Lower Jurassic magnetostratigraphy at the Breggia Gorge (Ticino, Switzerland) and Alpe Turati (Como, Italy)

Summary. The Breggia gorge (Ticino, Switzerland) provides a continuous outcrop of Mesozoic limestones covering the time between the Lower Jurassic and Upper Cretaceous. The Jurassic section from the Lower Pliens-bachian to Aalenian is well dated by ammonites. The limestones of these stages are a good quality recorder of the polarity of the geomagnetic field during this time interval. More than 500 cores have been drilled along a 120 m thick section with a median distance between cores of about 20 cm. Detailed thermal and af demagnetization and further rock magnetic studies were used to determine the characteristic NRM direction for each sample. Initial NRM intensities and low field susceptibilities reflect variations in oxidation potential and sedimentation rate during carbonate deposition. The Breggia section covers an estimated 12Myr of Lower to Middle Jurassic time during which more than 60 distinct reversals of the geomagnetic field are recorded. This corresponds to a comparatively high mean reversal frequency of about 5 reversals Myr⁻¹. The Breggia polarity zonation can be correlated with the nearby section at Alpe Turati (Como, Italy) and comparable polarity patterns are recognized in other biostratigraphically well-dated magnetostratigraphic profiles from Hungary and Umbria (Italy).     

TNOs are Cool: A Survey of the Transneptunian Region

Over one thousand objects have so far been discovered orbiting beyond Neptune. These trans-Neptunian objects (TNOs) represent the primitive remnants of the planetesimal disk from which the planets formed and are perhaps analogous to the unseen dust parent-bodies in debris disks observed around other main-sequence stars. The dynamical and physical properties of these bodies provide unique and important constraints on formation and evolution models of the Solar System. While the dynamical architecture in this region (also known as the Kuiper Belt) is becoming relatively clear, the physical properties of the objects are still largely unexplored. In particular, fundamental parameters such as size, albedo, density and thermal properties are difficult to measure. Measurements of thermal emission, which peaks at far-IR wavelengths, offer the best means available to determine the physical properties. While Spitzer has provided some results, notably revealing a large albedo diversity in this population, the increased sensitivity of Herschel and its superior wavelength coverage should permit profound advances in the field. Within our accepted project we propose to perform radiometric measurements of 139 objects, including 25 known multiple systems. When combined with measurements of the dust population beyond Neptune (e.g. from the New Horizons mission to Pluto), our results will provide a benchmark for understanding the Solar debris disk, and extra-solar ones as well.     

Constraints from deuterium on the formation of icy bodies in the Jovian system and beyond

We consider the role of deuterium as a potential marker of location and ambient conditions during the formation of small bodies in our Solar system. We concentrate in particular on the formation of the regular icy satellites of Jupiter and the other giant planets, but include a discussion of the implications for the Trojan asteroids and the irregular satellites. We examine in detail the formation of regular planetary satellites within the paradigm of a circum-Jovian subnebula. Particular attention is paid to the two extreme potential subnebulae—“hot” and “cold”. In particular, we show that, for the case of the “hot” subnebula model, the D:H ratio in water ice measured from the regular satellites would be expected to be near-Solar. In contrast, satellites which formed in a “cold” subnebula would be expected to display a D:H ratio that is distinctly over-Solar. We then compare the results obtained with the enrichment regimes which could be expected for other families of icy small bodies in the outer Solar system—the Trojan asteroids and the irregular satellites. In doing so, we demonstrate how measurements by Laplace, the James Webb Space Telescope, HERSCHEL and ALMA will play an important role in determining the true formation locations and mechanisms of these objects.     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

Is there a limit to bioretention effectiveness? Evaluation of stormwater bioretention treatment using a lumped urban ecohydrologic model and ecologically based design criteria

