Size Fractionation (Dissolved, Colloidal and Particulate) of Trace Metals in the Thur River, Switzerland

The distribution of some trace metals (Cu, Zn, Ni, Co,Fe, Mn) and of DOC over a particulate (> 1 m),a colloidal (size < 0.45 m and molecular weight > 10 kD) and an ultrafiltered fraction (< 10 kD)was determined at several sites on the Thur River,Switzerland, at various times of the year. Thecomplexation of Cu by strong ligands in theultrafiltrate and in the conventional filtrate (<0.45 m) was compared using a ligand-exchange/CSV method.The <0.45 m concentrations of Cu (from anaverage of 7 nM to 24 nM), Zn (<5–23 nM), Ni (5–13 nM),Co (1.5–3 nM) and Mn (7–92 nM)increased downstream. The major part of Cu, Zn, Niand Co usually occurred in the ultrafiltratefraction at all sites, whereas Fe and Mn were mostlyin the particulate fraction, under conditions of lowsuspended matter content (< 10 mg L^-1) in theriver. The percentage of metal in the colloidalfraction, with respect to the 0.45-m filtrate,decreased in the order: Cu (median 11%) > Zn Ni(median 5–6%) > Mn Co (median < 5%). DOCalso consisted mostly of molecules in the < 10 kDrange.Cu was strongly complexed by natural organic ligandsin all filtrate and ultrafiltrate samples. A largepart of the strong Cu binding ligands consisted ofcompounds in the < 10 kD range, but colloidalligands with similar properties also occurred. Cu wasdistributed among the dissolved and the colloidalligands, roughly in proportion to organic carbon.The colloidal fraction (as defined here) did notincrease in its proportional amount downstream and wasonly of limited significance in transporting traceelements in the Thur River under low discharge conditions.     

Seasonal fluctuations in the deep central equatorial Atlantic Ocean: a data–model comparison

Low-frequency current fluctuations in the deep central equatorial Atlantic are analyzed using current meter measurements recorded from November 1992 to November 1994. Current meters were located at about 14°W of longitude and 1° of latitude on both sides of the equator between 1,700 m depth and the ocean bottom. At all sampling depths, the velocity fluctuations are dominantly zonal and symmetrical with respect to the equator. At 1,700 and 2,000 m, the flow is dominated by annual period fluctuations, at 3,000 m, the velocity field amplitude presents a minimum, and at 3,750 and 3,950 m, the flow is modulated by annual and semiannual period variability. The annual signal exhibits an apparent upward phase propagation. When considering the phase and the amplitude of the seasonal fluctuations, the data compare well with the outputs of a realistic numerical simulation of the Atlantic Ocean. Together with a previous analysis of the model simulations, this supports the idea that the observed annual fluctuations are due to wind-forced vertically propagating Kelvin and Rossby waves. Data and model do not provide deciding evidences of the presence of semiannual equatorial waves deeper than 3,500 m depth in the central equatorial Atlantic Ocean.     

CFD simulation of airflow over a regular array of cubes. Part II: analysis of spatial average properties

In the first part of this study, results of a computational fluid dynamics simulation over an array of cubes have been validated against a set of wind-tunnel measurements. In Part II, such numerical results are used to investigate spatially-averaged properties of the flow and passive tracer dispersion that are of interest for high resolution urban mesoscale modelling (e.g. non resolved obstacle approaches). The results show that vertical profiles of mean horizontal wind are linear within the canopy and logarithmic above. The drag coefficient, derived from the numerical results using the classical formula for the drag force, is height dependent (it decreases with height). However, a modification of the formula is proposed (accounting for subgrid velocity scales) that makes the drag coefficient constant with height. Results also show that the dispersive fluxes are similar in magnitude to the turbulent fluxes, and that they play a very important role within the canopy. Vertical profiles of turbulent length scales (to be used in k–l closure schemes, where k is the turbulent kinetic energy and l a turbulent length scale) are also derived. Finally the distribution of the values around the mean over the reference volumes are analysed for wind and tracer concentrations.     

