Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

Mid-latitude electron content modelling: The role of interhemispheric coupling

A modelling study of the electron content of the mid-latitude ionosphere and protonosphere has been carried out for solstice conditions using the mathematical model of Bailey (1983). In the model calculations coupled time-dependent O⁺, H⁺ continuity and momentum equations and O⁺, H⁺ and electron heat balance equations are solved for a magnetic shell extending over both hemispheres. The inclusion of interhemispheric flow of plasma and of heat balance has enabled us to investigate the role of interhemispheric coupling on the electron content and related shape parameters. The computed results are compared with results from slant path observations of the ATS-6 radio beacon made at Lancaster (U.K.) and Boulder, Colorado (U.S.A.).It has been found that the conjugate photoelectron heating has a major effect on the shape of the daily variation of slant slab thickness (τ) and also on the magnitude of the protonospheric content (N_p). Some of the main features of τ are closely related to the sunrise and sunset times in the conjugate ionosphere. Also it is found that night-time increases in total electron content (N_T) and F2 region peak electron density (N_max) in winter are natural consequences of ionization loss at low altitudes causing an enhanced downward flow of plasma from the protonosphere which is coupled to the summer hemisphere. One other important consequence of the coupled protonosphere is that the effects on N_T of the neutral air wind are not much different in winter from those in summer.     

Nitrogen uptake,ammonium oxidation and nitrous oxide (N2O) levels in the coastal waters of western Cook Strait,New Zealand

Vertical measurements of $\text{NH}{}_4{}^{\mathrm{+}}$, $\text{NO}{}_3{}^{\mathrm{?}}$ and N₂O concentrations, $\text{NO}{}_3{}^{\mathrm{?}}$ and $\text{NH}{}_4{}^{\mathrm{+}}$ uptake, and $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom $\text{NO}{}_3{}^{\mathrm{?}}\text{N l}{}^{\mathrm{?1}}$ at the most strongly stratified station whereas $\text{NH}{}_4{}^{\mathrm{+}}$ was relatively constant with depth at all stations (～0.1 μg-atom $\text{NH}{}_4{}^{\mathrm{+}}\text{N l}{}^{\mathrm{?1}}$). The highest rates of $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation generally occurred in the near surface waters and decreased with depth. N₂O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation by nitrifying bacteria may account for about 30% of the total $\text{NH}{}_4{}^{\mathrm{+}}$ utilization (i.e. bacterial+agal) and, assuming oxidation through to $\text{NO}{}_3{}^{\mathrm{?}}$, may supply about 40% of the algal requirements of $\text{NO}{}_3{}^{\mathrm{?}}$ in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton.