Spatial and temporal zoning of hydrothermal alteration and mineralization in the Sossego iron oxide–copper–gold deposit,Carajás Mineral Province,Brazil: paragenesis and stable isotope constraints

The Sossego iron oxide–copper–gold deposit (245 Mt @ 1.1% Cu, 0.28 g/t Au) in the Carajás Mineral Province of Brazil consists of two major groups of orebodies (Pista–Sequeirinho–Baiano and Sossego–Curral) with distinct alteration assemblages that are separated from each other by a major high angle fault. The deposit is located along a regional WNW–ESE-striking shear zone that defines the contact between metavolcano–sedimentary units of the ∼2.76 Ga Itacaiúnas Supergroup and tonalitic to trondhjemitic gneisses and migmatites of the ∼2.8 Ga Xingu Complex. The deposit is hosted by granite, granophyric granite, gabbro, and felsic metavolcanic rocks. The Pista–Sequeirinho–Baiano orebodies have undergone regional sodic (albite–hematite) alteration and later sodic–calcic (actinolite-rich) alteration associated with the formation of massive magnetite–(apatite) bodies. Both these alteration assemblages display ductile to ductile–brittle fabrics. They are cut by spatially restricted zones of potassic (biotite and potassium feldspar) alteration that grades outward to chlorite-rich assemblages. The Sossego–Curral orebodies contain weakly developed early albitic alteration and very poorly developed subsequent calcic–sodic alteration. These orebodies contain well-developed potassic alteration assemblages that were formed during brittle deformation that resulted in the formation of breccia bodies. Breccia matrix commonly displays coarse mineral infill suggestive of growth into open space. Sulfides in both groups of deposits were precipitated first with potassic alteration and more importantly with a later assemblage of calcite–quartz–epidote–chlorite. In the Sequeirinho orebodies, sulfides range from undeformed to deformed; sulfides in the Sossego–Curral orebodies are undeformed. Very late, weakly mineralized hydrolytic alteration is present in the Sossego/Currral orebodies. The sulfide assemblage is dominated by chalcopyrite with subsidiary siegenite, and millerite. Pyrrhotite and pyrite are minor constituents of ore in the Sequerinho orebodies while pyrite is relatively abundant in the Sossego–Curral bodies. Oxygen isotope partitioning between mineral pairs constrains temperatures in the deposit spatially and through time. In the Sequeirinho orebody, the early sodic–calcic alteration stage was characterized by temperatures exceeding 500°C and values for the alteration fluid of 6.9 ± 0.9‰. Temperature declines outward and upward from the zone of most intense alteration. Paragenetically later copper–gold mineralization displays markedly lower temperatures (<300°C) and was characterized by the introduction of ¹⁸O-depleted hydrothermal fluids −1.8 ± 3.4‰. The calculated δD_H2O and values suggest that the fluids that formed the early calcic–sodic alteration assemblage were of formational/metamorphic or magmatic origin. The decrease of values through time may reflect influx of surficially derived waters during later alteration and mineralization events. Influx of such fluids could be related to episodic fluid overpressure, resulting in dilution and cooling of the metalliferous fluid, causing deposition of metals transported as metal chloride complexes.     

Subsurface evidence for late Mesozoic extension in western Mongolia: tectonic and petroleum systems implications

New seismic reflection profiles from the Tugrug basin in the Gobi‐Altai region of western Mongolia demonstrate the existence of preserved Mesozoic extensional basins by imaging listric normal faults, extensional growth strata, and partially inverted grabens. A core hole from this region recovered ca. 1600 continuous meters of Upper Jurassic – Lower Cretaceous (Kimmeridgian–Berriasian) strata overlying Late Triassic volcanic basement. The cored succession is dominated by lacustrine and marginal lacustrine deposits ranging from stratified lacustrine, to subaqueous fan and delta, to subaerial alluvial‐fluvial environments. Multiple unconformities are encountered, and these represent distinct phases in basin evolution including syn‐extensional deposition and basin inversion. Prospective petroleum source and reservoir intervals occur, and both fluid inclusions and oil staining in the core provide evidence of hydrocarbon migration. Ties to correlative outcrop sections underscore that, in general, this basin appears to share a similar tectono‐stratigraphic evolution with petroliferous rift basins in eastern Mongolia and China. Nevertheless, some interesting contrasts to these other basins are noted, including distinct sandstone provenance, less overburden, and younger (Neogene) inversion structures. The Tugrug basin occupies an important but perplexing paleogeographic position between late Mesozoic contractile and extensional provinces. Its formation may record a rapid temporal shift from orogenic crustal thickening to extensional collapse in the Late Jurassic, and/or an accommodation zone with a Mesozoic strike‐slip component.     

