Low calcification rates and calcium carbonate production in Porites panamensis at its northernmost geographic distribution

Porites panamensis is a hermatypic coral present in the eastern Pacific Ocean. Skeletal growth parameters have been reported, but studies of the relationship between annual calcification rates and environmental controls are scarce. In this study, we investigated three aspects of the annual calcification rates of P. panamensis: growth parameters among three P. panamensis populations; the sea surface temperature as a calcification rate control spanning a latitudinal gradient; and calcium carbonate production among three sites. Growth parameters varied among the sites due to the colony growth form. Massive colonies in the north showed a higher calcification rate than encrusting colonies in the south (mean: 1.22–0.49 g CaCO₃ · cm^?2 · yr^?1), where variations in calcification rates were related to growth rate (0.91–0.38 cm · yr^?1) rather than to skeletal density differences (overall mean ± SD, 1.31 ± 0.04 g CaCO₃ · cm^?3). Our results showed a positive linear relationship between annual calcification rates and sea surface temperatures within these P. panamensis populations. Differences were related to distinct oceanographic environments (within and at the entrance of the Gulf of California) with different sea surface temperature regimes and other chemical properties. Different populations calcified under different environmental conditions. Calcium carbonate production was dependent upon the calcification rate and coral cover and so carbonate production was higher in the north (coral cover 12%) than in the south (coral cover 3.5). Thus, the studied sites showed low calcium carbonate production (0.25–0.43 kg CaCO₃ · m^?2 · yr^?1). Our results showed reduced calcification rates, regional temperature regime control over calcification rates, different growth forms, low coral cover and low calcium carbonate production rates in P. panamensis.     

New stacked central configurations for the planar 5-body problem

A stacked central configuration in the n-body problem is one that has a proper subset of the n-bodies forming a central configuration. In this paper we study the case where three bodies with masses m ₁, m ₂, m ₃ (bodies 1, 2, 3) form an equilateral central configuration, and the other two with masses m ₄, m ₅ are symmetric with respect to the mediatrix of the segment joining 1 and 2, and they are above the triangle generated by {1, 2, 3}. We show the existence and non-existence of this kind of stacked central configurations for the planar 5-body problem.     

The lunar rock and mineral characterization consortium: Deconstruction and integrated mineralogical,petrologic, and spectroscopic analyses of mare basalts

The lunar rock and mineral characterization consortium (LRMCC) has conducted coordinated mineralogy/petrography/spectroscopy analyses of a suite of pristine lunar basalts. Four basalt slabs (two low‐Ti, two high‐Ti) and paired thin sections were analyzed. Thin sections were analyzed for mineralogy/petrography, while the slabs were used to prepare particulate separates of major mineral phases and bulk samples. Mineral separates and particulate bulk samples were crushed to controlled grain sizes and their reflectance spectra measured in the NASA RELAB at Brown University. The resulting data set provides an essential foundation for spectral mixing models, offers valuable endmember constraints for space weathering analyses, and represents critical new ground truth results for lunar science and exploration efforts.     

Near‐infrared spectra of clinopyroxenes: Effects of calcium content and crystal structure

Abstract– Pyroxenes are among the most common minerals in the solar system and are ideally suited for remote geochemical analysis because of the sensitivity of their distinctive spectra to mineral composition. Fe²⁺ is responsible for the dominant pyroxene absorptions in the visible and near‐infrared, but substitutions of other cations such as Ca²⁺ change the crystal structure and site geometries and thus the crystal field splitting energies of the Fe cations. To define spectral systematics resulting from major pyroxene cations (Ca²⁺, Mg²⁺, and Fe²⁺), we focus on a suite of pyroxenes synthesized with only Ca²⁺, Mg²⁺, and Fe²⁺ in the two octahedral sites, specifically examining the effect of Ca²⁺ on pyroxene absorption bands. The modified Gaussian model is used to deconvolve pyroxene spectra into component bands that can then be linked directly to crystal field absorptions. In orthopyroxenes and low‐Ca clinopyroxenes, Ca²⁺‐content has a strong and predictable effect on the positions of the absorption bands. At a threshold of Wo₃₀, the crystal field environment stagnates and the M2 bands cease to change significantly as more Ca²⁺ is added. At Wo₅₀, when most of the M2 sites are filled by Ca²⁺, band positions do not change drastically, although the presence and strengths of the 1 and 2 μm bands are affected by even trace amounts of Fe²⁺ in the M2 site. It is thus apparent that next‐nearest neighbors and the distortions they impose on the pyroxene lattice affect the electronic states around the Fe²⁺ cations and control absorption band properties.     

Evidence of space weathering in regolith breccias II: Asteroidal regolith breccias

Abstract– Space weathering products, such as agglutinates and nanophase iron‐bearing rims are easily preserved through lithification in lunar regolith breccias, thus such products, if produced, should be preserved in asteroidal regolith breccias as well. A study of representative regolith breccia meteorites, Fayetteville (H4) and Kapoeta (howardite), was undertaken to search for physical evidence of space weathering on asteroids. Amorphous or npFe⁰‐bearing rims cannot be positively identified in Fayetteville, although possible glass rims were found. Extensive friction melt was discovered in the meteorite that is difficult to differentiate from weathered materials. Several melt products, including spherules and agglutinates, as well as one irradiated rim and one possible npFe⁰‐bearing rim were identified in Kapoeta. The existence of these products suggests that lunar‐like space weathering processes are, or have been, active on asteroids.     

