Biodegradation of petroleum hydrocarbons at low temperature in the presence of the dispersant Corexit 9500

Our study examined the effects of Corexit 9500 and sediment on microbial mineralization of specific aliphatic and aromatic hydrocarbons found in crude oil. We also measured gross mineralization of crude oil, dispersed crude oil and dispersant by a marine microbial consortium in the absence of sediment. When provided as carbon sources, our consortium mineralized Corexit 9500 the most rapidly, followed by fresh oil, and finally weathered oil or dispersed oil. However, mineralization in short term assays favored particular components of crude oil (2-methyl-naphthalene > dodecane > phenanthrene > hexadecane > pyrene) and was not affected by addition of nutrients or sediment (high sand, low organic carbon). Adding dispersant inhibited hexadecane and phenanthrene mineralization but did not affect dodecane and 2-methyl-naphthalene mineralization. Thus, the effect of dispersant on biodegradation of a specific hydrocarbon was not predictable by class. The results were consistent for both high and low oiling experiments and for both fresh and weathered oil. Overall, our results indicate that environmental use of Corexit 9500 could result in either increases or decreases in the toxicity of residual oil through selective microbial mineralization of hydrocarbons.     

Experimental comparison of trace element partitioning between clinopyroxene and melt in carbonate and silicate systems, and implications for mantle metasomatism

Experiments in the systems diopside-albite (Di-Ab) and diopside-albite-dolomite (Di-Ab-Dmt), doped with a wide range of trace elements, have been used to characterise the difference between clinopyroxene-silicate melt and clinopyroxene-carbonate melt partitioning. Experiments in Di-Ab-Dmt yielded clinopyroxene and olivine in equilibrium with CO₂-saturated dolomitic carbonate melt at 3 GPa, 1375 °C. The experiments in Di-Ab were designed to bracket those conditions (3 GPa, 1640 °C and 0.8 GPa, 1375 °C), and so minimise the contribution of differential temperature and pressure to partitioning. Partition coefficients, determined by SIMS analysis of run products, differ markedly for some elements between Di-Ab and Di-Ab-Dmt systems. Notably, in the carbonate system clinopyroxene-melt partition coefficients for Si, Al, Ga, heavy REE, Ti and Zr are higher by factors of 5 to 200 than in the silicate system. Conversely, partition coefficients for Nb, light REE, alkali metals and alkaline earths show much less fractionation (<3). The observed differences compare quantitatively with experimental data on partitioning between immiscible carbonate and silicate melts, indicating that changes in melt chemistry provide the dominant control on variation in partition coefficients in this case. The importance of melt chemistry in controlling several aspects of element partitioning is discussed in light of the energetics of the partitioning process. The compositions of clinopyroxene and carbonate melt in our experiments closely match those of near-solidus melts and crystals in CMAS-CO₂ at 3 GPa, suggesting that our partition coefficients have direct relevance to melting of carbonated mantle lherzolite. Melts so produced will be characterised by elevated incompatible trace element concentrations, due to the low degrees of melting involved, but marked depletions of Ti and Zr, and fractionated REE patterns. These are common features of natural carbonatites. The different behaviour of trace elements in carbonate and silicate systems will lead to contrasted styles of trace element metasomatism in the mantle. Received: 15 July 1999 / Accepted: 18 February 2000     

正断层断距纵剖面图及其运动学:概念模型与地质实例

断距纵剖面图 （T H图）是指以断层的垂直断距为横轴、以地层或地质年龄为纵轴所绘制的随地层或地质年龄所变化的断距分布图。断距纵剖面图为确定正断层类型、断层形成时间和断层的纵向演化史提供了一个简单迅捷的工具。概念模型表明,断距纵剖面图可以明确无误地区分出简单后沉积型正断层、后沉积拱顶拉张型正断层、同沉积生长型正断层及其复合型正断层。简单后沉积型正断层的断距不随地层年龄的变化而变化, 其断距纵剖面图为一垂直线段。后沉积拱顶拉张型正断层的断距随地层年龄的增大而减小并趋向零值,同沉积生长型正断层的断距随地层年龄的增大而增大,复合型正断层则具其组合型断距纵剖面形态。除简单后沉积型正断层外,断距纵剖面图中的最大断距点代表了该断层的起始形成年代。     

