Enrichment pattern of leachable trace metals in roadside soils of Miri City,Eastern Malaysia

This article presents the results on distribution and enrichment pattern of acid-leachable trace metals (ALTMs) from roadside soil of Miri city, Sarawak, East Malaysia. The city is one of the fastest developing in the Malaysian region with huge petroleum resources. ALTMs Fe, Mn, Cr, Cu, Ni, Co, Pb, Zn and Cd along with organic carbon and carbonates (CaCO₃) were analyzed in 37 soil sediments collected from roadside. The enrichment of ALTMs [especially Cu (0.4–13.1 μg g^?1), Zn (9.3–70.7 μg g^?1), Pb (13.8–99.1 μg g^?1)] in the roadside soils indicate that these metals are mainly derived from sources related to traffic exhausts, forest fires and oil refineries. The comparative study and enrichment pattern of elements indicates that Mn, Cu, Zn and Pb are enriched multi-fold than the unpolluted soil and Ni, Pb, Cd in some samples compared to Sediment Quality Guidelines like Lowest Effect Level (LEL) and Effects Range Low (ERL) in the region which is mainly due to the recent industrial developments in the region.     

Ethnic enterprises and community development

Ethnic enterprises are growing rapidly in urban areas across the United States. Anecdotal evidence from around the country reports many success stories of how ethnic businesses transform communities; however, researchers have not provided a systematic review of the role of ethnic businesses in community developing. In practice, ethnic businesses have not been formally incorporated in local planning and development process. This article provides a systematic review of the multi-faceted ways ethnic businesses contribute to community building and neighborhood development. In addition to surveying the current literature, we also chose three communities for a focused review: Buford Highway in Atlanta, Monterey Park in Los Angeles, and Sunset Park in New York. A framework is developed to evaluate the economic, physical, social/cultural, and political effects that ethnic businesses exert on communities. We find that ethnic businesses can serve local economic interests and community-level cohesion and accrue economic, social, physical, and political benefits to their respective communities. These include serving the unmet market needs of certain neighborhoods and households, creating job opportunities and generating revenues, revitalizing and fueling the commercial development of abandoned communities, organizing and promoting social life and cultural diversity, as well as contributing their collective interest and voice in local communities. We argue that ethnic businesses should be better incorporated into urban policies in community economic development.     

Floodgate Operations and Fish Communities in Tidal Creeks of the Lower Fraser River (British Columbia,Canada)

Tidal creeks in large coastal deltas can be important habitat for fish but are often highly modified by human activities. Connectivity between tributary creeks and mainstem channels is often constrained by structures such as dikes and floodgates, designed to protect urban and agricultural areas from flooding. While they play important roles in flood mitigation, floodgates can diminish habitat quality and block fish from accessing tidal creeks. It is likely that floodgates differ in their operations and may consequently open for different amounts of time; however, floodgate operations and their effects are not well quantified. We asked the question: how does the mechanical functioning of these floodgates affect fish communities in tidal creeks? We used time-lapse cameras and quantified the timing of gate openings for 22 tributaries of the Lower Fraser River in British Columbia, Canada, and related these operational data to differences in fish communities above and below floodgates. Floodgate operations varied substantially, with some floodgates opening daily while others opened less than 20% of the day, on average. Sites with floodgates that seldom opened were associated with greater differences in fish communities and with reduced upstream native species richness by about one species on average. Where floodgates opened infrequently, we also found lower upstream dissolved oxygen concentrations than at sites where floodgates opened for longer periods of time. Thus, floodgate operations can influence fish communities as well as water quality. These data indicate a large scope for improving floodgate operations for connectivity.     

Coastal erosion vs man-made protective structures: evaluating a two-decade history from southeastern India

Remote sensing images of AD 1991–2011 and field observations help evaluate shoreline changes (erosion and accretion) in Puducherry and Tamil Nadu states of southeastern India. A minor harbor was constructed during AD 1986–1989 in the coast of Puducherry, and it initiated the gradual process of shoreline modification. In the subsequent years, beaches located toward the north of the harbor suffered erosion (?0.12–?4.19 m/year) and there was accretion (0.27–7.25 m/year) in the southern beaches. However, the man-made structures (seawall and groin) have reduced the shoreline changes after AD 2004. In the last two decades, the rate of erosion area-wise gradually decreased (0.24–0.013 km²/year) and accretion remained constant (0.019 km²/year). Our results suggest that accretion happened in the southern side of the breakwaters and erosion occurred in the northern part. Presence of groins structures in the region in the northern part has also provoked accretion in the south and erosion in the northern side close to the State of Tamil Nadu.