The Würm in NW Iberia, a pollen record from Area Longa (Galicia)

The pollen record at Area Longa is the westernmost sequence available for investigation of the last glaciation in continental Europe. It is located in a region, NW Iberia, for which data from times earlier than the late glacial period are scarce. It comprises a series of exposed limnetic levels that lie above an Eemian (Oxygen Isotope Stage [OIS] 5e) beach and are separated by inorganic layers. The oldest limnetic level (Level I), attributed to the early glacial period (OIS 5a to OIS 5d), shows a dominance of woodland with high proportions of Fagus pollen and is tentatively identified with St. Germain I. The lower pleniglacial (OIS 4) Level II records a stadial landscape of grassland and shrub. Level III, from the pleniglacial interstade (OIS 3), reflects a complex period in which three warmer woodland phases alternated with periods of more open vegetation. This cyclical behavior correlates with the ice core isotope record and with the general tendencies observed in other Würmian pollen records, but the composition of our pollen profiles differs from those observed in these other records. In NW Iberia, the dominant trees were deciduous taxa, not conifers. Of particular note is the presence of lowland Fagus woodlands during the pre-Würm, and the occurrence of Carpinus considerably farther west than the boundary of its current distribution in the Iberian Peninsula.     

Vulnerability assessment in a volcanic risk evaluation in Central Mexico through a multi-criteria-GIS approach

The Valley of Toluca is a major industrial and agricultural area in Central Mexico, especially the City of Toluca, the capital of The State of Mexico. The Nevado de Toluca volcano is located to the southwest of The Toluca Basin. Results obtained from the vulnerability assessment phase of the study area (5,040 km² and 42 municipalities) are presented here as a part of a comprehensive volcanic risk assessment of The Toluca Basin. Information has been gathered and processed at a municipal level including thematic maps at 1:250,000 scale. A database has been built, classified and analyzed within a GIS environment; additionally, a Multi-Criteria Evaluation (MCE) approach was applied as an aid for the decision-making process. Cartographic results were five vulnerability maps: (1) Total Population, (2) Land Use/Cover, (3) Infrastructure, (4) Economic Units and (5) Total Vulnerability. Our main results suggest that the Toluca and Tianguistenco urban and industrial areas, to the north and northeast of The Valley of Toluca, are the most vulnerable areas, for their high concentration of population, infrastructure, economic activity, and exposure to volcanic events.     

Bioenergy potentials from forestry in 2050

The purpose of this study was to evaluate the global energy production potential of woody biomass from forestry for the year 2050 using a bottom-up analysis of key factors. Woody biomass from forestry was defined as all of the aboveground woody biomass of trees, including all products made from woody biomass. This includes the harvesting, processing and use of woody biomass. The projection was performed by comparing the future demand with the future supply of wood, based on existing databases, scenarios, and outlook studies. Specific attention was paid to the impact of the underlying factors that determine this potential and to the gaps and uncertainties in our current knowledge. Key variables included the demand for industrial roundwood and woodfuel, the plantation establishment rates, and the various theoretical, technical, economical, and ecological limitations related to the supply of wood from forests. Forests, as defined in this study, exclude forest plantations. Key uncertainties were the supply of wood from trees outside forests, the future rates of deforestation, the consumption of woodfuel, and the theoretical, technical, economical, or ecological wood production potentials of the forests. Based on a medium demand and medium plantation scenario, the global theoretical potential of the surplus wood supply (i.e., after the demand for woodfuel and industrial roundwood is met) in 2050 was calculated to be 6.1 Gm³ (71 EJ) and the technical potential to be 5.5 Gm³ (64 EJ). In practice, economical considerations further reduced the surplus wood supply from forests to 1.3 Gm³ year⁻¹ (15 EJ year⁻¹). When ecological criteria were also included, the demand for woodfuel and industrial roundwood exceeded the supply by 0.7 Gm³ year⁻¹ (8 EJ year⁻¹). The bioenergy potential from logging and processing residues and waste was estimated to be equivalent to 2.4 Gm³ year⁻¹ (28 EJ year⁻¹) wood, based on a medium demand scenario. These results indicate that forests can, in theory, become a major source of bioenergy, and that the use of this bioenergy can, in theory, be realized without endangering the supply of industrial roundwood and woodfuel and without further deforestation. Regional shortages in the supply of industrial roundwood and woodfuel can, however, occur in some regions, e.g., South Asia and the Middle East and North Africa.     

