Reconstructing Holocene palaeoclimate and palaeoceanography in Ìsafjarðardjúp,northwest Iceland,from two fjord records overprinted by relative sea‐level and local hydrographic changes

We reconstruct palaeoclimate and palaeoceanography of the Ísafjarðardjúp fjord system from two cores – one from the inner fjord and one near the fjord mouth – while separating the potential overprinting of relative sea‐level (RSL) and local fjord hydrographic changes on these records. The inner fjord core (B997‐339) reflects local fjord hydrography; the outer fjord core (MD99‐2266) reflects the regional oceanic signal. Glacial marine conditions ended at ca. 10 200 cal. a BP, indicated by both ice‐rafted debris records. The other proxy records show spatial and temporal variability within the fjord system. At the inner fjord site (B997‐339) foraminiferal assemblages and the δ¹⁸O record indicate lowered RSL between ca. 10 600 and 8900 cal. a BP and document the onset of fjord water overturning at ca. 8900 cal. a BP, which obscured the climate record. At the fjord mouth (MD99‐2266) mass accumulation rates suggest lowered RSL between ca. 10 200 and 5500 cal. a BP and local freshwater and/or reduced salinities of the Irminger Current water masses affected the δ¹⁸O signal between ca. 10 200 and 7900 cal. a BP. At MD99‐2266, foraminiferal fauna record the Holocene Thermal Maximum between ca. 8000 and 5700 cal. a BP and the onset of modern oceanic circulation at ca. 7000 cal. a BP. Copyright © 2010 John Wiley & Sons, Ltd.     

The pattern of Ni and Co abundances in lunar olivines

Near liquidus experiments on peridotite and other olivine normative compositions from 1.7 to 6 GPa confirm the applicability of exchange-based empirical models of Ni and Co partitioning between olivine and silicate liquids with compositions close to the liquidus of peridotite. Given that most estimates of lunar bulk composition are peridotitic, the partitioning models thus lend themselves to calculation of olivine compositions produced during the early stages of magma ocean crystallization. Calculation of olivine compositions produced by fractional crystallization of a model lunar magma ocean, initially 700 km deep, reveals a prominent maximum in Ni concentration versus fraction crystallized or Mg’ (molar MgO/(MgO + FeO)), but a pattern of monotonically increasing Co concentration. These patterns qualitatively match the puzzling patterns of Ni and Co concentrations observed in lunar rocks in which forsteritic olivines in magnesian suite cumulates have lower Ni and Co abundances than do less magnesian olivines from low-Ti mare basalts, and olivines from the ferroan anorthosite suite (FAS) have lower Ni, but similar Co to mare basalt olivines.The Ni and Co abundances in olivines from the magnesian suite cumulates can be reconciled in terms of fractional crystallization of a deep magma ocean which initially produces a basal dunite comprised of the hottest and most magnesian olivine overlain by an olivine-orthopyroxene (harzburgite) layer that is in turn overlain by an upper zone of plagioclase-bearing cumulates. The ultramafic portion of the cumulate pile overturns sending the denser harzburgite layer, which later becomes a portion of the green glass source region, to the bottom of the cumulate pile with Ni- and Co-rich olivine. Meanwhile, the less dense, but hottest, most magnesian olivines with much lower Ni and Co abundances are transported upward to the base of the plagioclase-bearing cumulates where subsequent heat transfer leads to melting of mixtures of primary dunite, norite, and gabbronorite with KREEP (a K-REE-P enriched component widely believed to be derived from the very latest stage magma ocean liquid). These hybrid melts have Al₂O₃, Ni, and Co abundances and Mg’ appropriate for parent magmas of the magnesian suite. Ni and Co abundances in the FAS are consistent with either direct crystallization from the magma ocean or crystallization of melts of primary dunite-norite mixtures without KREEP.     

The Record of an Extreme Flood in the Sediments of Montane Lillooet Lake, British Columbia: Implications for Paleoenvironmental Assessment

Severe rainfall in mid October, 2003 produced the largest floods in almost a century of record on rivers in the Cordillera of southwestern British Columbia. Sediment deposited in Lillooet Lake as a result of this event is clearly distinguished by stratigraphy, colour, texture, magnetic properties, and organic content. Each of these physical properties is related to the lacustrine processes, especially turbid underflow, that distributed the sediment through the lake. The flood, which lasted less than a week, delivered 8–12 times the amount of sediment that accumulates in most entire years in the deepest, central parts of the lake. Recognition of events of this type in the stratigraphic record offers a means of assessing the changing nature of extreme hydroclimatic events, and their relation to more ubiquitous, lower-energy processes.     

