Natural Gradient Tracer Test to Evaluate Natural Attenuation of MTBE Under Anaerobic Conditions

A natural gradient tracer test using perdeuterated MTBE was conducted in an anaerobic aquifer to determine the relative importance of dispersion and degradation in reducing MTBE concentrations in ground water. Preliminary ground water chemistry and hydraulic conductivity data were used to place the tracer within an existing dissolved MTBE plume at Port Hueneme, California. Following one year of transport, the tracer plume was characterized in detail.
Longitudinal dispersion was identified as the dominant mechanism for lowering the perdeuterated MTBE concentrations. The method of moments was used to determine the longitudinal and lateral dispersion coefficients (0.85 m²/day and 0.08 m²/day, respectively). A mass-balance analysis, carried out after one year of transport, accounted for 110% of the injected mass and indicated that no significant mass loss occurred. The plume structure created by zones of higher and lower hydraulic conductivity at the site was complex, consisting of several localized areas of high tracer concentration in a lower concentration plume. This is important because the aquifer has generally been characterized as exhibiting fairly minor heterogeneity. In addition, the tracer plume followed a curved flowpath that deviated from the more macroscopic direction of ground water flow inferred from local ground water elevation measurements and the behavior of the existing plume. Understanding the mass balance, plume structure, curvature of the tracer plume, and consequently natural attenuation behavior required the detailed sampling approach employed in this study. These data imply that a detailed understanding of site hydrogeology and an extensive sampling network may be critical for the correct interpretation of monitored natural attenuation of MTBE.     

The OSIRIS‐REx target asteroid (101955) Bennu: Constraints on its physical,geological, and dynamical nature from astronomical observations

We review the results of an extensive campaign to determine the physical, geological, and dynamical properties of asteroid (101955) Bennu. This investigation provides information on the orbit, shape, mass, rotation state, radar response, photometric, spectroscopic, thermal, regolith, and environmental properties of Bennu. We combine these data with cosmochemical and dynamical models to develop a hypothetical timeline for Bennu's formation and evolution. We infer that Bennu is an ancient object that has witnessed over 4.5 Gyr of solar system history. Its chemistry and mineralogy were established within the first 10 Myr of the solar system. It likely originated as a discrete asteroid in the inner Main Belt approximately 0.7–2 Gyr ago as a fragment from the catastrophic disruption of a large (approximately 100‐km), carbonaceous asteroid. It was delivered to near‐Earth space via a combination of Yarkovsky‐induced drift and interaction with giant‐planet resonances. During its journey, YORP processes and planetary close encounters modified Bennu's spin state, potentially reshaping and resurfacing the asteroid. We also review work on Bennu's future dynamical evolution and constrain its ultimate fate. It is one of the most Potentially Hazardous Asteroids with an approximately 1‐in‐2700 chance of impacting the Earth in the late 22nd century. It will most likely end its dynamical life by falling into the Sun. The highest probability for a planetary impact is with Venus, followed by the Earth. There is a chance that Bennu will be ejected from the inner solar system after a close encounter with Jupiter. OSIRIS‐REx will return samples from the surface of this intriguing asteroid in September 2023.     

Modelling the spatial and temporal distribution of rainfall: a case study in the wet and dry tropics of North East Australia

Rainfall regimes with strong spatial and temporal variation are characteristic of many coastal regions of north and eastern Australia. In coastal regions of north eastern Australia, regimes vary considerably over short distances. This occurs because of changes in local topography, including the height and orientation of mountain ranges and the direction of the coastline with respect to the prevailing moist south east air stream. Northern Australia experiences a tropical monsoon climate with rainfall occurring predominantly during the summer months. Areas with a closer proximity to the coast typically experience the heavier rainfalls. While networks of rainfall gauges have been established and continuous records are available for most of these stations from the 1890s, their low distribution density relative to the complexity of rainfall pattern they are required to represent means that there remains a poor understanding of the spatial and temporal distribution of rainfall in the wet tropics. An enhanced knowledge of rainfall distribution in both space and time has the potential to deliver significant economic and environmental benefits to managers of natural resources. This paper reports on the application of a technique for estimating mean annual and mean monthly rainfall across the Herbert River catchment of north east Australia's dry and wet tropics. The technique utilises thin plate smoothing splines to incorporate both location and elevation into estimates of rainfall distribution. We demonstrate that the method can be applied successfully at the meso scale and within the domain of routinely available data. As such, the method has broad relevance for decision making.     

