Spatial and temporal variability in the concentration and speciation of metals in suspended sediment transported by the River Aire,Yorkshire, UK

In recent years, there has been an increasing awareness of the important role of fine sediment in the transport and storage of metals in fluvial systems. However, there has been little research on the behaviour of contaminated sediment in industrial rivers in the UK. This paper examines spatial and temporal variations in the concentration and speciation of lead, copper and chromium associated with suspended sediment in the River Aire in Yorkshire, UK. An increase in the total concentration of all three metals in sediment was identified in the lower reaches, which reflected inputs of road dust, sewage and industrial effluents. Spatial variations in the chemical speciation of the metals were also identified. The iron–manganese oxides and organic fractions were the most significant for the adsorption of metals by sediment. Both the concentrations and speciation of sediment‐associated metals exhibited substantial temporal variation. Such variation reflected the accumulation of metals and organic matter on the river‐bed during low flows, the subsequent remobilization of the sediment at high flows and the additional supply of sediment from uncontaminated and contaminated sources, including pulse inputs of road dust, sewage and industrial effluent. The findings presented have important implications for the development of effective catchment management strategies for the control of point‐ and diffuse‐source pollution. Copyright © 2006 John Wiley & Sons, Ltd.     

Ion escape at Mars: Comparison of a 3-D hybrid simulation with Mars Express IMA/ASPERA-3 measurements

We have analysed ion escape at Mars by comparing ASPERA-3/Mars Express ion measurements and a 3-D quasi-neutral hybrid model. As Mars Express does not have a magnetometer onboard, the analysed IMA data are from an orbit when the IMF clock angle was possible to determine from the magnetic field measurements of Mars Global Surveyor. We found that fast escaping planetary ions were observed at the place which, according to the 3-D model, is anticipated to contain accelerated heavy ions originating from the martian ionosphere. The direction of the interplanetary magnetic field was found to affect noticeably which regions can be magnetically connected to Mars Express and to the overall 3-D Mars-solar wind interaction.     

The analysis of finite elasto-plastic consolidation

A theoretical formulation and a numerical solution method are proposed for the problem of the time dependent consolidation of an elasto-plastic soil subject to finite deformations. The soil is assumed to be a two-phase material with a skeleton which may yield according to a general yield criterion with plastic flow governed by a general flow law, and whose pore fluid flows according to Darcy's Law. Governing equations are cast in a rate form and constitutive laws are expressed in a frame indifferent manner. The method of analysis is illustrated by several examples of practical interest for both a soil with an elastic skeleton and a soil with an elasto-plastic skeleton which obeys a Morh–Coulomb yield criterion and a non-associated flow law.     

Large-amplitude variables near the Galactic Centre

We report here the results of a 4-yr K -band (2.2 μm) survey for large-amplitude variable stars in a     area centred on the Galactic Centre. A total of 409 likely long-period variables (LPVs) were detected, for which positions, amplitudes, average magnitudes and periods were obtained whenever possible. The surface density of LPVs is more than ten times greater than in the Sgr I Baade window at        
The limits of completeness arising from interstellar and circumstellar absorption are discussed. Most of the area suffers interstellar extinction of     The shorter-period LPVs are less luminous than the longer-period ones and may be slightly under-represented in the data. Extremely heavy extinction     which affects the probability of detecting variables, occurs in less than 25 per cent of the area.
Almost all of the LPVs are Miras or OH/IR stars, with periods ranging from 150 d to about 800 d. K -band counterparts have been found for 59 per cent of the 109 known OH sources in the field. The average period of the variables found is 427 d, while that of the OH/IR stars is 524 d. For comparison, the average period in the Sgr I window, which contains no known OH/IR stars, is 333 d and only two stars are detected with     The survey field also contains a number of long-period, large-amplitude variables that are not OH emitters.     

A Bayesian statistical assessment of representative samples for asteroidal or meteoritical material

Primitive substances in asteroid and meteorite materials represent a record of early solar system evolution. To allow the study of these materials, they must be collected and transferred to the laboratory. Collection during sample return missions requires an assessment of the size of samples needed. Meteorite falls or finds must be subdivided into appropriate subsamples for analysis by successive generations of scientists. It is essential, therefore, to determine a representative mass or volume at which the collected or allocated sample is representative of the whole. For the first time, we have used a Bayesian statistical approach and a selected meteorite sample, Murchison, to identify a recommended smallest sample mass that can be used without interferences from sampling bias. Enhancing background knowledge to inform sample selection and analysis is an effective means of increasing the probability of obtaining a positive scientific outcome. The influence of the subdivision mechanism when preparing samples for distribution has also been examined. Assuming a similar size distribution of fragments to that of the Murchison meteorite, cubes can be similarly representative as fragments, but at orders of magnitude smaller sizes. We find that: (1) at all defined probabilities (90%, 95%, and 99%), nanometer‐sized particles (where the axes of a three‐dimensional sample are less that a nanometer in length) are never representative of the whole; (2) at the intermediate and highest defined probabilities (95% and 99%), micrometer‐sized particles are never representative of the whole; and (3) for micrometer‐sized samples, the only sample that is representative of the whole is a cube and then only at a 90% probability. The difference between cubes and fragments becomes less important as sample size increases and any >0.5 mm‐sized sample will be representative of the whole with a probability of 99.9%. The results provide guidance for sample return mission planners and curators or advisory boards that must distribute valuable samples for analysis.     