In this study, we developed the urban ecohydrology model (UEM) to investigate the role of bioretention on watershed water balance, runoff production, and streamflow variability. UEM partitions the land surface into pervious, impervious, and bioretention cell fractions. Soil moisture and vegetation dynamics are simulated in pervious areas and bioretention cells using a lumped ecohydrological approach. Bioretention cells receive runoff from a fraction of impervious areas. The model is calibrated in an urban headwater catchment near Seattle, WA, USA, using hourly weather data and streamflow observations for 3 years. The calibrated model is first used to investigate the relationship between streamflow variability and bioretention cell size that receives runoff from different values of impervious area in the watershed. Streamflow variability is quantified by 2 indices, high pulse count (HPC), which quantifies the number of flow high pulses in a water year above a threshold, and high pulse range (HPR), which defines the time over which the pulses occurred. Low values of these indices are associated with improved stream health. The effectiveness of the modelled bioretention facilities are measured by their influence on reducing HPC and HPR and on flow duration curves in comparison with modelled fully forested conditions. We used UEM to examine the effectiveness of bioretention cells under rainfall regimes that are wetter and drier than the study area in an effort to understand linkages between the degree of urbanization, climate, and design bioretention cell size to improve inferred stream health conditions. In all model simulations, limits to the reduction of HPC and HPR indicators were reached as the size of bioretention cells grew. Bioretention was more effective as the rainfall regime gets drier. Results may guide bioretention design practices and future studies to explore climate change impacts on bioretention design and management.     

The balance between microzooplankton grazing and phytoplankton growth in a highly productive estuarine fjord

During 24, three-day cruises to Dabob Bay, Washington State, USA, from February 4 to April 26, 2002, and February 4 to May 1 2003, we examined the relative growth and grazing rates of phytoplankton and microzooplankton using dilution experiments. Experiments were conducted over two time intervals: 8–10 h during the nighttime only, or 24 h from noon to noon. We used water from two depths during each cruise: from the surface mixed layer, and from a deep layer below the seasonal thermocline. During 2002, there was one mid-sized bloom consisting mainly of Thalassiosira spp. in early February, and a larger bloom in April comprised of two Chaetoceros spp. and Phaeocystis sp. During 2003, there were also two blooms, one in early February, which was again dominated by Thalassiosira spp., and a second larger bloom in mid-April, comprised mainly of Thalassiosira spp. and Chaetoceros spp. During all four of these blooms, and for both water source depths, specific grazing rates of microzooplankton were most often as high or higher than the calculated phytoplankton specific growth rates. The major microzooplankton categories that could have accounted for this were (1) a large Gyrodinium spp., (2) a group of fusiform-shaped mid-sized Protoperidinium species, and (3) three loosely defined taxonomic groups consisting of naked ciliates, tintinnids, and unidentified heterotrophic dinoflagellates. Based on our measurements, it appears that the microzooplankton community grazing pressure can often exert significant control on phytoplankton biomass, even during the extremely productive spring bloom periods and under several different diatom-dominated bloom types. These results suggest that even in highly productive estuarine ecosystems, which are often nurseries to economically important fisheries species, microzooplankton play a critical role and may significantly alter the availability and efficiency of transfer of energy to higher trophic levels.     

Constraints on the Formation Regions of Comets from their D:H Ratios

Studies of the D:H ratio in H₂O within the Solar nebula provide a relationship between the degree of enrichment of deuterium and the distance from the young Sun. In the context of cometary formation, such models suggest that comets which formed in different regions of the Solar nebula should have measurably different D:H ratios. We aim to illustrate how the observed comets can give information about the formation regions of the reservoirs in which they originated. After a discussion of the current understanding of the regions in which comets formed, simple models of plausible formation regions for two different cometary reservoirs (the Edgeworth–Kuiper belt and the Oort Cloud) are convolved with a deuterium-enrichment profile for the pre-solar nebula. This allows us to illustrate how different formation regions for these objects can lead to great variations in the deuterium enrichment distributions that we would observe in comets today. We also provide an illustrative example of how variations in the population within a source region can modify the resulting observational profile. The convolution of a deuterium-enrichment profile with examples of proto-cometary populations gives a feel for how observations could be used to draw conclusions on the formation region of comets which are currently fed into the inner Solar system from at least two reservoirs. Such observations have, to date, been carried out on only three comets, but future work with instruments such as ALMA and Herschel should vastly improve the dataset, leading to a clearer consensus on the formation of the Oort cloud and Edgeworth–Kuiper belt.