses of n-alkanes allowed differentiating between Cretaceous and Cretaceous/Tertiary oil samples. Cretaceous sourced samples have δ¹³C-enriched values than Cretaceous/Tertiary sourced samples; the heavier isotope composition of these samples is due to their major terrigenous organic matter input. Their isotope distribution patterns suggest significant algal and/or bacterial contribution (marine origin). The analysis of the n-alkane fractions by GC–IRMS confirms that the organic matter has marine origin in those samples from Cusiana, Cupiagua and Apiay while Castilla and Chichimene have marine origin with terrestrial inputs. The results were confirmed by gas chromatography/FID and gas chromatography/mass spectrometry (GC/MS). Basic geochemical composition show that samples from Cupiagua/Cusiana fields and Apiay/Castilla/Chichimene fields in the Llanos basin, Colombia present different characteristics reflecting a specific for each depositional environment.     

A hydrological record extension model for reconstructing streamflows from tree‐ring chronologies

Characterizing drought events is an important factor in designing and operating water resource projects, but instrumental hydrologic records are generally short (<100 years). Because estimates of drought statistics can improve when longer records are available, we developed a stochastic model to extend instrumental streamflows based on tree‐ring chronologies. This Record Extension plus Noise (or REXTN) model consists of an autoregressive term to account for the temporal persistence of streamflows, predictor variables with longer records, and a noise term. The noise term was included to avoid underestimating the variability of the flows and to generate multiple extensions, which offer the possibility of quantifying the uncertainty of drought statistics such as the critical drought. For cases where having multiple extensions is not desirable, a statistically based algorithm was developed to select a single extended record. Using a simulation experiment, model REXTN was found to perform better than other existing reconstruction methods. The model was then applied to extend streamflows of the Poudre River, CO, USA, based on tree ring‐chronologies back to the year 1600, and the reconstructions were used to determine drought statistics such as duration and magnitude. When results based on the classical linear regression model were compared with those calculated by model REXTN, the latter was found to better match flow and drought statistics from the instrumental records, as well as to give a broader range of drought duration and magnitude. The REXTN model provides a useful addition to the range of tools available to hydrologists for coping with the uncertainty associated with water resource management under future climate scenarios. Copyright © 2014 John Wiley & Sons, Ltd.