Characteristics of the hepatic microsomal cytochrome P-450 system of the minke whale (Balaenoptera acutorostrata)

The whales are an interesting group in several aspects of science, including evolutionary biology, marine ecology and toxicology. Some of the whale species, including the minke whale, graze at the top of the food chains, where they become susceptible to the accumulation of marine pollutants ingested by organisms at lower levels. The northern stock of the minke whale grazes in Arctic waters in the summer, an area of increasing interest in the development of new oil fields. Studies on the metabolism, disposition and effects of xenobiotics in marine mammals are few. The only reports in the open literature so far have dealt with these questions in seals.^1–3 Although the marine mammals comprise a particularly interesting group in marine ecology and toxicology, no data have to our knowledge been presented on the xenobiotic metabolising enzyme systems of the whales. In this study, components of the microsomal cytochrome P-450 system were measured in liver samples from several females, one male, and two foetal minke whales, caught in the Norwegian whaling season of 1983. Because of the limited number of samples studied we have treated the samples individually and not performed any statistical analysis of the data. The trends discussed below must therefore be considered with this background.     

Decadal‐scale change of infiltration characteristics of a tephra‐mantled hillslope at Mount St Helens,Washington

The cataclysmic 1980 eruption of Mount St Helens radically reduced the infiltration characteristics of ∼60 000 ha of rugged terrain and dramatically altered landscape hydrology. Two decades of erosional, biogenic, cryogenic, and anthropogenic activity have modified the infiltration characteristics of much of that devastated landscape and modulated the hydrological impact of the eruption. We assessed infiltration and runoff characteristics of a segment of hillslope thickly mantled with tephra, but now revegetated primarily with grasses and other plants, to evaluate hydrological modifications due to erosion and natural turbation. Eruptive disturbance reduced infiltration capacity of the hillslope by as much as 50‐fold. Between 1980 and 2000, apparent infiltration capacities of plots on the hillslope increased as much as ten fold, but remain approximately three to five times less than the probable pre‐eruption capacities. Common regional rainfall intensities and snowmelt rates presently produce little surface runoff; however, high‐magnitude, low‐frequency storms and unusually rapid snowmelt can still induce broad infiltration‐excess overland flow. After 20 years, erosion and natural mechanical turbation have modulated, but not effaced, the hydrological perturbation caused by the cataclysmic eruption. Copyright © 2005 John Wiley & Sons, Ltd.     

激光剥蚀-等离子体质谱技术及其在地球化学宇宙化学和环境研究中的应用

激光剥蚀-等离子体质谱(LA-ICPMS)已成为地球化学、宇宙化学和环境研究领域元素和同位素原位分析最重要的技术之一。文章介绍了多种类型的质谱仪及其使用的激光器。用途最广的LA-ICPMS仪器之一是单接收器扇形磁场质谱仪,配有Nd:YAG激光剥蚀系统(激光波长分为193 nm和213 nm两种),MPI Mainz实验室使用的就是这套系统,文章对此作一详细介绍。文中阐述了数据优化技术及其多种校正过程;介绍LA-ICPMS在痕量元素和同位素分析领域的一些应用,包括参考物质的研制,Hawaiian玄武岩、Martian陨石、生物骨针和珊瑚虫中痕量元素分析及熔融包裹体和富钙-铝碳质球粒陨石中的铅和锶同位素测量。     

Palaeoglaciation of Bayan Har Shan,northeastern Tibetan Plateau: glacial geology indicates maximum extents limited to ice cap and ice field scales

Key locations within an extensive area of the northeastern Tibetan Plateau, centred on Bayan Har Shan, have been mapped to distinguish glacial from non‐glacial deposits. Prior work suggests palaeo‐glaciers ranging from valley glaciers and local ice caps in the highest mountains to a regional or even plateau‐scale ice sheet. New field data show that glacial deposits are abundant in high mountain areas in association with large‐scale glacial landforms. In addition, glacial deposits are present in several locations outside areas with distinct glacial erosional landforms, indicating that the most extensive palaeo‐glaciers had little geomorphological impact on the landscape towards their margins. The glacial geological record does indicate extensive maximum glaciation, with local ice caps covering entire elevated mountain areas. However, absence of glacial traces in intervening lower‐lying plateau areas suggests that local ice caps did not merge to form a regional ice sheet on the northeastern Tibetan Plateau around Bayan Har Shan. No evidence exists for past ice sheet glaciation. Copyright © 2009 John Wiley & Sons, Ltd.     

