Growth of large sulfide structures on the endeavour segment of the Juan de Fuca ridge

Mapping and sampling with DSRV “Alvin” has established that sulfide blocks 0.5 m across, dredged from the axial valley of the Endeavour Segment at 47°57′N, are samples of unusually large sulfide structures. The steep-sided structures, up to 30 m in length, 20 m in height, and 10–15 m across, are localized by venting along normal faults at the base of the western axial valley wall, and are distributed for about 200 m along strike paralleling the 020 trend of the ridge crest. High-temperature fluids (350 to more than 400°C) pass through the massive sulfide structures and enter seawater through small, concentric “nozzle-like” features projecting from the top or the sides of the larger vent structures. Diffuse, low-temperature flow is pervasive in the vicinity of the active sulfide structures, exiting from basalt and sulfide surfaces alike. Evidence of recent volcanic activity is sparse.The two largest samples taken with the dredge would not have been recoverable using the submersible. These samples represent massive, complex portions of the sulfide structures which were not closely associated with rapid high-temperature fluid flow at the time of sampling; they contain textural evidence of sealed hydrothermal fluid exit channels. Mineralogy is dominated by Fe sulfides nnd amorphous silica. Pyrite, marcasite, wurtzite, chalcopyrite, and iss are the most common sulfide phases. Pyrrhotite, galena, and sphalerite are present in trace amounts. Barite, amorphous silica, and chalcedony are the only non-sulfide phases; anhydrite is not observed in any of the dredge samples, although it is common in the chimney-like samples recovered by “Alvin”.Specific mineralogical-textural zones within the dredge samples are anaoogous to individual layers in East Pacific Rise at 21°N and southern Juan de Fuca Ridge samples, with two exceptions: a coarse-grained, highly porous Fe sulfide-rich interior containing sulfidized tubeworm casts, and a 2–5 cm thick zone near the outer margin of the samples dominated by late stage amorphous silica. The porous interior may have formed by dendritic crystal growth from a slowly circulating fluid within a large enclosed chamber. The amorphous silica deposited from a seawater/hydrothermal fluid mixture percolating slowly through the walls of the enclosed chamber; conductive cooling of the fluid as it traversed the walls allowed amorphous silica to precipitate. These silica-rich zones are the densest, most durable portions of the structures and may be responsible for the lasting stability of the large sulfide features.Observations in these samples are consistent with two distinct phases of development. Phase 1 is analogous to chimney growth and construction at 21°N and ends when flow channels become sealed to rapid flow of through-going fluid. The flow is evidently redirected within the structure. Phase 2 includes dissolution of anhydrite and precipitation of amorphous silica during conductive cooling of sluggishly circulating hydrothermal fluid or seawater/hydrothermal fluid mixtures. Evolution of vent structures through phase 2 allows lateral and vertical growth of unusually large structures.     

Watershed structural influences on the distributions of stream network water and solute travel times under baseflow conditions

Watershed structure influences the timing, magnitude, and spatial location of water and solute entry to stream networks. In turn, stream reach transport velocities and stream network geometry (travel distances) further influence the timing of export from watersheds. Here, we examine how watershed and stream network organization can affect travel times of water from delivery to the stream network to arrival at the watershed outlet. We analysed watershed structure and network geometry and quantified the relationship between stream discharge and solute velocity across six study watersheds (11.4 to 62.8 km²) located in the Sawtooth Mountains of central Idaho, USA. Based on these analyses, we developed stream network travel time functions for each watershed. We found that watershed structure, stream network geometry, and the variable magnitude of inputs across the network can have a pronounced affect on water travel distances and velocities within a stream network. Accordingly, a sample taken at the watershed outlet is composed of water and solutes sourced from across the watershed that experienced a range of travel times in the stream network. We suggest that understanding and quantifying stream network travel time distributions are valuable for deconvolving signals observed at watershed outlets into their spatial and temporal sources, and separating terrestrial and in‐channel hydrological, biogeochemical, and ecological influences on in‐stream observations. Copyright © 2016 John Wiley & Sons, Ltd.     