     

Sphene and zircon in the Highland Range volcanic sequence (Miocene, southern Nevada, USA): elemental partitioning, phase relations, and influence on evolution of silicic magma

Sphene is prominent in Miocene plutonic rocks ranging from diorite to granite in southern Nevada, USA, but it is restricted to rhyolites in coeval volcanic sequences. In the Highland Range volcanic sequence, sphene appears as a phenocryst only in the most evolved rocks (72?C77 mass% SiO₂; matrix glass 77?C78 mass% SiO₂). Zr-in-sphene temperatures of crystallization are mostly restricted to 715 and 755°C, in contrast to zircon (710?C920°C, Ti-in-zircon thermometry). Sphene rim/glass Kds for rare earth elements are extremely high (La 120, Sm 1200, Gd 1300, Lu 240). Rare earth elements, especially the middle REE (MREE), decrease from centers to rims of sphene phenocrysts along with Zr, demonstrating the effect of progressive sphene fractionation. Whole rocks and glasses have MREE-depleted, U-shaped REE patterns as a consequence of sphene fractionation. Within the co-genetic, sphene-rich Searchlight pluton, only evolved leucogranites show comparable MREE depletion. These results indicate that sphene saturation in intruded and extruded magmas occurred only in highly evolved melts: abundant sphene in less silicic plutonic rocks represents a late-stage ??bloom?? in fractionated interstitial melt.     

Lithic fragments,glasses and chondrules from Luna 16 fines

Bulk compositions of igneous and microbreccia lithic fragments, glasses, and chondrules from Luna 16 fines as well as compositions of minerals in basaltic lithic fragments were determined with the electron microprobe. Igneous lithic fragments and glasses are divided into two groups, the anorthositic-noritic-troctolitic (hereafter referred to as ANT) and basaltic groups. Chondrules are always of ANT composition and microbreccia lithic fragments are divided into groups 1 and 2. The conclusions reached may be summarized as follows: (1) Luna 16 fines are more similar in composition to Apollo 11 than to Apollo 12 and 14 materials (e.g. Apollo 11 igneous lithic fragments and glasses fall into similar ANT and basaltic groups; abundant norites in Luna 16 and Apollo 11 are not KREEP as in Apollo 12 and 14; Luna 16 basaltic lithic fragments may represent high-K and low-K suites as is the case for Apollo 11; rare colorless to greenish, FeO-rich and TiO₂-poor glasses were found in both Apollo 11 and Luna 16; Luna 16 spinels are similar to Apollo 11 spinels but unlike those from Apollo 12). (2) No difference was noted in the composition of lithic fragments, glasses and chondrules from Luna 16 core tube layers A and D. (3) Microbreccia lithic fragments of group 1 originated locally by mixing of high proportions of basaltic with small proportions of ANT materials. (4) Glasses are the compositional analogs to the lithic fragments and not to the microbreccias; most glasses were produced directly from igneous rocks. (5) Glasses show partial loss of Na and K due to vaporization in the vitrification process. (6) Luna 16 chondrules have ANT but not basaltic composition. It is suggested that either liquid droplets of ANT composition are more apt to nucleate from the supercooled state; or basaltic droplets have largely been formed in small and ANT droplets in large impact events (in the latter case, probability for homogeneous and inhomogeneous nucleation is larger. (7) No evidence for ferric iron and water-bearing minerals was found. (8) Occurrence of a great variety of igneous rocks in Luna 16 samples (anorthosite, noritic anorthosite, anorthositic norite, olivine norite, troctolite, and basalt) confirm our earlier conclusion that large-scale melting or partial melting to considerable depth and extensive igneous differentiation must have occurred on the moon.     

Trace element zoning in pyroxenes from ODP Hole 735B gabbros: diffusive exchange or synkinematic crystal fractionation?

Major and trace element profiles of clinopyroxene grains in oceanic gabbros from ODP Hole 735B have been investigated by a combined in situ analytical study with ion probe, and electron microprobe. In contrast to the homogeneous major element compositions, trace elements (REE, Y, Cr, Sr, and Zr) show continuous core to rim zoning profiles. The observed trace element systematics in clinopyroxene cannot be explained by a simple diffusive exchange between melts and gabbros along grain boundaries. A simultaneous modification of the melt composition is required to generate the zoning, although Rayleigh fractional crystallization modelling could mimic the general shape of the profiles. Simultaneous metasomatism between the cumulate crystal and the porous melt during crystal accumulation is the most likely process to explain the zoning. Deformation during solidification of the crystal mush could have caused squeezing out of the incompatible element enriched residual melts (interstitial liquid). Migration of the melt along grain boundaries might carry these melt out of the system. This process named as synkinematic differentiation or differentiation by deformation (Natland and Dick in J Volcanol Geotherm Res 110(3–4):191–233, 2001) may act as an important magma evolution mechanism in the oceanic crust, at least at slow-spreading ridges.     