The energy balance experiment EBEX-2000. Part II: Intercomparison of eddy-covariance sensors and post-field data processing methods

The eddy-covariance method is the primary way of measuring turbulent fluxes directly. Many investigators have found that these flux measurements often do not satisfy a fundamental criterion—closure of the surface energy balance. This study investigates to what extent the eddy-covariance measurement technology can be made responsible for this deficiency, in particular the effects of instrumentation or of the post-field data processing. Therefore, current eddy-covariance sensors and several post-field data processing methods were compared. The differences in methodology resulted in deviations of 10% for the sensible heat flux and of 15% for the latent heat flux for an averaging time of 30 min. These disparities were mostly due to different sensor separation corrections and a linear detrending of the data. The impact of different instrumentation on the resulting heat flux estimates was significantly higher. Large deviations from the reference system of up to 50% were found for some sensor combinations. However, very good measurement quality was found for a CSAT3 sonic together with a KH20 krypton hygrometer and also for a UW sonic together with a KH20. If these systems are well calibrated and maintained, an accuracy of better than 5% can be achieved for 30-min values of sensible and latent heat flux measurements. The results from the sonic anemometers Gill Solent-HS, ATI-K, Metek USA-1, and R.M. Young 81000 showed more or less larger deviations from the reference system. The LI-COR LI-7500 open-path H₂O/CO₂ gas analyser in the test was one of the first serial numbers of this sensor type and had technical problems regarding direct solar radiation sensitivity and signal delay. These problems are known by the manufacturer and improvements of the sensor have since been made. The National Center for Atmospheric Research is supported by the National Science Foundation.     

Concentration profiles of particles settling in the neutral and stratified atmospheric boundary layer

An expression for the vertical equilibrium concentration profile of heavy particles, including the effects of canopy on the eddy diffusivity as well as corrections for atmospheric stability, is proposed. This expression is validated against measurements of vertical concentration profiles of corn pollen above a corn field. The fitted theoretical profiles show that particle settling is correctly accounted for. The sensitivity to variations in the turbulent Schmidt number, settling velocity and stability corrections are explicitly characterized. The importance of independent measurements of the surface flux of pollen in future experiments is noted.     

Time mean and variability of the scale-decomposed atmospheric water budget in a 25-year simulation of the Canadian Regional Climate Model over North America

The scaled-decomposed atmospheric water budget over North America is investigated through the analysis of 25 years of simulation by the Canadian Regional Climate Model (CRCM) driven by the NCEP–NCAR reanalyses for the period 1975–1999. The time average and time variability of the atmospheric water budget for the winter and summer seasons are decomposed into their large-scale and small-scale components to identify the added value of the regional model. For the winter season, the intra-seasonal transient-eddy variance is the main temporal variability. The large- and small-scale terms are of the same order of magnitude, and are large over both coasts and weak over the continent. For the summer season, the time–mean atmospheric water budget is rather different to that of winter, with maximum values over the south-eastern part of the continent. The summer intra-seasonal variance is about twice stronger than in winter and also dominates the variability, but the inter-monthly variance is non-negligible and can be in part associated to North American Monsoon System. Over the continent, the intra-seasonal climatological variance is dominated by the variability of the small scales. The small scales, that is those scales that are only resolved in the regional model but not in the reanalyses, contribute to the added value in a regional climate simulation. In the winter season, the added value of the CRCM is large and dominated by oceanic forcing, while in summer, it is dominant (larger than the large scales) and controlled mainly by convective processes.     

Occurrence and Resistance of Pathogenic Bacteria Along the Tietê River Downstream of São Paulo in Brazil

The load of pathogenic bacteria, their fate and their dangerousness in the Tietê River were assessed along 100 km starting from the city of São Paulo, Brazil. The data were compared with those from two German rivers. High loads of pathogens were found in the Tietê River near the city of São Paulo (Escherichia coli O157:H7, Shigella flexneri, and Shigella boydii), which were absent 30 km downstream of São Paulo. The antibiotic resistances observed in the Tietê river were rather low and decreased after the major input in São Paulo to significantly lower levels about 30 km downstream. While the Brazilian isolates were more susceptible for ampicillin than the German ones, the reverse was observed for gentamycin. For optimal control of infections in humans critical areas where these bacteria survived longer and their elimination mechanisms should be identified as well as the extent and the origin of antibiotic resistance should be determined.