Molecular line mapping of the giant molecular cloud associated with RCW 106 – III. Multimolecular line mapping

We present multimolecular line maps obtained with the Mopra telescope towards the southern giant molecular cloud (GMC) complex G333, associated with the H  ii region RCW 106. We have characterized the GMC by decomposing the 3D data cubes with gaussclumps , and investigated spatial correlations among different molecules with principal component analysis (PCA). We find no correlation between clump size and linewidth, but a strong correlation between emission luminosity and linewidth. PCA classifies molecules into high- and low-density tracers, and reveals that HCO⁺ and N₂H⁺ are anticorrelated.     

Modelling the effects of fire and rainfall regimes on extreme erosion events in forested landscapes

Existing models of post-fire erosion have focused primarily on using empirical or deterministic approaches to predict the magnitude of response from catchments given some initial rainfall and burn conditions. These models are concerned with reducing uncertainties associated with hydro-geomorphic transfer processes and typically operate at event timescales. There have been relatively few attempts at modelling the stochastic interplay between fire disturbance and rainfall as factors which determine the frequency and severity with which catchments are conditioned (or primed) for a hazardous event. This process is sensitive to non-stationarity in fire and rainfall regime parameters and therefore suitable for evaluating the effects of climate change and strategic fire management on hydro-geomorphic hazards from burnt areas. In this paper we ask the question, “What is the first-order effect of climate change on the interaction between fire disturbance and storms?” The aim is to isolate the effects of fire and rainfall regimes on the frequency of extreme erosion events. Fire disturbance and storms are represented as independent stochastic processes with properties of spatial extent, temporal duration, and frequency of occurrence, and used in a germ–grain model to quantify the annual area affected by extreme erosion events due to the intersection of fire disturbance and storms. The model indicates that the frequency of extreme erosion events will increase as a result of climate change, although regions with frequent storms were most sensitive.     

Dissociation kinetics of Fe(III)- and Al(III)-natural organic matter complexes at pH 6.0 and 8.0 and 25 °C

The rate at which iron- and aluminium-natural organic matter (NOM) complexes dissociate plays a critical role in the transport of these elements given the readiness with which they hydrolyse and precipitate. Despite this, there have only been a few reliable studies on the dissociation kinetics of these complexes suggesting half-times of some hours for the dissociation of Fe(III) and Al(III) from a strongly binding component of NOM. First-order dissociation rate constants are re-evaluated here at pH 6.0 and 8.0 and 25 °C using both cation exchange resin and competing ligand methods for Fe(III) and a cation exchange resin method only for Al(III) complexes. Both methods provide similar results at a particular pH with a two-ligand model accounting satisfactorily for the dissociation kinetics results obtained. For Fe(III), half-times on the order of 6-7 h were obtained for dissociation of the strong component and 4-5 min for dissociation of the weak component. For aluminium, the half-times were on the order of 1.5 h and 1-2 min for the strong and weak components, respectively. Overall, Fe(III) complexes with NOM are more stable than analogous complexes with Al(III), implying Fe(III) may be transported further from its source upon dilution and dispersion.     

Core-mantle interactions

Several aspects of core-mantle interactions were considered during a Royal Astronomical Society Discussion Meeting on 12th May 1989, including modelling the geomagnetic field at the core surface, the morphology of the field between 1600 and 1820 AD, dynamo theory, Taylor's constraint, fluid motions at the top of the core that reproduce the observed secular variation, pressure coupling between the core and mantle and its geophysical consequences, topographic core-mantle coupling, angular momentum transfer at the core-mantle interface, the detection and implications of core oscillations, particularly those with associated fluctuations in the Earth's rotation rate, and the seismological determination of the core-mantle boundary topography from lateral inhomogeneities in the mantle.     