Characterization of uranium-contaminated sediments from beneath a nuclear waste storage tank from Hanford, Washington: Implications for contaminant transport and fate

The concentration and distribution of uranium (U) in sediment samples from three boreholes recovered near radioactive waste storage tanks at Hanford, Washington, USA, were determined in detail using bulk and micro-analytical techniques. The source of contamination was a plume that contained an estimated 7000 kg of dissolved U that seeped into the subsurface as a result of an accident that occurred during filling of tank BX-102. The desorption character and kinetics of U were also determined by experiment in order to assess the mobility of U in the vadose zone. Most samples contained too little moisture to obtain quantitative information on pore water compositions. Concentrations of U (and contaminant phosphate—P) in pore waters were therefore estimated by performing 1:1 sediment-to-water extractions and the data indicated concentrations of these elements were above that of uncontaminated “background” sediments. Further extraction of U by 8 N nitric acid indicated that a significant fraction of the total U is relatively immobile and may be sequestered in mobilization-resistant phases. Fine- and coarse-grained samples in sharp contact with one another were sub-sampled for further scrutiny and identification of U reservoirs. Segregation of the samples into their constituent size fractions coupled with microwave-assisted digestion of bulk samples showed that most of the U contamination was sequestered within the fine-grained fraction. Isotope exchange (²³³U) tests revealed that ∼51% to 63% of the U is labile, indicating that the remaining fund of U is locked up in mobilization-resistant phases. Analysis by Micro-X-ray Fluorescence and Micro-X-ray Absorption Near-Edge Spectroscopy (μ-XRF and μ-XANES) showed that U is primarily associated with Ca and is predominately U(VI). The spectra obtained on U-enriched “hot spots” using Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLIFS) provide strong evidence for uranophane-type [Ca(UO₂)₂(SiO₃OH)₂(H₂O)₅] and uranyl phosphate [Ca(UO₂)₂(PO₄)₂(H₂O)_10-12] phases. These data show that disseminated micro-precipitates can form in narrow pore spaces within the finer-grained matrix and that these objects are likely not restricted to lithic fragment environments. Uranium mobility may therefore be curtailed by precipitation of uranyl silicate and phosphate phases, with additional possible influence exerted by capillary barriers. Consequently, equilibrium-based desorption models that predict the concentrations and mobility of U in the subsurface matrix at Hanford are unnecessarily conservative.     

Methodological problems of intercultural comparisons of retail environments

The internationalising activities of retailers have tended to precede the theoretical contributions of academics. This is particularly the case for the cultural context within which retail internationalisation takes place. Following an examination of the growth of international retailing activity, the article reviews generic difficulties in studying inter-cultural differences before considering the specific steps which retail practitioners have taken to understand the comparative characteristics of retail and consumer markets through the growth of geodemographic and lifestyle analysis. Finally, we relate one of the most significant integrative intercultural theoretical instruments to the case of retail internationalisation within Western Europe. We find that significant insights into retailer behaviour and strategy can be gained from an understanding of the culturally-specific characteristics of the activity. This revised version was published online in July 2006 with corrections to the Cover Date.     

Tropical cyclone activity and western North Atlantic stratification over the last millennium: a comparative review with viable connections

Tropical cyclones (TC) are recognized to modify the thermal structure of the upper ocean through the process of vertical mixing. Assessing the role this mixing plays in the overall stratification of the upper ocean is difficult, due to the relatively short and incomplete instrumental record. Proxy records for both TC landfalls and oceanographic stratification are preserved within the geological record and provide insight for how past changes in TC‐induced mixing have potentially affected water column structure prior to the instrumental record. Here we provide the first comparison between previously published paleo‐reconstructions of vertical ocean density and tropical cyclone activity from the western North Atlantic. A prominent lull in TC activity has been observed prior to approximately 1700 CE that extends back several centuries. This interval of low TC activity is shown to be concurrent with the timing of increased ocean stratification near Great Bahama Bank, potentially due in part to reduced TC‐induced mixing. To test whether this relationship is feasible, we present numerical results from a coarse‐resolution ocean general circulation model experiment isolating the effect of TC surface wind forcing on the upper ocean. An anomaly of roughly 0.12 kg m^?3 in vertical stratification occurs above and below the mixed layer for model runs with and without TC mixing. This anomaly is roughly 25% of the entire paleo‐density signal observed just prior to 1700 CE. These results suggest that TC mixing alone cannot completely explain the density anomaly observed prior to 1700 CE, but support TC variability as an important contributor to enhancing oceanic stratification during this interval. Copyright © 2011 John Wiley & Sons, Ltd.