Solar system observations by the Wisconsin Ultraviolet Photopolarimeter Experiment– III. The first ultraviolet linear spectropolarimetry of the Moon

Portions of the Moon were observed by the Wisconsin Ultraviolet Photopolarimeter Experiment ( WUPPE ) on 1995 March 12, 14 and 17, and represent the first ultraviolet (UV) spectropolarimetric observations of the Moon. The polarimetric observations confirm that a change in the dominant scattering process occurs in the UV, changing from volume scattering in the near-UV to surface scattering in the far-UV. The data are investigated empirically. It is found that Umov's relationship holds when the polarization is perpendicular to the scattering plane. It is also found that the degree of polarization can be modelled by a phase-angle-dependent polarization modified by a wavelength-dependent depolarization factor. The scattering function for each observation is determined.     

Reconstructing orogenic exhumation histories using synorogenic detrital zircons and apatites: an example from the Betic Cordillera, SE Spain

Fission track thermogeochronology using detrital apatite and zircon from a synorogenic foreland basin on the northern margin of the Betic Cordillera Internal Zone is used to reconstruct the cooling and unroofing history of the sediment source areas in the Oligo-Miocene mountain belt. Previously, a heavy mineral study on the same sedimentary rocks showed that progressively deeper tectonometamorphic units were being unroofed during the latest Oligocene to middle Miocene at a minimum rate of 3  km Myr⁻¹. The fission track data have further constrained the exhumation history showing that the structurally highest (i.e. shallowest) parts of the mountain belt (Malaguide Complex) cooled relatively slowly during the latest Oligocene–Aquitanian, while the deeper metamorphic units (Alpujarride Complex) cooled at much higher rates (up to 300 °C Myr⁻¹) during the Burdigalian–Langhian. These fast cooling rates from synorogenic detritus are consistent with cooling rates calculated previously for the deeper parts of the early Miocene orogenic belt, using ³⁹Ar–⁴⁰Ar dating of muscovite, biotite and amphibole from basement metamorphic rocks. Rapid cooling in the early Miocene, which commenced at ≈21  Ma, is attributed to the change in process from erosional to tectonic denudation by orogen-scale extension within the eastern Betic Cordillera.

     

Remediating Ground Water with Zero-Valent Metals: Chemical Considerations in Barrier Design

To gain perspective and insight into the performance of permeable reactive barriers containing granular iron metal, it is useful to compare the degradation kinetics of individual chlorinated solvents over a range of operating conditions. Pseudo first-order disappearance rate constants normalized to iron surface area concentration (k_SA) recently have been reported for this purpose. This paper presents the results of further exploratory data analysis showing the extent to which variation in k_SA is due to initial halocarbon concentration, iron type, and other factors. To aid in preliminary design calculations, representative values of k_SA and a reactive transport model have been used to calculate the minimum barrier width needed for different ground water flow velocities and degrees of halocarbon conversion. Complete dechlorination of all degradation intermediates requires a wider treatment zone, but the effect is not simply additive because degradation occurs by sequential and parallel reaction pathways.     

Organochlorines and other environmental contaminants in muscle tissues of sportfish collected from San Francisco Bay

Edible fish species were collected from 13 locations throughout San Francisco Bay, during the spring of 1994, for determination of contaminant levels in muscle tissue. Species collected included white croaker, surfperch, leopard and brown smoothhound sharks, striped bass, white sturgeon and halibut. 66 composite tissue samples were analysed for the presence of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (P0CBs), pesticides, trace elements and dioxin/furans. The US EPA approach to assessing chemical contaminant data for fish tissue consumption was used for identifying the primary chemicals of concern. Six chemicals or chemical groups were found to exceed screening values (SVs) established using the US EPA approach. PCBs (as total Aroclors) exceeded the screening level of 3 ng g⁻¹ in all 66 muscle tissue samples, with the greatest concentrations (638 ng g⁻¹) found near San Francisco's industrial areas. Mercury was elevated (> 0.14 μg g⁻¹) in 40 of 66 samples with the greatest concentrations (1.26 μg g⁻¹) occurring in shark muscle tissues. Concentrations of the organochlorine pesticides dieldrin, total chlordane and total dichlorodiphenyltri-chloroethane (DDT) exceeded screening levels in a number of samples. Dioxin/furans (as toxic equivalent concentrations (TEQ's)) were elevated (> 0.15 pg g⁻¹) in 16 of the 19 samples analysed. Fish with high lipid content (croaker and surfperch) in their muscle tissue generally exhibited higher organic contaminant levels while fish with low lipid levels (halibut and shark) exhibited lower organic contaminant levels. Tissue samples taken from North Bay stations most often exhibited high levels of chemical contamination. The California Office of Health Hazard Assessment is currently evaluating the results of this study and has issued an interim Health Advisory concerning the human consumption of fish tissue from San Francisco Bay.     

Sensitivity to open boundary forcing in a fine-resolution model of the Iberian shelf-slope region

A fine-resolution primitive equation numerical model is constructed for the Iberian continental shelf and slope region, with open boundaries to the north, south and west. The model is forced by climatological wind fields and relaxed at the surface to climatological temperature and salinity fields. A series of numerical experiments is conducted to investigate the influence of the open boundary conditions. The numerical results include coastal upwelling in summer and a poleward current in winter. The effects of advection of Mediterranean Water and eastern North Atlantic Central Water feature in the circulation. Qualitative comparisons are made with observations.