Pressure and composition dependence of the electrical conductivity of iron-rich synthetic olivines to 200 kbar

The objectives of this study of olivines are, to calibrate the variation of electrical conductivity with pressure, up to 200 kbar in a diamond-anvil cell, and to determine how this is influenced by chemical composition. Experimentally, we have found that the variation of the electrical conductivity of three synthetic olivines containing 50, 75 and 100 mole percent of fayalite, is an exponential function of pressure P, closely represented at room temperature by:σ_xP=σ_x·exp ·(B _x·P) where x is the iron content of the olivine, σ _x the extrapolated value of conductivity at normal pressure and B _x the slope of the regression line in semi-logarithmic coordinates. It is thus possible to express the temperature dependence of conductivity through the Boltzmann relationship:σ_xPT= σ_αT· exp ·(-H*/RT)=σ_xT·exp ·[-(E*+PV _* ^x )/RT] where H* is the activation enthalpy, E* the activation energy and V _x ^* the activation volume. At constant temperature V _* ^x =B _x·RT and is approximately equal to 0,6 cm³/mole at 295 K. On the other hand, we have found that σ_xT is an exponential function of x and thus, B _x and of course V _x ^* are linear functions. The experimental procedure is described and the results discussed.     

Is geographical proximity necessary in the innovation networks in the era of global economy?

In the analysis of geographical spillovers, a commonly accepted hypothesis is that the different actors of innovation need to be physically closed to one another because the transfer of tacit knowledge implies frequent face-to-face relations. This hypothesis is put under closer examination in this paper. The first section analyses the need for economic agents to be closely located to develop research and innovative activities, starting with the analysis of their need for co-ordination and using some case studies. Based on the example of three French regions, the second section examines the importance given by the local development policies to geographical proximity in order to support the rapid development of local networks favouring innovation. In both sections, nonlocal relations appear as a key factor to develop innovation. As a conclusion, nonlocal relations should be encouraged by local development policies in the same way as local relations.     

Generalized plasticity state parameter‐based model for saturated and unsaturated soils. Part 1: Saturated state

The behavior of granular materials is known to depend on its loose or dense nature, which in turns depends both on density and confining pressure. Many models developed in the past require the use of different sets of constitutive parameters for the same material under different confining pressures. The purpose of this paper is to extend a basic generalized plasticity model for sands proposed by Pastor, Zienkiewicz and Chan by modifying the main ingredients of the model flow—rule, loading–unloading discriminating direction and plastic modulus—to include a dependency on the state parameter. The proposed model is tested against the available experimental data on three different sands, using for each of them a single set of material parameters, finding a reasonably good agreement between experiments and predictions. Copyright © 2010 John Wiley & Sons, Ltd.     

Monte-Carlo Simulations of Cosmic-ray and Internal Radiation Effects on ISOCAM on Board ISO

One of the main limitations to the sensitivity of the infrared camera ISOCAM on-board the Infrared Space Observatory (ISO) comes from responsivity variations and glitches caused by the impacts of charged particles in photo-detectors. Glitch rate measurements, glitch properties and removal methods have already been addressed during the first ISO detector workshop(Madrid, 1998) and published in a special issue of Experimental Astronomy. It appeared that glitch rate and most of glitch properties could be reproduced by Monte-Carlo simulations. This is very interesting in order to predict before launch the effect of charged particles in photo-detectors operated in space. This paper presents results of Monte-Carlo simulations of radiation effects on ISOCAM detectors. Glitch rates, spatial and energetic properties of glitches have been computed and are compared with measured values. This revised version was published online in July 2006 with corrections to the Cover Date.     

Natural and anthropogenic C2 to C6 hydrocarbons in the central-eastern Venezuelan atmosphere during the rainy season

The levels of low molecular weight hydrocarbons were measured at pristine sites and rural locations affected by hydrocarbon emissions from oil and gas producing fields in Venezuela. At the clean sites, lower concentrations of C₂ to C₆ alkanes were observed, whereas, in comparison with remotes sites, very much higher levels were measured at the polluted sites. Alkenes present relatively high concentrations, with isoprene being the most abundant, all over the study region. The main sources of alkenes are likely to be natural, mainly from vegetation. The levels of alkanes recorded at the clean sites and the alkene levels found everywhere in the region are in agreement with the values reported for other clean sites in the tropics. The increase of ozone production capacity due to the anthropogenic emissions of alkanes from oil and gas fields was estimated. Due to the presence in the atmosphere of important amounts of naturally emitted isoprene, ethene and propene, which makes a substantial contribution to the reactivity of the hydrocarbon mixture, a small increase (<5%) was estimated to occur in the capacity of the ozone production at a regional scale during the rainy season.     