Linking gold mineralization to regional-scale drivers of mineral systems using in situ U–Pb geochronology and pyrite LA-ICP-MS element mapping

Proterozoic orogens commonly host a range of hydrothermal ores that form in diverse tectonic settings at different times. However, the link between mineralization and the regional-scale tectonothermal evolution of orogens is usually not well understood, especially in areas subject to multiple hydrothermal events.Regional-scale drivers for mineral systems vary between the different classes of hydrothermal ore, but all involve an energy source and a fluid pathway to focus mineralizing fluids into the upper crust. The Mount Olympus gold deposit in the Proterozoic Capricorn Orogen of Western Australia, was regarded as an orogenic gold deposit that formed at ca. 1738 Ma during the assembly of Proterozoic Australia. However,the trace element chemistry of the pyrite crystals closely resembles those of the Carlin deposits of Nevada,with rims that display solid solution gold accompanied by elevated As, Cu, Sb, Hg, and Tl, surrounding gold-poor cores. New SHRIMP UeP b dating of xenotime intergrown with auriferous pyrite and ore-stage alteration minerals provided a weighted mean~(207) Pb*/~(206) Pb* date of 1769 ± 5 Ma, interpreted as the age of gold mineralization. This was followed by two discrete episodes of hydrothermal alteration at 1727 ± 7 Ma and 1673 ± 8 Ma. The three ages are linked to multiple reactivation of the crustal-scale Nanjilgardy Fault during repeated episodes of intracratonic reworking. The regional-scale drivers for Carlin-like gold mineralization at Mount Olympus are related to a change in tectonic regime during the final stages of the intracratonic 1820 -1770 Ma Capricorn Orogeny. Our results suggest that substantial sized Carlin-like gold deposits can form in an intracratonic setting during regional-scale crustal reworking.     

Postglacial vegetation history of Mitkof Island, Alexander Archipelago, southeastern Alaska

An AMS radiocarbon-dated pollen record from a peat deposit on Mitkof Island, southeastern Alaska provides a vegetation history spanning ∼12,900 cal yr BP to the present. Late Wisconsin glaciers covered the entire island; deglaciation occurred > 15,400 cal yr BP. The earliest known vegetation to develop on the island (∼12,900 cal yr BP) was pine woodland (Pinus contorta) with alder (Alnus), sedges (Cyperaceae) and ferns (Polypodiaceae type). By ∼12,240 cal yr BP, Sitka spruce (Picea sitchensis) began to colonize the island while pine woodland declined. By ∼11,200 cal yr BP, mountain hemlock (Tsuga mertensiana) began to spread across the island. Sitka spruce-mountain hemlock forests dominated the lowland landscapes of the island until ∼10,180 cal yr BP, when western hemlock (Tsuga heterophylla) began to colonize, and soon became the dominant tree species. Rising percentages of pine, sedge, and sphagnum after ∼7100 cal yr BP may reflect an expansion of peat bog habitats as regional climate began to shift to cooler, wetter conditions. A decline in alders at that time suggests that coastal forests had spread into the island's uplands, replacing large areas of alder thickets. Cedars (Chamaecyparis nootkatensis, Thuja plicata) appeared on Mitkof Island during the late Holocene.     

