Sulfur isotope variations from orebody to hand-specimen scale at the Mežica lead–zinc deposit, Slovenia: a predominantly biogenic pattern

The Mississippi Valley-type (MVT) Pb–Zn ore district at Mežica is hosted by Middle to Upper Triassic platform carbonate rocks in the Northern Karavanke/Drau Range geotectonic units of the Eastern Alps, northeastern Slovenia. The mineralization at Mežica covers an area of 64 km² with more than 350 orebodies and numerous galena and sphalerite occurrences, which formed epigenetically, both conformable and discordant to bedding. While knowledge on the style of mineralization has grown considerably, the origin of discordant mineralization is still debated. Sulfur stable isotope analyses of 149 sulfide samples from the different types of orebodies provide new insights on the genesis of these mineralizations and their relationship. Over the whole mining district, sphalerite and galena have δ ³⁴ S values in the range of –24.7 to –1.5‰ VCDT (–13.5 ± 5.0‰) and –24.7 to –1.4‰ (–10.7 ± 5.9‰), respectively. These values are in the range of the main MVT deposits of the Drau Range. All sulfide δ ³⁴ S values are negative within a broad range, with δ ³⁴ S _pyrite <δ ³⁴ S _sphalerite <δ ³⁴ S _galena for both conformable and discordant orebodies, indicating isotopically heterogeneous H₂S in the ore-forming fluids and precipitation of the sulfides at thermodynamic disequilibrium. This clearly supports that the main sulfide sulfur originates from bacterially mediated reduction (BSR) of Middle to Upper Triassic seawater sulfate or evaporite sulfate. Thermochemical sulfate reduction (TSR) by organic compounds contributed a minor amount of ³⁴S-enriched H₂S to the ore fluid. The variations of δ ³⁴ S values of galena and coarse-grained sphalerite at orefield scale are generally larger than the differences observed in single hand specimens. The progressively more negative δ ³⁴ S values with time along the different sphalerite generations are consistent with mixing of different H₂S sources, with a decreasing contribution of H₂S from regional TSR, and an increase from a local H₂S reservoir produced by BSR (i.e., sedimentary biogenic pyrite, organo-sulfur compounds). Galena in discordant ore (–11.9 to –1.7‰; –7.0 ± 2.7‰, n = 12) tends to be depleted in ³⁴ S compared with conformable ore (–24.7 to –2.8‰, –11.7 ± 6.2‰, n = 39). A similar trend is observed from fine-crystalline sphalerite I to coarse open-space filling sphalerite II. Some variation of the sulfide δ ³⁴ S values is attributed to the inherent variability of bacterial sulfate reduction, including metabolic recycling in a locally partially closed system and contribution of H₂S from hydrolysis of biogenic pyrite and thermal cracking of organo-sulfur compounds. The results suggest that the conformable orebodies originated by mixing of hydrothermal saline metal-rich fluid with H₂S-rich pore waters during late burial diagenesis, while the discordant orebodies formed by mobilization of the earlier conformable mineralization.     

Enregistrement de la variabilité hydroclimatique au cours des 6500 dernières années sur le littoral de Cabo Frio (Rio de Janeiro,Brésil)

This study concerns a core collected in Brejo do Espinho's lagoon from Cabo Frio littoral (Brazil) submitted to dry influence of local upwelling controlled by north-east trade winds from the South Atlantic and particularly strengthened during El Niño events. Diatoms study supported by sedimentological and isotopic analyses shows dry phases infrequent before 4000 yr, a highly variable climatic phase between 3600 and 2900 yr and from 2400 yr onward a dryness enhancement. To cite this article: B. Laslandes et al., C. R. Geoscience 338 (2006).     

Vulnerability assessment in a volcanic risk evaluation in Central Mexico through a multi-criteria-GIS approach

The Valley of Toluca is a major industrial and agricultural area in Central Mexico, especially the City of Toluca, the capital of The State of Mexico. The Nevado de Toluca volcano is located to the southwest of The Toluca Basin. Results obtained from the vulnerability assessment phase of the study area (5,040 km² and 42 municipalities) are presented here as a part of a comprehensive volcanic risk assessment of The Toluca Basin. Information has been gathered and processed at a municipal level including thematic maps at 1:250,000 scale. A database has been built, classified and analyzed within a GIS environment; additionally, a Multi-Criteria Evaluation (MCE) approach was applied as an aid for the decision-making process. Cartographic results were five vulnerability maps: (1) Total Population, (2) Land Use/Cover, (3) Infrastructure, (4) Economic Units and (5) Total Vulnerability. Our main results suggest that the Toluca and Tianguistenco urban and industrial areas, to the north and northeast of The Valley of Toluca, are the most vulnerable areas, for their high concentration of population, infrastructure, economic activity, and exposure to volcanic events.     