Characterization of hard‐to‐differentiate dune stratification types in the Permian Coconino Sandstone (Arizona,USA)

Dune stratification types, which include grainfall, grainflow and ripple lamination, provide a record of the fine‐scale processes that deposited sediment on palaeo‐dune foresets. While these facies are relatively easy to distinguish in some cross‐bedded sandstones, for others – like the Permian Coconino Sandstone of northern and central Arizona – discrete stratification styles are hard to recognize at the bedding scale. Furthermore, few attempts have been made to classify fine‐scale processes in this sandstone, despite its renown as a classic aeolian dune deposit and Grand Canyon formation. To interpret depositional processes in the Coconino Sandstone, cross‐bed facies were characterized using a suite of sedimentary textures and structures. Bedding parameters were described at multiple scales via a combination of field and laboratory methods, including annotated outcrop photomosaics, strike and dip measurements, sandstone disaggregation and laser‐diffraction particle analysis, high‐resolution scans of thin sections, and scanning electron microscopy. Cross‐beds were observed to be laterally extensive along‐strike, with most dip angles ranging from the mid‐teens to mid‐twenties. While some cross‐bed sets are statistically coarser near their bases, others exhibit no significant vertical sorting trends. Both massive and laminated textures are visible in high‐resolution scans of thin sections, but laminae contacts are commonly indistinct, making normal and reverse grading difficult to define. Diagenetic features, such as stylolite seams and large pores, are also present in some samples and might indicate alteration of original textures like detrital clay laminae and carbonate minerals. Observed textures and sedimentary structures suggest that the cross‐beds may consist of grainflow and grainfall deposits, but these remain difficult to differentiate at outcrop and thin‐section scales. This characterization of fine‐scale processes will play a critical part in the development of depositional models for the Coconino Sandstone and elucidate interpretations for similar cross‐bedded formations.     

Laboratory and case studies of thermal cycling and stored strain on the stability of selected marbles

Studies of marble panels from the exterior of two buildings document the processes leading to bowing of the material. Bowing of panels is most extensive in those areas that are exposed to direct or reflected thermal energy. The thermal anisotropic behavior of calcite results in grain-boundary separation, grain sliding and microfracturing. The resulting loss of strength is one factor leading to bowing. The development of bows further reduces the panel strength as the outer portions elongate by inelastic deformation mechanisms. Laboratory experiments cycling marble samples for over 200 cycles at three temperatures up to 107°C above room conditions show similar strength losses as the natural situation. The second factor contributing to the bowing process is the release of residual elastic strain. The strain is in part stored in the marble from its geologic history, but may also be accumulated during thermal cycling due to the properties of calcite. Marble panels have been found to bow when stored outside, but not attached to any framework, indicating that the release of residual strain is a critical factor in producing the bows.     

The ductility reduction factor in the seismic design of buildings

This paper presents new trends in the relationship between the ductility reduction factor and the ductility demand in the seismic design of buildings. A total of 4860 inelastic time-history analyses were carried out to study this relationship using 60 single-degree-of-freedom models excited by an ensemble of 81 earthquake accelerogram records from around the world. The asymmetrical distribution of the results highlighted the inaccuracies associated with assuming a normal distribution simply described by the mean and standard deviation to represent the data. A probability of exceedence approach has been used based on counting the number of occurrences the ductility demand exceeds a specified level. The ductility reduction factors developed in this study are consistent with other studies in the long-period range but are different in the short-period range. The ductility reduction factor for very short period buildings of limited ductility has been found to be greater than previously predicted. © 1998 John Wiley & Sons, Ltd.     

Tides in the Tongan Region of the Pacific Ocean

Tidal levels and currents in the Tongan region of the Pacific were simulated using a two-dimensional frequency-domain finite element model. The eight major diurnal and semidiurnal tidal constituents were modeled successfully, using open boundary conditions taken from a global tidal model based on the Topex/Poseidon satellite altimeter. Comparison of model results with observations from the single tide gauge site in the area were later used to adjust the boundary conditions. The validity of omitting horizontal eddy viscosity from the finite element model was checked by running an equivalent finite difference model. The results show that although the submarine Tongan ridge does not appear to trap tidal energy, there are residual tidal currents and possible recirculations which are capable of influencing biological productivity around Tonga. The model results are reduced to a simple method for predicting tidal heights in outlying areas, based only on the tidal calendar for the capital, Nuku'alofa.     

Beneficiation and digestion of Georgia offshore phosphates

Abstract

The U.S. Bureau of Mines conducted beneficiation and digestion tests to evaluate the potential of recovering P₂O₅ from an apatite deposit located 10 nautical miles offshore Savannah, GA, in the Exclusive Economic Zone (EEZ). A 1.8 metric ton sample containing 1.0–1.5% P₂O₅ was obtained in a cooperative drilling project involving the Bureau of Mines, the Marine Minerals Technology Center‐Continental Shelf Division, the Minerals Management Service, and the Georgia Nonenergy Minerals Offshore Task Force. Beneficiation methods were evaluated with the goal of producing a 29–31% P₂O₅ concentrate with a CaO: P₂O₅ratio of less than 1.6: 1. These specifications were obtained using a combination of gravity separation and flotation. Comparative leaching tests conducted using EEZ, Idaho, and Florida phosphate concentrates showed that these EEZ phosphates behaved similarly to land‐based phosphates. The results suggest that as land‐based phosphate deposits are depleted, ocean phosphates represent a feasible alternate source.