Decadal water mass variations along 20°W in the Northeastern Atlantic Ocean

Water mass variations in the northeastern Atlantic Ocean along 20°W are analyzed with pentadal resolution over the past 15 years using data from four repeat occupations of a meridional hydrographic section running south from Iceland. The section was sampled in 1988, 1993, 1998, and 2003. The results are interpreted in the context of changes in air–sea forcing, ocean circulation, and water properties associated with the North Atlantic Oscillation (NAO). The NAO index oscillated around zero from 1984 to 1988, was strongly positive from 1989 to 1995, after which it shifted to lower positive, and occasionally negative values from 1996 to 2003. Previously published studies suggest that after the 1995–1996 shift of the NAO, the subpolar gyre largely retreated to the northwest in the northeastern Atlantic Ocean, resulting in an increasingly southeastern character of local water masses with time. Water property changes extending from the SubPolar Mode Water (SPMW) just below the seasonal pycnocline through the density range shared by Mediterranean Outflow Water and SubArctic Intermediate Water (SAIW) along 20°W are consistent with changes in wind-driven ocean circulation and air–sea heat flux associated with shifts in the NAO, especially after accounting for ocean memory. After periods of lower NAO index the SPMW is warmer, saltier, and lighter. At these same times, large increases of apparent oxygen utilization (AOU) and potential vorticity are found at the SPMW base, consistent with SPMW ventilation to lighter densities during lower NAO index periods. Deeper and denser in the water column, the cold, fresh, and dense SAIW signature within the permanent pycnocline that was most strongly present in 1993, near the culmination of a period of high NAO index, is much reduced in 1988 and 1998. In 2003, after a prolonged period of lower NAO index, increasing influence of warmer, saltier subtropical waters is clear within the permanent pycnocline. The deep penetration of the changes implies that they are caused primarily by circulation changes resulting from NAO-associated wind shifts, but changes in air–sea heat flux could also have played a role.     

Studies on the reflectance spectral features of saline soil along the middle reaches of Tarim River: a case study in Xinjiang Autonomous Region, China

There has been growing interest in the use of reflectance spectroscopy as a rapid and inexpensive tool for soil characterization. In this study, 53 soil samples were collected from the oasis in the Weigan and Kuqa River delta along the middle reaches of Tarim River to investigate the level of soil chemical components in relation to soil spectral. An approach combining spectral technology and multi-variant statistical analysis was used to determine the reflectance spectral features of saline soil. The spectral data was first pretreated to remove noises and absorption bands from water, which eliminated influence from instrument errors and other external background factors. Several spectral absorption features were calculated for several saline soil samples to confirm that soil at the same salinity level had similar absorption spectral properties. Secondly, a correlation relationship between reflectance spectra and salinity factors was estimated by bivariate correlation method. Fourteen salinity factors including eight major ions and soil electrical conductivity (EC), soil salt content (SSC), pH, and total dissolved solid (TDS) in the saline soil were evaluated. Datasets of the salinity factors that correlated significantly with field data measurements of reflectance rate and the corresponding spectrum data were used to construct quantitative regression models. According to the multiple linear regression analysis, SSC, SO₄ ^2?, TDS, and EC had a correlation coefficient at 0.746, 0.908, 0.798, and 0.933 with the raw spectral data, respectively, which confirmed strong correlation between salinity factors and soil reflectance spectrum. Findings from this study will have significant impact on characterization of spectral features of saline soil in oasis in arid land.     

