Thermodynamics of selected trace elements in the Jovian atmosphere

The thermochemistry of several hundred compounds of twelve selected trace elements (Ge, Se, Ga, As, Te, Pb, Sn, Cd, Sb, Tl, In, and Bi) has been investigated for solar composition material along a Jupiter adiabat. The results indicate that AsF₃, InBr, TlI, and SbS, in addition to CO, PH₃, GeH₄, AsH₃, H₂Se, HCl, HF, and H₃BO₃ proposed by Barshay and Lewis (1978), may be potential chemical tracers of atmospheric dynamics. The reported observations of GeH₄ is interpreted on the basis of new calculations as implying rapid vertical transport from levels where T ? 800°K. Upper limits are also set on the abundances of many gaseous compounds of the elements investigated.     

Newtonian cosmology with a varying gravitational constant

Newtonian cosmology is developed with the assumption that the gravitational constantG diminishes with time. The functional form adopted forG(t), a modification of a suggestion of Dirac, isG=A(k+t) ^–1, wheret is the age of the Universe and a small constantk is inserted to avoid a singularity in the two-body problem. IfR is the scale factor, normalized to unity at an epoch time , the differential equation is then . Here ₀ is the mean density at the epoch time. With the above form forG(t), the solution is reducible to quadratures.The scale factorR either increases indefinitely or has one and only one maximum. LetH ₀ be the present value of Hubble's constant /R and _0c the minimum density for a maximum ofR, i.e., for closure of the Universe. The conditions for a maximum lead to a boundary curve of _0c versusH ₀ and the numbers indicate strongly that thisG-variable Newtonian model corresponds to an open universe. An upward estimate of the age of the Universe from 10¹⁰ yr to five times such a value would still lead to the same conclusion.The present Newtonian cosmology appears to refute the statement, sometimes made, that the Dirac model forG necessarily leads to the conclusion that the age of the Universe is one-third the Hubble time. Appendix B treats this point, explaining that this incorrect conclusion arises from using all the assumptions in Dirac (1938). The present paper uses only Dirac's final result, viz,G(k+t)^–1, superposing it on the differential equation .     

Deep drilling at the Siljan Ring impact structure: oxygen-isotope geochemistry of granite

The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, ¹⁸O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5 at 5760 m depth. In contrast, feldspar ¹⁸O values decrease with depth from near 10 at the surface to 7.1 at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of ¹⁸O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar ¹⁸O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100–300° C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500° C) exchange between alkali feldspar and fluids. The high-temperature exchange may have been a post-impact event involving impact-heated fluids, or a post-magmatic event.     

Large-scale ionization fronts and the nature and distribution of light scattering particles in the orion nebula

Image-tube filter photographs calibrated against photoelectric filter photometry have been used to give maps of M42 in absolute flux units over the central 15 arc min of the nebula in Hα, [Nii] (λ 6584 Å), Hβ and continuum at λ 4700 Å. Maps of the ratios Hα/[Nii] and (for the first time) of continuum/Hβ have been produced with unprecedented spatial resolution. These show that the gas to dust ratio is high near the exciting stars and falls strongly in the vicinity of large scale ionization fronts marked by minima in the Hα/[Nii] ratio. These results are interpreted in terms of detailed shell models containing either ice or graphite or silicate scattering particles. In all models there must be a central hole in the distribution of scattering particles. The effect of neutral globules and intrusions is investigated. It is found that all types of grain are trapped inside neutral intrusions near the centre of the nebula by the pressure of the Lα light surrounding the globule, but in the early evolution of the nebula particles can escape into the ionized medium when fronts are R-type. Ice grains escaping at this time will be destroyed for distances to the exciting stars less than 1 pc. These results can explain both the central hole in dust and the underabundance of oxygen in the ionized gas observed earlier. Arguments depending on colour index of the scattered light indicate that mixtures of scattered light from ice in the globules and from ice in the ionized medium can explain the observations, but that the graphite and silicate particles fail. A schematic model of the Orion Nebula is presented to attempt to explain the large scale phenomena observed here. It demonstrates that simple shell models for this nebula are dubious.     

Food Deserts in the Prairies? Supermarket Accessibility and Neighborhood Need in Edmonton,Canada*

The U.S. and U.K. literatures have discussed “food deserts,” reflecting populated, typically urban, low‐income areas with limited access to full‐service supermarkets. Less is known about supermarket accessibility within Canadian cities. This article uses the minimum distance and coverage methods to determine supermarket accessibility within the city of Edmonton, Canada, with a focus on high‐need and inner‐city neighborhoods. The results show that for 1999 both of these areas generally had higher accessibility than the remainder of the city, but six high‐need neighborhoods had poor supermarket accessibility. We conclude by examining potential reasons for differences in supermarket accessibility between Canadian, U.S., and U.K. cities.     

Some Aspects of Resource Uncertainty and Their Economic Consequences in Assessment of the 1002 Area of the Arctic National Wildlife Refuge

Natural Resources Research - Exploration ventures in frontier areas have high risks. Before committing to them, firms prepare regional resource assessments to evaluate the potential payoffs. With...     

Chasing a 'loose and baggy monster': almshouses and the geography of charity

This paper goes some way towards redressing the lack of geographical literature on charity through exploring the geography of the British domestic charitable sector. The size and geography of the third sector is outlined, followed by an analysis of how almshouses can be understood as inherently geographical and deeply embedded in local social networks of inclusion as well as exclusion.     

Responses of interrill runoff and erosion rates to vegetation change in southern Arizona

Vegetation change, fi-om grassland to shrubland, has occurred over much of the Sonoran and Chihuahuan Deserts during the past century. The effect of this vegetation change on interrill runoff and erosion was examined by conducting rainfall-simulation experiments on large runoff plots on contemporary grassland and shrubland hillslopes. These experiments show that, compared to the grassland, the interrill portions of shrubland hillslopes (1) have higher runoff rates, (2) experience equilibrium runoff conditions much more frequently, (3) exhibit higher overland flow velocities, and (4) are subject to greater rates of erosion. The environmental change that has led to the vegetation change has been relatively minor, but its geomorphic impact has been substantial.