The Chandrayaan-1 X-ray Spectrometer: First results

We present X-ray fluorescence observations of the lunar surface, made by the Chandrayaan-1 X-ray Spectrometer during two solar flare events early in the mission (12th December 2008 and 10th January 2009). Modelling of the X-ray spectra with an abundance algorithm allows quantitative estimates of the MgO/SiO₂ and Al₂O₃/SiO₂ ratios to be made for the two regions, which are in mainly basaltic areas of the lunar nearside. One of these ground tracks includes the Apollo 14 landing site on the Fra Mauro Formation. Within the 1σ errors provided, the results are inside the range of basaltic samples from the Apollo and Luna collections. The Apollo 14 soil composition is in agreement with the results from the January flare at the 1σ uncertainty level. Discrepancies are observed between our results and compositions derived for the same areas by the Lunar Prospector gamma-ray spectrometer; some possible reasons for this are discussed.     

Characterization of hydrated silicate-bearing outcrops in Tyrrhena Terra,Mars: Implications to the alteration history of Mars

The Tyrrhena Terra region of Mars is studied with the imaging spectrometers OMEGA (Observatoire pour la Minéralogie, l’Eau, les Glaces et l’Activité) onboard Mars Express and CRISM (Compact Reconnaissance Infrared Spectrometer for Mars) onboard Mars Reconnaissance Orbiter, through the observation of tens of craters that impacted into this part of the martian highlands. The 175 detections of hydrated silicates are reported, mainly associated with ejecta blankets, crater walls and rims, and central up-lifts. Sizes of craters where hydrated silicates are detected are highly variable, diameters range from less than 1 km to 42 km. We report the presence of zeolites and phyllosilicates like prehnite, Mg-chlorite, Mg-rich smectites and mixed-layer chlorites–smectites and chlorite–vermiculite from comparison of hyperspectral infrared observations with laboratory spectra. These minerals are associated with fresh craters post-dating any aqueous activity. They likely represent ancient hydrated terrains excavated by the crater-forming impacts, and hence reveal the composition of the altered Noachian crust, although crater-related hydrothermal activity may have played a minor role for the largest craters (>20 km in diameter). Most detected minerals formed over relatively high temperatures (100–300 °C), likely due to aqueous alteration of the Noachian crust by regional low grade metamorphism from the Noachian thermal gradient and/or by extended hydrothermal systems associated with Noachian volcanism and ancient large impact craters. This is in contrast with some other phyllosilicate-bearing regions like Mawrth Vallis where smectites, kaolinites and hydrated silica were mainly identified, pointing to a predominance of surface/shallow sub-surface alteration; and where excavation by impacts played only a minor role. Smooth plains containing hydrated silicates are observed at the boundary between the Noachian altered crust, dissected by fluvial valleys, and the Hesperian unaltered volcanic plains. These plains may correspond to alluvial deposition of eroded material. The highlands of Tyrrhena Terra are therefore particularly well suited for investigating the diversity of hydrated minerals in ancient martian terrains.     

Geography,Race, and Quantification

This article reviews how race, quantification, and raced quantification have been used and written about in geography. Its two primary arguments are that race should be more central in the discipline and that a reluctance to address ontological and epistemological issues has left quantitative geography methodologically impoverished. These two issues merge in an examination of two cases where race is employed as a variable in quantitative models. The critique of these cases is not meant as a condemnation of quantitative geography but as an instructive example on which to construct a critical quantitative geography. The article ends by stressing the importance of quantification in geography and by presenting exemplars of race-critical quantification.     

Comparative Evaluation of Single‐Well LNAPL Tracer Testing at Five Sites

Light nonaqueous phase liquid (LNAPL) tracer testing is a technique used to directly measure LNAPL flow in situ and evaluate LNAPL mobility and recoverability. The test method consists of adding a fluorescent oil‐soluble tracer to LNAPL within a well, isolating small volumes of LNAPL with known tracer concentrations for use as in‐well calibration standards, and measuring the rate of tracer concentration decline in the well over time. The test measures LNAPL flux through the well, which is directly related to LNAPL mobility and recoverability in the surrounding formation. Test results for a total of 29 wells at five sites are presented. Results from LNAPL tracer testing were comparable to results obtained through other methods, and the method offers a time‐averaged result measured over a relatively long period, in ambient conditions, and reflects the influences of heterogeneity and hydraulic changes. In some cases, tracer concentration decline followed unexpected patterns, and these data have led to a better understanding of test assumptions, mechanisms influencing tracer distribution, and options to improve test execution and data interpretation. Method improvements developed over the course of the field studies included refinement of pre‐test screening of LNAPL fluorescence and improvements to measurement equipment. Overall, the field studies confirmed the technical validity and usefulness of the LNAPL tracing technique to support LNAPL mobility and recoverability assessments.     

The influence of a season of extreme wet weather events on exposure of the World Heritage Area Great Barrier Reef to pesticides

The 2010-2011 wet season was one of extreme weather for the State of Queensland, Australia. Major rivers adjacent to the Great Barrier Reef (GBR) were discharging at rates 1.5 to >3 times higher than their long term median. Exposure to photosystem II herbicides has been routinely monitored over a period of up to 5 years at 12 inshore GBR sites. The influence of this wet season on exposure to photosystem II herbicides was examined in the context of this long-term monitoring record and during flood plume events in specific regions. Median exposures expressed as diuron equivalent concentration were an average factor of 2.3 times higher but mostly not significantly different (p<0.05) to the median for the long-term monitoring record. The herbicides metolachlor and tebuthiuron were frequently detected in flood plume waters at concentrations that reached or exceeded relevant water quality guidelines (by up to 4.5 times).