Reconstruction of past methane availability in an Arctic Alaska wetland indicates climate influenced methane release during the past ~12,000?years

Atmospheric contributions of methane from Arctic wetlands during the Holocene are dynamic and linked to climate oscillations. However, long-term records linking climate variability to methane availability in Arctic wetlands are lacking. We present a multi-proxy ~12,000?year paleoecological reconstruction of intermittent methane availability from a radiocarbon-dated sediment core (LQ-West) taken from a shallow tundra lake (Qalluuraq Lake) in Arctic Alaska. Specifically, stable carbon isotopic values of photosynthetic biomarkers and methane are utilized to estimate the proportional contribution of methane-derived carbon to lake-sediment-preserved benthic (chironomids) and pelagic (cladocerans) components over the last ~12,000?years. These results were compared to temperature, hydrologic, and habitat reconstructions from the same site using chironomid assemblage data, oxygen isotopes of chironomid head capsules, and radiocarbon ages of plant macrofossils. Cladoceran ephippia from ~4,000?cal?year BP sediments have ??¹³C values that range from ~?39 to ?31??, suggesting peak methane carbon assimilation at that time. These low ??¹³C values coincide with an apparent decrease in effective moisture and development of a wetland that included Sphagnum subsecundum. Incorporation of methane-derived carbon by chironomids and cladocerans decreased from ~2,500 to 1,500?cal?year BP, coinciding with a temperature decrease. Live-collected chironomids with a radiocarbon age of 1,640?cal?year BP, and fossil chironomids from 1,500?cal?year BP in the core illustrate that ??old?? carbon has also contributed to the development of the aquatic ecosystem since ~1,500?cal?year BP. The relatively low ??¹³C values of aquatic invertebrates (as low as ?40.5??) provide evidence of methane incorporation by lake invertebrates, and suggest intermittent climate-linked methane release from the lake throughout the Holocene.     

Patterns of pH change inferred from chrysophyte microfossils in Adirondack and northern New England lakes

The silica-scaled chrysophytes are being used increasingly in paleolimnological studies of lake acidification. This study compares the distribution of scaled chrysophytes in the surface sediment of a calibration set of lakes from the Adirondack Park and from northern New England. With the exception of two taxa, species distributions with respect to pH are similar in the two regions. The stratigraphic distribution of chrysophytes is then compared in five Adirondack and three New England lakes. All the presently acid lakes indicate recent lake acidification, with more acid tolerant chrysophytes increasing in relative frequency in the recent sediments. Because the timing of these species changes is unrelated to any watershed disturbances that may have occurred in the lakes' catchments, atmospheric deposition of acids is believed responsible for these recent pH changes.This is the seventh of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.     

Simulation of geomembrane response to settlement in landfills by using the material point method

Because of the multiple layers of dissimilar materials and large deformations involved in the subsidence of a landfill system, large-scale computer simulation of the geomechanical response to subsidence with the use of conventional numerical methods are problematic. The Material Point (MPM), which was recently developed for dynamic problems such as penetration and perforation, is a newly emerging numerical method. The MPM is modified in this paper to simulate the geomechanical response of a landfill cover system that includes a geomembrane under quasi-static loading conditions. Sample problems, for which an analytical solution is available with certain assumptions, are considered to demonstrate the proposed solution procedure. Future work is discussed based on current research results. Copyright © 1999 John Wiley & Sons, Ltd.     

Crustal structure across the Grand Banks–Newfoundland Basin Continental Margin – II. Results from a seismic reflection profile

New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins.     

Implementation of a second‐order paraxial boundary condition for a water‐saturated layered half‐space in plane strain

A half‐space finite element and a transmitting boundary are developed for a water‐saturated layered half‐space using a paraxial boundary condition. The exact dynamic stiffness of a half‐space in plane strain is derived and a second‐order paraxial approximation of the stiffness is obtained. A half‐space finite element and a transmitting boundary are then formulated. The development is verified by comparison of the dynamic stiffness of impermeable and permeable rigid strip foundations with other published results. The advantage of using the paraxial boundary condition in comparison with the rigid boundary condition is examined. It is shown that the paraxial boundary condition offers significant gain and the resulting half‐space finite element and transmitting boundary can represent the effects of a water‐saturated layered half‐space with good accuracy and efficiency. In addition, the numerical method described herein maintains the strengths and advantages of the finite element method and can be easily applied to demanding problems of soil–structure interaction in a water‐saturated layered half‐space. Copyright © 2010 John Wiley & Sons, Ltd.     