Geochemical characteristics of lavas from Broken Ridge, the Naturaliste Plateau and southernmost Kerguelen Plateau: Cretaceous plateau volcanism in the southeast Indian Ocean

Lavas from several major bathymetric highs in the eastern Indian Ocean that are likely to have formed as Early to Middle Cretaceous manifestations of the Kerguelen hotspot are predominantly tholeiitic; so too are glass shards from Eocene to Paleocene volcanic ash layers on Broken Ridge, which are believed to have come from eruptions on the Ninetyeast Ridge. The early dominance of tholeiitic compositions contrasts with the more recent intraplate, alkalic volcanism of the Kerguelen Archipelago. Isotopic and incompatible-element ratios of the plateau lavas are distinct from those of Indian mid-ocean ridge basalts; their Nd, Sr, ²⁰⁷Pb/²⁰⁴Pb and isotopic ratios overlap with but cover a much wider range than measured for more recent oceanic products of the Kerguelen hotspot (including the Ninetyeast Ridge) or, indeed, oceanic lavas from any other hotspot in the world. Samples from the Naturaliste Plateau and ODP Site 738 on the southern tip of the Kerguelen Plateau are particularly noteworthy, with ε_Nd(T) = − 13 to −7, (⁸⁷Sr/⁸⁶Sr)_T=0.7090 to 0.7130 and high ²⁰⁷Pb/²⁰⁴Pb relative to ²⁰⁶Pb/²⁰⁴Pb. In addition, the low-ε_Nd(T) Naturaliste Plateau samples are elevated in SiO₂ (> 54 wt%). In contrast to “DUPAL” oceanic islands such as the Kerguelen Archipelago, Pitcairn and Tristan da Cunha, the plateau lavas with extreme isotopic characteristics also have relative depletions in Nb and Ta (e.g., Th/Ta, La Nb > primitive mantle values); the lowest ε_Nd(T) and highest Th/Ta and La Nb values occur at sites located closest to rifted continental margins. Accepting a Kerguelen plume origin for the plateau lavas, these characteristics probably reflect the shallow-level incorporation of continental lithosphere in either the head of the early Kerguelen plume or in plume-derived magmas, and suggest that the influence of such material diminished after the period of plateau construction. Contamination of asthenosphere with the type of material affecting Naturaliste Plateau and Site 738 magmatism appears unlikely to be the cause of low-²⁰⁶Pb/⁰⁴Pb Indian mid-ocean ridge basalts. Finally, because isotopic data for the plateaus do not cluster or form converging arrays in isotope-ratio plots, they provide no evidence for either a quickly evolving, positive ε_Nd, relatively high-²⁰⁶Pb/²⁰⁴Pb plume composition, or a plume source dominated by mantle with ε_Nd of −3 to 0.     

How do Local People Value Rural Waterways? A Study in the Upper Catchments of South East Queensland’s Rivers

In Integrated Catchment (or Watershed) Management, the impacts of upstream conditions and actions on downstream environments and people is a key issue. Knowing upstream people’s values towards waterways is, therefore, important for community engagement and the development of publicly acceptable management approaches. This qualitative study applies Kellert’s framework of relational values to explore the types and diversity of people’s values towards the upper catchments of South East Queensland, Australia, and tests the “universality” of Kellert’s framework. We found the full range of values identified by Kellert with some variations and elaborations in content. People living, working, and enjoying recreation in the upper catchments have affection for their local waterways and a moral inclination to protect them. This extends our understanding of how people value these waterways, which is more often depicted in terms of utilitarian and economic value. The findings provide managers with new opportunities for engaging with local communities and waterway users.     