The bituminous mixtures of Tall-e Abu Chizan: A Vth millennium BC settlement in southwestern Iran

Various bituminous artifacts were excavated from the Tall-e Abu Chizan, a late prehistoric (Middle Susiana to Middle Uruk) settlement on the middle of the Curvy plain, between the Karun River and the Ram Hormoz Plain. All samples dated from the Vth millennium BC and cover three periods: 5000–4700 BC (Late Middle Susiana), 4700–4200 BC (Late Susiana 1) and 4200–3900 BC (Late Susiana 2). The bitumens were studied using the techniques of petroleum geochemistry and were compared both to the unaltered crude oils produced from the main oil fields in the area and to the famous Mamatain oil seeps. All samples are very rich in bitumen (average 46 wt%) which has been biodegraded and oxidized. Despite these alteration phenomena, δ¹³C of asphaltenes occur within a narrow range of less than 1‰ PDB. Biodegradation affected the steranes, terpanes, dibenzothiophenes and mono- and triaromatic steroids. Molecular characteristics of terpanes, especially the occurrence of 18α (H)-oleanane, suggest that the bitumen from Tall-e Abu Chizan is a mixture generated from Cretaceous Kazdhumi and Eocene Pabdeh petroleum source rocks. In that respect, bitumens from Tall-e Abu Chizan belong to the same oil family as oil from the Naft Safid field, which is in the vicinity of the archaeological site. In fact, the bitumen at Tall-e Abu Chizan likely originated from oil seepages at Naft Safid. These oil seeps have not yet been sampled or analysed.     

Stable carbon-isotopic compositions of lipids isolated from the ammonia-oxidizing chemoautotroph Nitrosomonas europaea

For the ammonia-oxidizing bacterium Nitrosomonas europaea, grown autotrophically using semicontinuous culturing, average biomass was depleted in ¹³C relative to CO₂ dissolved in the medium by ca. 20‰ and the total-lipid extract was depleted in ¹³C relative to biomass by 3.7‰. The n-alkyl lipids (weighted average of fatty acids) and isoprenoid lipids (weighted average of hopanoids) were both depleted in ¹³C relative to biomass by about 9‰. The large depletion in the isoprenoid lipids seems to indicate that isotopic fractionations associated with the biosynthesis of methylerythritol phosphate (MEP) affected at least two carbon positions in each isoprene unit. Among the fatty acids, trans-9-hexadecenoic acid was most depleted (13.0‰ relative to biomass), followed by cis-9- hexadecenoic acid (9.6‰) and hexadecanoic acid (6.9‰). Isotopic relationships between the three acids suggest that significant isotope effects were associated with the desaturation and cis to trans isomerization of fatty acids. Given these observations, hopanoids produced by ammonia-oxidizing bacteria growing in natural waters are likely to be depleted in ¹³C by 26–30‰ relative to dissolved CO₂. Since CO₂ at aquatic oxyclines is often depleted in ¹³C, the range of δ values expected for hopanoids is ca. −34‰ to −55‰. The δ values of geohopanoids observed in numerous studies and attributed to unspecified chemoautotrophs fall within this range.     

Tectonics of a fast spreading center: A Deep-Tow and sea beam survey on the East Pacific rise at 19°30′ S