Spring-dashpot-mass models for foundation vibrations

The foundation on deformable soil, which, in general, radiates energy, can be represented in structural dynamics as a simple spring-dashpot-mass model with frequency-independent coefficients. For the two limiting cases of a site, the homogeneous half-space and the homogeneous layer fixed at its base, the coefficients are specified in tables for varying parameters such as ratios of dimensions and Poisson's ratio. Rigid foundations on the surface and with embedment are considered for all translational and rotational motions. In a practical analysis of soil–structure interaction this dynamic model of the foundation is coupled directly to that of the structure, whereby a standard dynamics program is used. © 1997 by John Wiley & Sons, Ltd.     

The sea-surface microlayer of puget sound: Part I. Toxic effects on fish eggs and larvae

The sea surface is an important habitat for the developmental stages (eggs and larvae) of many fish and invertebrates; it is also a concentration point for anthropogenic contaminants entering the sea. Studies were conducted to determine the extent to which the sea surface of Puget Sound was toxic to the early life history stages of fish. Three urban bays with suspected contamination, a rural reference bay, and a Central Sound site were compared. Surface-dwelling eggs and organisms (zooneuston) were collected with a surface-skimming neuston net and their densities enumerated. Sand sole (Psettichthys melanostictus) embryos were exposed in the field and laboratory to the sea-surface microlayer. To develop a useful year-round approach to monitoring sea-surface toxicity, larval development of anchovies, kelp bass, and sea urchins was also evaluated as an indication of sea-surface microlayer toxicity.During the spawning season (February and March), urban boys in Puget Sound had lower concentrations of sand sole eggs and neustonic organisms on the sea surface than did the rural bayor Central Sound reference sites. Compared to the reference sites, laboratory exposure to surface microlayer samples collected from urban bay sites generally resulted in more chromsomal aberrations in developing sole embryos, reduced hatching success of sole larvae, and reduced growth in trout cell cultures. In situ hatching success of sole eggs was reduced by half or more in urban bays compared to reference sites.Toxicity was associated with visible surface slicks and, in urban bays, increased with increasing surface pressure (dynes cm⁻¹). Results to be reported separately (Part II) indicate that toxicity is strongly correlated with the presence of high concentrations of polycyclic aromatic hydrocarbons and metals in the sea-surface microlayer. The toxicity of SMIC samples was similar when evaluated by sole, anchovy, kelp bass, or sea urchin tests. A sea-surface monitoring program could use sea urchin embryos to evaluate site-specific sea-surface toxicity throughout the year.     

Tracking recent recovery from eutrophication in a high arctic lake (Meretta Lake, Cornwallis Island, Nunavut, Canada) using fossil diatom assemblages

Meretta Lake (Resolute Bay, Cornwallis Island, Nunavut, Canada) is a high arctic lake that received raw sewage for almost 50 years from the Canadian Department of Transport Base. The lake was sampled from 1968–72 during the International Biological Programme, as part of the Char Lake Project. As the number of users at the Transport Base declined throughout the 1990s, so too did the lake's nutrient levels, and Meretta Lake is now classified as oligotrophic. A previous diatom-based paleolimnological study revealed marked species assemblage shifts coincident with sewage inputs beginning in the late 1940s; however, because the core was taken at a time when nutrient levels were still relatively high (i.e., 1993), the diatom record did not yet track any signs of recovery. In this present study, we examined fossil diatom assemblages from a sediment core taken in 2001. Our results indicate a shift to the pre-impact diatom assemblages in the most recent sediments, indicating that the paleolimnological record is tracking the decreased nutrient inputs to this high arctic lake, and confirms that no significant lags exist in these largely ice-covered lakes.