Mineral species control of aluminum solubility in sulfate-rich acidic waters

The identification of the mineral species controlling the solubility of Al in acidic waters rich in sulfate has presented researchers with several challenges. One of the particular challenges is that the mineral species may be amorphous by X-ray diffraction. The difficulty in discerning between adsorbed or structural sulfate is a further complication. Numerous studies have employed theoretical calculations to determine the Al mineral species forming in acid sulfate soil environments. The vast majority of these studies indicate the formation of a mineral species matching the stoichiometry of jurbanite, Al(OH)SO₄·5H₂O. Much debate, however, exists as to the reality of jurbanite forming in natural environments, particularly in view of its apparent rare occurrence. In this work the use of Al, S and O K-edge XANES spectroscopy, in combination with elemental composition analyses of groundwater precipitates and a theoretical analysis of soluble Al concentrations ranging from pH 3.5 to 7, were employed to determine the mineral species controlling the solubility of Al draining from acid sulfate soils into Blacks Drain in north-eastern New South Wales, Australia. The results indicate that a mixture of amorphous Al hydroxide (Al(OH)₃) and basaluminite (Al₄(SO₄)(OH)₁₀·5H₂O) was forming. The use of XANES spectroscopy is particularly useful as it provides insight into the nature of the bond between sulfate and Al, and confirms the presence of basaluminite. This counters the possibility that an Al hydroxide species, with appreciable amounts of adsorbed sulfate, is forming within these groundwaters.Below approximately pH 4.5, prior to precipitation of this amorphous Al(OH)₃/basaluminite mixture, our studies indicate that the Al³⁺ activity of these acidic sulfate-rich waters is limited by the availability of dissolved Al from exchangeable and amorphous/poorly crystalline mineral species within adjacent soils. Further evidence suggests the Al³⁺ activity below pH 4.5 is then further controlled by dilution with either rainwater or pH 6-8 buffered estuarine water, and not a notional Al(OH)SO₄ mineral species.     

Contrasting sedimentation rates in Lake Illawarra and St Georges Basin,two large barrier estuaries on the southeast coast of Australia

Sedimentation rates over the last 100 years within two lagoons on the southeast coast of Australia, Lake Illawarra and St Georges Basin, have been quantified to determine the effects of catchment land use change and native vegetation clearance on infill rates, and spatial variations in the rate at which the estuaries have filled. Both catchments have similar lake and catchment area but have experience different degrees of modification due to land clearing for agriculture practices, urbanisation and industrialisation. Results indicate that in the heavily modified catchment of Lake Illawarra sedimentation rates close to fluvial deltas can be in excess of 16 mm/year, and between 2 and 4 mm/year in the adjacent central basin. This is approximately an order of magnitude greater than the pre-European rates. In contrast, at St Georges Basin, where the catchment has experienced much less modification, sedimentation rates in the central basin appear to have remained close to those prior to European settlement. However, sedimentation rates in the urbanized margin of St Georges Basin are relatively high (up to 4.4 mm/year). This rapid modern sedimentation in the margin of the estuarine embayments has been detected in several other estuaries in the region. However the degree of sedimentation within the bay-head deltas, and more significantly in the central basin appears proportional to the degree clearance of native vegetation (forest) in the catchment, urban expansion and development of heavy industry in the respective catchment areas.     

Schwertmannite stability in acidified coastal environments

A combination of analytical and field measurements has been used to probe the speciation and cycling of iron in coastal lowland acid sulfate soils. Iron K-edge EXAFS spectroscopy demonstrated that schwertmannite dominated (43-77%) secondary iron mineralization throughout the oxidized and acidified soil profile, while pyrite and illite were the major iron-bearing minerals in the reduced potential acid sulfate soil layers. Analyses of contemporary precipitates from shallow acid sulfate soil groundwaters indicated that 2-line ferrihydrite, in addition to schwertmannite, is presently controlling secondary Fe(III) mineralization. Although aqueous pH values and concentrations of Fe(II) were seasonally high, no evidence was obtained for the Fe(II)-catalyzed crystallization of either mineral to goethite. The results of this study indicate that: (a) schwertmannite is likely to persist in coastal lowland acid sulfate soils on a much longer time-scale than predicted by laboratory experiments; (b) this mineral is less reactive in these types of soils due to surface-site coverage by components such as silicate and possibly, to a lesser extent, natural organic matter and phosphate and; (c) active water table management to promote oxic/anoxic cycles around the Fe(II)-Fe(III) redox couple, or reflooding of these soils, will be ineffective in promoting the Fe(II)-catalyzed transformation of either schwertmannite or 2-line ferrihydrite to crystalline iron oxyhydroxides.