Numerical studies of wind forced internal waves with a nonhydrostatic model

The nonhydrostatic pressure effects on the generation and propagation of wind-forced internal waves are studied with a two-dimensional numerical ocean model. A one-way directed wind pulse over a stratified ocean initiates surface and internal waves in a closed basin. The studies are performed with horizontal grid sizes in the range from 1 km to 62.5 m. The experiments are performed with both a hydrostatic and a nonhydrostatic model, facilitating systematic studies of the sensitivity of the numerical model results to the grid size and to the nonhydrostatic pressure adjustments. The results show that the nonhydrostatic pressure effects are highly dependent on the grid size and grow with increased resolution. In the internal depression wave, the horizontal nonhydrostatic pressure gradients reach the same order of magnitude as the hydrostatic gradients in the high-resolution nonhydrostatic studies. In these studies, the nonhydrostatic pressure gradients approximately balance the corresponding hydrostatic pressure gradients in the internal depression wave, and the wave degenerates into a train of soliton waves. The time for the soliton form to develop agrees with the steepening timescale calculated from Korteweg-de Vries theory. In the high-resolution hydrostatic model, the internal depression wave takes the form of a single wave front. When the internal waves are generated in the boundary layers, the nonhydrostatic pressure gradients are much smaller than the hydrostatic gradients and the generation processes are not effected by the nonhydrostatic pressure with the present range of grid sizes.     

Controls on the height and spacing of eolian ripples and transverse dunes: A numerical modeling investigation

Ripples and transverse dunes in areas of abundant sand supply increase in height and spacing as a function of time, grain size, and excess shear velocity. How and why each of these factors influence ripple and transverse dune size, however, is not precisely known. In this paper, the controls on the height and spacing of ripples and transverse dunes in areas of abundant sand supply are investigated using a numerical model for the formation of eolian bedforms from an initially flat surface. This bedform evolution model combines the basic elements of Werner's [Werner, B.T., 1995. Eolian dunes: Computer simulations and attractor interpretation. Geology 23, 1107–1110.] cellular automaton model of dune formation with a model for boundary layer flow over complex topography. Particular attention is paid to the relationship between bed shear stress and slope on the windward (stoss) side of evolving bedforms. Nonlinear boundary layer model results indicate that bed shear stresses on stoss slopes increase with increasing slope angle up to approximately 20°, then decrease with increasing slope angle as backpressure effects become limiting. In the bedform evolution model, the linear boundary layer flow model of Jackson and Hunt [Jackson, P.S., Hunt, J.C.R., 1975. Turbulent wind flow over a low hill. Quarterly Journal of the Royal Meteorological Society 101, 929–955.], generalized to 3D, is modified to include the nonlinear relationship between bed shear stress and slope. Bed shear stresses predicted by the modified Jackson and Hunt flow model are then used to predict rates of erosion and deposition iteratively through time within a mass-conservative framework similar to Werner [Werner, B.T., 1995. Eolian dunes: Computer simulations and attractor interpretation. Geology 23, 1107–1110.]. Beginning with a flat bed, the model forms ripples that grow in height and spacing until a dynamic steady-state condition is achieved in which bedforms migrate downwind without further growth. The steady-state ripple spacing predicted by this model is approximately 3000 times greater than the aerodynamic roughness length of the initially flat surface, which is a function of grain size and excess shear velocity. Once steady-state ripples form, they become the dominant roughness element of the surface. The increase in roughness associated with ripple formation triggers the same bedform instability that created ripples, causing dunes to form at a larger scale. In this way, the numerical model of this paper suggests that ripples and dunes are genetically linked. Transverse dunes in this model have a steady-state height and spacing that is controlled by the effective roughness length of the rippled surface, which is shown to be on the order of 500 times greater than the original roughness length, but varies significantly with the details of ripple morphology. The model predictions for ripple and dune spacing and their controlling variables are consistent with field measurements from the published literature. The model of this paper provides a preliminary process-based understanding of the granulometric control of ripples and dunes in areas of abundant sand supply and unidirectional prevailing winds, and it argues for a genetic linkage between ripples and dunes via a scaling relationship between eolian bedform size and the aerodynamic roughness length.     