Sea Beam and Deep-Tow were used in a tectonic investigation of the fast-spreading (151 mm yr^-1) East Pacific Rise (EPR) at 19°30 S. Detailed surveys were conducted at the EPR axis and at the Brunhes/Matuyama magnetic reversal boundary, while four long traverses (the longest 96 km) surveyed the rise flanks. Faulting accounts for the vast majority of the relief. Both inward and outward facing fault scarps appear in almost equal numbers, and they form the horsts and grabens which compose the abyssal hills. This mechanism for abyssal hill formation differs from that observed at slow and intermediate spreading rates where abyssal hills are formed by back-tilted inward facing normal faults or by volcanic bow-forms. At 19°30 S, systematic back tilting of fault blocks is not observed, and volcanic constructional relief is a short wavelength signal (less than a few hundred meters) superimposed upon the dominant faulted structure (wavelength 2–8 km). Active faulting is confined to within approximately 5–8 km of the rise axis. In terms of frequency, more faulting occurs at fast spreading rates than at slow. The half extension rate due to faulting is 4.1 mm yr^-1 at 19°30 S versus 1.6 mm yr^-1 in the FAMOUS area on the Mid-Atlantic Ridge (MAR). Both spreading and horizontal extension are asymmetric at 19°30 S, and both are greater on the east flank of the rise axis. The fault density observed at 19°30 S is not constant, and zones with very high fault density follow zones with very little faulting. Three mechanisms are proposed which might account for these observations. In the first, faults are buried episodically by massive eruptions which flow more than 5–8 km from the spreading axis, beyond the outer boundary of the active fault zone. This is the least favored mechanism as there is no evidence that lavas which flow that far off axis are sufficiently thick to bury 50–150 m high fault scarps. In the second mechanism, the rate of faulting is reduced during major episodes of volcanism due to changes in the near axis thermal structure associated with swelling of the axial magma chamber. Thus the variation in fault spacing is caused by alternate episodes of faulting and volcanism. In the third mechanism, the rate of faulting may be constant (down to a time scale of decades), but the locus of faulting shifts relative to the axis. A master fault forms near the axis and takes up most of the strain release until the fault or fault set is transported into lithosphere which is sufficiently thick so that the faults become locked. At this point, the locus of faulting shifts to the thinnest, weakest lithosphere near the axis, and the cycle repeats.     

Watershed structural influences on the distributions of stream network water and solute travel times under baseflow conditions

Watershed structure influences the timing, magnitude, and spatial location of water and solute entry to stream networks. In turn, stream reach transport velocities and stream network geometry (travel distances) further influence the timing of export from watersheds. Here, we examine how watershed and stream network organization can affect travel times of water from delivery to the stream network to arrival at the watershed outlet. We analysed watershed structure and network geometry and quantified the relationship between stream discharge and solute velocity across six study watersheds (11.4 to 62.8 km²) located in the Sawtooth Mountains of central Idaho, USA. Based on these analyses, we developed stream network travel time functions for each watershed. We found that watershed structure, stream network geometry, and the variable magnitude of inputs across the network can have a pronounced affect on water travel distances and velocities within a stream network. Accordingly, a sample taken at the watershed outlet is composed of water and solutes sourced from across the watershed that experienced a range of travel times in the stream network. We suggest that understanding and quantifying stream network travel time distributions are valuable for deconvolving signals observed at watershed outlets into their spatial and temporal sources, and separating terrestrial and in‐channel hydrological, biogeochemical, and ecological influences on in‐stream observations. Copyright © 2016 John Wiley & Sons, Ltd.     

Precursory slope distress prior to the 2010 Mount Meager landslide,British Columbia

In 2010, the south flank of Mount Meager failed catastrophically, generating the largest (53 ± 3.8 × 10⁶ m³) landslide in Canadian history. We document the slow deformation of the edifice prior to failure using archival historic aerial photographs spanning the period 1948–2006. All photos were processed using Structure from Motion (SfM) photogrammetry. We used the SfM products to produce pre-and post-failure geomorphic maps that document changes in the volcanic edifice and Capricorn Glacier at its base. The photographic dataset shows that the Capricorn Glacier re-advanced from a retracted position in the 1980s then rapidly retreated in the lead-up to the 2010 failure. The dataset also documents 60 years of progressive development of faults, toe bulging, and precursory failures in 1998 and 2009. The 2010 collapse was conditioned by glacial retreat and triggered by hot summer weather that caused ice and snow to melt. Meltwater increased pore water pressures in colluvium and fractured rocks at the base of the slope, causing those materials to mobilize, which in turn triggered several secondary failures structurally controlled by lithology and faults. The landslide retrogressed from the base of the slope to near the peak of Mount Meager involving basement rock and the overlying volcanic sequence. Elsewhere on the flanks of Mount Meager, large fractures have developed in recently deglaciated areas, conditioning these slopes for future collapse. Potential failures in these areas have larger volumes than the 2010 landslide. Anticipated atmospheric warming over the next several decades will cause further loss of snow and glacier ice, likely producing additional slope instability. Satellite- and ground-based monitoring of these slopes can provide advanced warning of future landslides to help reduce risk in populated regions downstream.