Taphonomy and site formation on California's Channel Islands

Inhabited by humans for over 12,000 calendar years, California's Channel Islands contain thousands of archaeological sites, ranging from dense shell middens and villages to small lithic scatters and camps. Similar to many islands around the world, the Channel Islands have a dearth of burrowing animals and limited historical development leading to generally good preservation of archaeological constituents and relatively high stratigraphic integrity. Despite these favorable preservation conditions, numerous natural and cultural processes have impacted the island's archaeological record. Channel Islands archaeologists, however, have given relatively limited attention to the effects of taphonomic and formation processes. The authors provide an overview of taphonomic and formation processes affecting Channel Islands archaeology, illustrating the importance of regional taphonomic syntheses in the management, preservation, and interpretation of archaeological sites. These data also demonstrate the significance of detailing formation processes in islands and other areas where burrowing rodents and other disturbances are thought to be absent or limited. © 2006 Wiley Periodicals, Inc.     

Linking meteorites to their asteroid parent bodies: The capabilities of dust analyzer instruments during asteroid flybys

Linking meteorites to their asteroid parent bodies remains an outstanding issue. Space-based dust characterization using impact ionization mass spectrometry is a proven technique for the compositional analysis of individual cosmic dust grains. Here we investigate the feasibility of determining asteroid compositions via cation mass spectrometric analyses of their dust ejecta clouds during low (7–9 km s⁻¹) velocity spacecraft flybys. At these speeds, the dust grain mass spectra are dominated by easily ionized elements and molecular species. Using known bulk mineral volume abundances, we show that it is feasible to discriminate the common meteorite classes of carbonaceous chondrites, ordinary chondrites, and howardite–eucrite–diogenite achondrites, as well as their subtypes, relying solely on the detection of elements with ionization efficiencies of ≤700 or ≤800 kJ mol⁻¹, applicable to low (~7 km s⁻¹) and intermediate (~9 km s⁻¹) flyby speed scenarios, respectively. Including the detection of water ion groups enables greater discrimination between certain meteorite types, and flyby speeds ≥10 km s⁻¹ enhance the diagnostic capabilities of this technique still further. Although additional terrestrial calibration is required, this technique may allow more unequivocal asteroid-meteorite connections to be determined by spacecraft flybys, emphasizing the utility of dust instruments on future asteroid missions.     

Global warming vs. climate change, taxes vs. prices: Does word choice matter?

Does ??climate change?? seem like a less serious problem than ??global warming?? to Americans and Europeans? Does describing the costs of climate change mitigation in terms of ??higher taxes?? instead of ??higher prices?? reduce public support for such efforts? In an experiment embedded in an American national survey, respondents were randomly assigned to rate the seriousness of ??global warming,?? ??climate change,?? or ??global climate change.?? Contrary to predictions made by a leading political strategist, the full sample and political Independents perceived ??climate change?? and ??global warming?? to be equally serious. Among Republicans, ??climate change?? was perceived to be more serious than ??global warming,?? whereas the reverse was true among Democrats. A similar experiment embedded in a survey of residents of 31 European countries showed that ??global warming?? and ??climate change?? were perceived to be equally serious problems. And an experiment embedded in an American survey showed that describing the increased costs of climate change mitigation legislation via ??higher taxes?? instead of via ??higher prices?? did not reduce popular support for such legislation, also contradicting a political strategy memo. Thus, word choice may sometimes affect public perceptions of the climate change seriousness or support for mitigation policies, but a single choice of terminology may not influence all people the same way, making strategic language choices difficult to implement.