Wind Tunnel And Field Measurements Of Turbulent Flow In Forests. Part I: Uniformly Thinned Stands

Many forest management methods alterstand density uniformly. The effectsof such a change on the wind andturbulence regimes in the forest arecritical to a number of processes governingthe stability of the stand and itsmicroclimate. We measured wind speed andturbulence statistics with a Dantec tri-axialhot-film probe in model forests of variousdensities (31–333 trees m^-2), created byremoving whole trees in a regular pattern in awind tunnel, and compared them with similarmeasurements made with propeller anemometers insimilarly thinned plots (156–625 trees ha^-1)within a Sitka spruce stand in Scotland. The results agree well, in general, with measurements made inother such studies with diverse canopy types.The systematic variations with density and verticalleaf-area distribution (which differed betweenwind-tunnel and field trees) in our work can explainmuch of the variability shown in scaled profiles ofbasic turbulence statistics reported in theliterature. The wind tunnel and field results are shown to be in good agreement overalldespite the difference in vertical leaf-areadistribution. Within-canopy and isolated-treedrag coefficients in the wind tunnel showthat tree-scale shelter effects increase astree density increases. The measurements indicatethat turbulence in the canopy is dominated bylarge-scale structures with dimensions of the sameorder as the height of the canopy as found inother studies but suggest that inter-tree spacing also modulates the size of these structures. These structures are associated with the sweeps that dominatemomentum exchange in the canopy and it is thisfact that allows the tri-axial probe to operate sowell despite the relatively narrow range of anglesin which the wind vector is correctly measured. Theratio of streamwise periodicity of these structuresto vorticity thickness varies systematically withtree density in the range 2.7–5.1, which spans theexpected range of 3.5–5 found in a laboratorymixing-layer, suggesting that tree spacing imposes another relevant length scale. This test andothers show that the results are in agreement withthe idea that canopy turbulence resembles that of a mixing layer even though they disagree with, and challenge the linear relationship between, streamwise periodicity andshear length scale presented recently in theliterature. The measurements are also in goodoverall agreement with simple drag models presented recently by other researchers.     

A Lagrangian Solution To The Relationship Between A Distributed Source And Concentration Profile

A new solution is presented to the problem ofrelating source strength and concentration profiles within a plant canopy. The solution is based on the Lagrangian dispersion theory developed by G. I. Taylor in 1921. A dispersion matrix is derived that relates the source and concentration profiles based on profiles of the turbulent length and velocity scales. The matrix translates the effects of persistence (a temporal effect) into spatialcoordinates and represents the change from near-field to far-field in acontinuous fashion, successfully accounting for both regimes. A test ofthe new model using wind-tunnel data showed excellent quantitative agreement between model and measurements. A comparison was also made withM. R. Raupach's localized near-field theory, which underestimated the near-field effect in the wind-tunnel data and relative to the new model.     

River loads of suspended solids, nitrogen, phosphorus and herbicides delivered to the Great Barrier Reef lagoon

Degradation of coastal ecosystems in the Great Barrier Reef (GBR) lagoon, Australia, has been linked with increased land-based runoff of suspended solids, nutrients and pesticides since European settlement. This study estimated the increase in river loads for all 35 GBR basins, using the best available estimates of pre-European and current loads derived from catchment modelling and monitoring. The mean-annual load to the GBR lagoon for (i) total suspended solids has increased by 5.5 times to 17,000ktonnes/year, (ii) total nitrogen by 5.7 times to 80,000tonnes/year, (iii) total phosphorus by 8.9 times to 16,000tonnes/year, and (iv) PSII herbicides is 30,000kg/year. The increases in river loads differ across the 10 pollutants and 35 basins examined, reflecting differences in surface runoff, urbanisation, deforestation, agricultural practices, mining and retention by reservoirs. These estimates will facilitate target setting for water quality and desired ecosystem states, and enable prioritisation of critical sources for management.