The solubility of SO2 and the dissociation of H2SO3 in NaCl solutions

The pK ₁ ^* and pK ₂ ^* of H₂SO₃ have been determined in NaCl solutions as a function of ionic strength (0.1 to 6 m) and temperature (5 and 25 °C). The extrapolated values in water were found to be in good agreement with literature data. The experimental results have been used to determine the Pitzer interaction parameters for SO₂, HSO ₃ ^- and SO ₃ ^- in NaCl solutions. The resultant parameters for NaHSO₃ and Na₂SO₃ were found to be in reasonable agreement with the values for NaHSO₄ and Na₂SO₄. It, thus, seems reasonable to assume that the interactions of Mg²⁺ and Ca²⁺ with HSO ₃ ^- and SO ₃ ^- can be estimated from the values with HSO ₄ ^- and SO ₄ ^- until experimental values are available. Measurements of pK ₁ ^* and pK ₂ ^* in artificial seawater were found to be in good agreement with the calculated values using the derived Pitzer parameters. It is, thus, possible to make reasonable estimates of the activity coefficients of HSO ₃ ^- and SO ₃ ^- ions and pK ₁ ^* and pK ₂ ^* for the ionization of H₂SO₃ in marine aerosols.     

Using second-order approximation to incorporate GCM uncertainty in climate change impact assessments

This study presents a method to incorporate uncertainty of climate variables in climate change impact assessments, where the uncertainty being considered refers to the divergence of general circulation model (GCM) projections. The framework assesses how much bias occurs when the uncertainties of climate variables are ignored. The proposed method is based on the second-order expansion of Taylor series, called second-order approximation (SOA). SOA addresses the bias which occurs by assuming the expected value of a function is equal to the function of the expected value of the predictors. This assumption is not valid for nonlinear systems, such as in the case of the relationship of climate variables to streamflow. To investigate the value of SOA in the climate change context, statistical downscaling models for monthly streamflow were set up for six hydrologic reference stations in Australia which cover contrasting hydro-climate regions. It is shown that in all locations SOA makes the largest difference for low flows and changes the overall mean flow by 1–3%. Another advantage of the SOA approach is that the individual contribution of each climate variable to the total difference can be estimated. It is found that geopotential height and specific humidity cause more bias than wind speeds in the downscaling models considered here.     

Steady, balanced rates of uplift and erosion of the Santa Monica Mountains, California

Topographic change in regions of active deformation is a function of rates of uplift and denudation. The rate of topographic development and change of an actively uplifting mountain range, the Santa Monica Mountains, southern California, was assessed using landscape attributes of the present topography, uplift rates and denudation rates. Landscape features were characterized through analysis of a digital elevation model (DEM). Uplift rates at time scales ranging from 10⁴ to 10⁶ years were constrained with geological cross-sections and published estimates. Denudation rate was determined from sediment yield data from debris basins in southern California and from the relief of rivers set into geomorphic surfaces of known age. First-order morphology of the Santa Monica Mountains is set by large-scale along-strike variations in structural geometry. Drainage spacing, drainage geometry and to a lesser extent relief are controlled by bedrock strength. Dissection of the range flanks and position of the principal drainage divide are modulated by structural asymmetry and differences in structural relief across the range. Topographic and catchment-scale relief are ≈300–900 m. Mean denudation rate derived from the sediment yield data and river incision is 0.5±0.3 mm yr^?1. Uplift rate across the south flank of the range is ≈0.5±0.4 mm yr^?1 and across the north flank is 0.24±0.12 mm yr^?1. At least 1.6–2.7 Myr is required to create either the present topographic or the catchment-scale relief based on either the mean rates of denudation or uplift. Although the landscape has had sufficient time to achieve a steady-state form, comparison of the time-scale of uplift and denudation rate variation with probable landscape response times implies the present topography does not represent the steady-state form.