Stable isotope (C,O, S) systematics of the mercury mineralization at Idrija,Slovenia: constraints on fluid source and alteration processes

The world-class Idrija mercury deposit (western Slovenia) is hosted by highly deformed Permocarboniferous to Middle Triassic sedimentary rocks within a complex tectonic structure at the transition between the External Dinarides and the Southern Alps. Concordant and discordant mineralization formed concomitant with Middle Triassic bimodal volcanism in an aborted rift. A multiple isotopic (C, O, S) investigation of host rocks and ore minerals was performed to put constraints on the source and composition of the fluid, and the hydrothermal alteration. The distributions of the ¹³C and ¹⁸O values of host and gangue carbonates are indicative of a fracture-controlled hydrothermal system, with locally high fluid-rock ratios. Quantitative modeling of the ¹³C and ¹⁸O covariation for host carbonates during temperature dependent fluid-rock interaction, and concomitant precipitation of void-filling dolomites points to a slightly acidic hydrothermal fluid (¹³C–4 and ¹⁸O+10), which most likely evolved during isotopic exchange with carbonates under low fluid/rock ratios. The ³⁴S values of hydrothermal and sedimentary sulfur minerals were used to re-evaluate the previously proposed magmatic and evaporitic sulfur sources for the mineralization, and to assess the importance of other possible sulfur sources such as the contemporaneous seawater sulfate, sedimentary pyrite, and organic sulfur compounds. The ³⁴S values of the sulfides show a large variation at deposit down to hand-specimen scale. They range for cinnabar and pyrite from –19.1 to +22.8, and from –22.4 to +59.6, respectively, suggesting mixing of sulfur from different sources. The peak of ³⁴S values of cinnabar and pyrite close to 0 is compatible with ore sulfur derived dominantly from a magmatic fluid and/or from hydrothermal leaching of basement rocks. The similar stratigraphic trends of the ³⁴S values of both cinnabar and pyrite suggest a minor contribution of sedimentary sulfur (pyrite and organic sulfur) to the ore formation. Some of the positive ³⁴S values are probably derived from thermochemical reduction of evaporitic and contemporaneous seawater sulfates.Editorial handling: P. Lattanzi     

Coupled hydrogeological and reactive transport modelling of the Simpevarp area (Sweden)

The Simpevarp area is one of the alternative sites being considered for the deep geological disposal of high level radioactive waste in Sweden. In this paper, a coupled regional groundwater flow and reactive solute transport model of the Simpevarp area is presented that integrates current hydrogeological and hydrochemical data of the area. The model simulates the current hydrochemical pattern of the groundwater system in the area. To that aim, a conceptual hydrochemical model was developed in order to represent the dominant chemical processes. Groundwater flow conditions were reproduced by taking into account fluid-density-dependent groundwater flow and regional hydrogeologic boundary conditions. Reactive solute transport calculations were performed on the basis of the velocity field so obtained. The model was calibrated and sensitivity analyses were carried out in order to investigate the effects of heterogeneities of hydraulic conductivity in the subsurface medium. Results provided by the reactive transport model are in good agreement with much of the measured hydrochemical data. This paper emphasizes the appropriateness of the use of reactive solute transport models when water-rock interaction reactions are involved, and demonstrates what powerful tools they are for the interpretation of hydrogeological and hydrochemical data from site geological repository characterization programs, by providing a qualitative framework for data analysis and testing of conceptual assumptions in a process-oriented approach.     

Generative Adversarial Network Applied to Ore Type Modeling in Complex Geological Environments

Mathematical Geosciences - In complex geological environments, the spatial domain characterization of different ore types has been one of the most important challenges in the assessment of mineral...     

Toxic metals in a highly urbanized industry-impacted estuary (Bahia Blanca Estuary,Argentina): spatio-temporal analysis based on GIS

Cadmium, chromium, nickel, and lead were evaluated in the particulate fraction at one of the most industrialized estuaries at the Southwestern Atlantic Ocean, through Geographic Information System (GIS). Concentrations were analyzed at 21 stations during 2008–2010. The highest metal concentrations (Cd: 8,9; Cr: 256,49; Ni: 27,02; Pb: 78,43 µg g^??1 d. w.) were recorded at the stations located near industrial and urban discharges situated along the estuary. In addition, Pb presented a different seasonal and spatial behavior in comparison with Cd, Cr and Ni. Winter and spring presented the higher concentrations of Pb, and the inner stations presented the higher values. The estuary is considered a moderate to strongly polluted and significantly polluted according to the Index of geoaccumulation (I_geo) and the Enrichment Factor of Cd, respectively. The Multidimensional Scaling plot showed three groups of stations: the inner, associated to low levels of metals (G1), middle stations (G2) with intermediate levels and the outer (G3) with the highest ones. In addition, this work reveals the usefulness of the GIS-mapping techniques in the distribution of pollutants along an estuarine environment and the environmental quality assessment of estuarine systems.