Propagation of the cosmic-ray iron group at intermediate energies

Elemental abundances of the VH group of cosmic radiation have been measured in the energy interval 250–550 MeV nucl^–1 in a balloon exposure at Sioux Falls (South Dakota) of a plastic detector LeXAN stack. The so obtained abundances have been extrapolated to the sources in the frame of the homogeneous model correcting for energy loss. After taking into account solar modulation, the best fit to model values has led to a escape mean free path _e = 5E ^–0.4 g cm^–2, whereE is the energy in GeV nucl^–1, forE>1 GeV nucl^–1, and a constant _e = 5 g cm^–2 forE1 GeV nucl^–1. When turning to the diffusion model, also including an energy loss term, a diffusion coefficientD=3×10²⁸ cm² s^–1 has been estimated.     

Heat balance for the high-temperature component of a solar flare

Shortly after the occurrence of the impulsive spikes of the two-ribbon flare of May 21, 1980, a temperature analysis of the X-ray emitting flare plasma showed the presence of a low-temperature component [n = 15 × 10¹⁰ cm^#X2212;3; T = 20 × 10⁶ K] and a high-temperature component [n = 2 × 10¹⁰ cm^#X2212;3; T = 40 × 10⁶ K]. The mean free path of an electron in the hot component is comparable to the size of the source (≈ 10⁴ km). Heat losses from the hot source can therefore not be described with classical formulae. Theoretical arguments show that most likely the electron to ion temperature ratio T _e/T_i in the hot plasma is close to unity. This implies the presence of a hot ion component (T _i ≈ 40 × 10⁶ K) as well. Under these conditions (T _e ≈ T _i) heat flux limitation by electrostatic turbulence is ineffective. However, reduction of the heat flux is still possible due to the breakdown of classical theory. It is demonstrated that only non-classical current dissipation processes can sustain a hot source against cooling by a saturated heat flux. Investigation of the collisionality as a function of position along a magnetic loop shows that the breakdown of classical theory should be expected to occur first near the base of the loop. We conclude that the newly discovered hot source is important for the energy budget of the flare, even if the heat losses are considerably reduced. It is estimated that for the May 21, 1980 flare a total of about 10³¹ ergs were necessary to maintain the hot source against heat losses over the time period that it was observed (≈ 10 min).     

Temporal variability of selected dissolved elements in the lower Orinoco River,Venezuela

Monthly analyses of pH, conductance, alkalinity, total suspended solids, dissolved major cations (Na, K, Ca and Mg), and selected dissolved trace elements (Fe, Al, Mn, Cu, Zn and Cr) were conducted on waters of the lower Orinoco River from February 2004 to May 2006. The data show strong seasonal variability. Major cations had maximum concentrations at low water, and were correlated with pH, conductance and alkalinity because of the tributaries coming from the Andean zones, where the weathering of evaporites and carbonate shales controls water chemistry. K concentrations did not show any relation with evaporite weathering, probably because large amounts of K come from the Guayana Shield rivers as a consequence of feldspar weathering. The concentrations of dissolved Fe, Mn and Cu were highest during the high water stage. Concentrations of the elements K, Cr, Zn and Cu are correlated with each other but not with dissolved Fe and Al, which probably are complexed with humic and fulvic substances. Mn concentrations did not show relationships with other variables. Inter‐annual variability of dissolved elements is explained by temporal changes in precipitation. Copyright © 2008 John Wiley & Sons, Ltd.     

Mushroom production as an alternative for rural development in a forested mountainous area

Wild mushrooms are recognized as important non-wood forest products in mountainous ecosystems, but their real potential for generating rural economies has not been fully evaluated due to the difficulties in obtaining reliable productivity data, minimizing their true potential as contributor to rural economies. Mushroom yield models based on large data series from Pinus forest ecosystems in the region of Catalonia(Spain), combined with data from the Spanish National Forest Inventory allow us to estimate the potential mushroom productivity by forest ecosystems. The results of 24,500 tons/yr of mushrooms of which 16,300 tons are classified as edible and 7,900 tons are commonly marketed demonstrate the importance of mushroom productions in Catalonian pine forests, mostly located in mountainous areas where the development of agricultural activities is limited. Economic mushroom value is estimated at 48 million € for the edible mushroom and 32 million € for those corresponding to marketable yields, confirming the potential of this non-wood forest product. These production results and corresponding economic values provide a basis for the incorporation of wild mushrooms as significant non-wood forest products in the development of forest policies in mountainous areas.