Post-solidification cooling and the age of Io's lava flows

The modeling of thermal emission from active lava flows must account for the cooling of the lava after solidification. Models of lava cooling applied to data collected by the Galileo spacecraft have, until now, not taken this into consideration. This is a flaw as lava flows on Io are thought to be relatively thin with a range in thickness from ∼1 to 13 m. Once a flow is completely solidified (a rapid process on a geological time scale), the surface cools faster than the surface of a partially molten flow. Cooling via the base of the lava flow is also important and accelerates the solidification of the flow compared to the rate for the ‘semi-infinite’ approximation (which is only valid for very deep lava bodies). We introduce a new model which incorporates the solidification and basal cooling features. This model gives a superior reproduction of the cooling of the 1997 Pillan lava flows on Io observed by the Galileo spacecraft. We also use the new model to determine what observations are necessary to constrain lava emplacement style at Loki Patera. Flows exhibit different cooling profiles from that expected from a lava lake. We model cooling with a finite-element code and make quantitative predictions for the behavior of lava flows and other lava bodies that can be tested against observations both on Io and Earth. For example, a 10-m-thick ultramafic flow, like those emplaced at Pillan Patera in 1997, solidifies in ∼450 days (at which point the surface temperature has cooled to ∼280 K) and takes another 390 days to cool to 249 K. Observations over a sufficient period of time reveal divergent cooling trends for different lava bodies [examples: lava flows and lava lakes have different cooling trends after the flow has solidified (flows cool faster)]. Thin flows solidify and cool faster than flows of greater thickness. The model can therefore be used as a diagnostic tool for constraining possible emplacement mechanisms and compositions of bodies of lava in remote-sensing data.     

Fossil midge associations and the historical status of fish in acidified lakes

Chaoborid and chironomid (Diptera) fossils were examined in sediment cores form nine Ontario Precambrian Shield lakes that were fishless in 1979. An abundance of Chaoborus americamus (intolerant of predation by fish) throughout cores from four lakes indicated that they were fishless historically. Occurrence of Chaoborus punctipennis and C. flavicans and absence of C. americanus in cores, except near the surface in two cases, indicated that four other lakes were inhabited by fish historically. One of these was probably periodically fishless as suggested by fluctuations among these Chaoborus species. The ninth lake was not suitable for Chaoborus; only one specimen of C. trivittatus was found in this core. Chironomid fossil associations were substantially different in historically fishless and inhabited lakes. Fishless lakes had chironomids typical of eutrophic conditions indicating that seasonal oxygen depletion likely was inimical to fish. Chironomid associations of oligotrophic waters occurred in lakes historically inhabited by fish. Both good water quality and accessibility were required for long-term habitation by fish. Partial recovery of alkalinity and rise in pH were accompanied by substantial re-invasion by fish in two lakes which had been inhabited historically by fish. Diptera associations provide valuable information on the historical suitability of lakes for fish and the presence/absence of fish in regions where acidification of surface waters has occurred.     

Financing rapid community reconstruction after catastrophic disaster: lessons from the 2008 Wenchuan earthquake in China

Catastrophic disasters can change the course of urban development and challenge the long-run sustainability of cities and regions. How to rapidly reconstruct communities impaired by catastrophic disaster is a world-wide challenge. The reconstruction after the 2008 Wenchuan earthquake in China was an unusual case of very rapid reconstruction after a catastrophic disaster. Over US$147 billion was invested to rebuild the damaged areas within 3 years. The reconstruction was not simply building back what was destroyed, but was used as an opportunity to advance national goals for urbanization, rural transformation, and poverty reduction. In this article, we review how the reconstruction was planned, budgeted, and financed in the sociopolitical context of 2008 China. Particularly, we discuss two innovative programs, namely pair assistance and land-based financing. Despite the unique circumstances of China, lessons can be learned to speed up post-disaster reconstruction and urban development in other countries. Conversely, this case illustrates that a narrow focus on physical reconstruction may overlook broader economic and social issues.