Exchange of ejecta between Telesto and Calypso: Tadpoles, horseshoes, and passing orbits

We have numerically integrated the orbits of ejecta from Telesto and Calypso, the two small Trojan companions of Saturn’s major satellite Tethys. Ejecta were launched with speeds comparable to or exceeding their parent’s escape velocity, consistent with impacts into regolith surfaces. We find that the fates of ejecta fall into several distinct categories, depending on both the speed and direction of launch.The slowest ejecta follow suborbital trajectories and re-impact their source moon in less than one day. Slightly faster debris barely escape their parent’s Hill sphere and are confined to tadpole orbits, librating about Tethys’ triangular Lagrange points L₄ (leading, near Telesto) or L₅ (trailing, near Calypso) with nearly the same orbital semi-major axis as Tethys, Telesto, and Calypso. These ejecta too eventually re-impact their source moon, but with a median lifetime of a few dozen years. Those which re-impact within the first 10 years or so have lifetimes near integer multiples of 348.6 days (half the tadpole period).Still faster debris with azimuthal velocity components ?10 m/s enter horseshoe orbits which enclose both L₄ and L₅ as well as L₃, but which avoid Tethys and its Hill sphere. These ejecta impact either Telesto or Calypso at comparable rates, with median lifetimes of several thousand years. However, they cannot reach Tethys itself; only the fastest ejecta, with azimuthal velocities ?40 m/s, achieve “passing orbits” which are able to encounter Tethys. Tethys accretes most of these ejecta within several years, but some 1% of them are scattered either inward to hit Enceladus or outward to strike Dione, over timescales on the order of a few hundred years.     

Medium-term responses of rocky bottoms to sewage discharges from a deepwater outfall in the NE Atlantic

An investigation on the effects of deepwater outfall discharges on the status of rocky reef communities was carried out. The sanitation system was found to be an environmentally suitable option for the protection of those habitats situated in high energy coastal environments. Sediments occurring between the predominating rocky substrates showed low values of the fine fraction (<63microm) and organic matter content. In addition, high average concentrations of Cd, Hg and Zn were found in these sediments, though these values were similar to those registered in non-affected sites, far away from the outfall. On the other hand, those assemblages typical of hard substrates that settled near the outfall showed an increase in total richness and abundance of macroinvertebrates. Moreover, the average number of species of each taxonomic group, a good indicator of the maintenance of the previous trophic structure, only varied considerably over time at the rip-rap protection. In a global context, those changes were not directly related to the discharge disturbances, but to the natural variability or the successional processes occurring within those communities. Only communities dwelling in the rip-rap protection area were affected by the proximity of the discharges.     

Carbon isotopes and iodine concentrations in a Mississippi River delta core recording land use, sediment transport, and dam building in the river's drainage basin

Sedimentary material from coastal and nearshore areas in the Mississippi Delta region are comprised of different organic carbon sources with diverse ages that require isotopic and elemental records for resolving the various sources of plant residues. Carbon isotopic ((13)C, (14)C) values were used to differentiate contributions from plants using the C3, C4, and/or CAM (crassulacean acid metabolism) carbon fixation pathways., and iodine concentrations indicated that wetland plant residues are a significant source of organic carbon in a sediment core from the Mississippi River delta region collected at a 60 m water depth. This sediment core had been extensively described in Oktay et al. [Oktay, S.D., Santschi, P.H., Moran, J.E., Sharma, P., 2000. The (129)Iodine Bomb Pulse Recorded in Mississippi River delta Sediments: Results from Isotopes of I, Pu, Cs, Pb, and C. Geochim. Cosmochim. Acta 64 (6), 989-996.] and significantly, includes unique features that had not previously been seen in the marine environment. These special features include a plutonium isotopic close-in fallout record that indicates a purely terrestrial source for these sediment particles and the elements associated with it, and a distinct iodine isotopic peak (as well as peaks for plutonium and cesium isotopes) that indicate little bioturbation in this core. Our carbon isotopic and iodine data can thus be compared to published records of changes in drainage basin land use, river hydrology, and hydrodynamic sorting of suspended particles to elucidate if these changes are reflected in nearshore sediments. This comparison suggests a significant contribution for organic carbon (OC) from C4 plants to these sediments during the 1950's to early 1960's. Relative older carbon isotopes, and episodically high iodine concentrations (up to 34 ppm) were observed during this time period that (1) indicate sediment deposition that is coincident with the times of major hydrological changes induced from dam and levee building in both the upper and lower reaches of the Mississippi River drainage basin, and (2) suggest episodic organic carbon deposition from wetland plant residues.     

Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C₁–C₄, CO₂]). Molecular ratios of LMWHC (C₁/[C₂ + C₃] > 1000) and stable isotopic compositions of methane (δ¹³C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C₁/C₂₊ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C₁–C₄, CO₂]) relative to the other gas types and the virtual lack of ¹⁴C–CH₄ indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C₁–C₄, CO₂)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of ¹⁴C–CH₄ (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area.     

Modelling shallow landslide susceptibility: a new approach in logistic regression by using favourability assessment

A new method for estimating shallow landslide susceptibility by combining Geographical Information System (GIS), nonparametric kernel density estimation and logistic regression is described. Specifically, a logistic regression is applied to predict the spatial distribution by estimating the probability of occurrence of a landslide in a 16 km² area. For this purpose, a GIS is employed to gather the relevant sample information connected with the landslides. The advantages of pre-processing the explanatory variables by nonparametric density estimation (for continuous variables) and a reclassification (for categorical/discrete ones) are discussed. The pre-processing leads to new explanatory variables, namely, some functions which measure the favourability of occurrence of a landslide. The resulting model correctly classifies 98.55% of the inventaried landslides and 89.80% of the landscape surface without instabilities. New data about recent shallow landslides were collected in order to validate the model, and 92.20% of them are also correctly classified. The results support the methodology and the extrapolation of the model to the whole study area (278 km²) in order to obtain susceptibility maps.