Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Palaeomagnetism of the Tudor gabbro, Ontario: evidence for divergence between Grenvillia and interior Laurentia

Summary. After thermal and alternating field (AF) cleaning, the characteristic high blocking temperature A component of natural remanent magnetization (NRM) of the Tudor gabbro of southern Ontario has a mean direction D = 326°, I =–46° ( k = 132, α₉₅= 4.8°, N = 8 sites). The corresponding palaeopole, 133°E, 12°N ( dp = 4°, dm = 6°), confirms the palaeopole 137°E, 17°N (α₉₅= 8.4°) reported earlier by Palmer & Carmichael, based on AF cleaning only. The A NRM has unblocking temperatures > 515–525°C which exceed the estimated 500°C peak temperature reached locally during ∼ 1050 Ma Grenvillian regional metamorphism. The A NRM therefore predates metamorphism and is probably a primary thermoremanence (TRM). The age of the Tudor NRM has previously been taken to be about 675 Ma, but recent ⁴⁰Ar/³⁹Ar dating by Baksi has shown that this is the time of post-metamorphic cooling to 200–250°C. Hornblendes record initial cooling of the intrusion to 590±20°C at 1110 Ma and this is the best estimate of the age of the A remanence. Successful Thellier-type palaeointensity determinations on 11 Tudor samples confirm that the A NRM is a TRM and indicate a palaeofield at this time of 18–27 μT, about 50–70 per cent of the present field intensity at 27° magnetic latitude. The anomalous Tudor A palaeopole, which lies well to the west of both 1000–800 Ma Grenvillian palaeopoles and 1100–1050 Ma poles from Interior Laurentia, is interpreted as recording divergence between Grenvillia and Interior Laurentia just before the Grenvillian orogeny, rather than a post-metamorphic extension of the apparent polar wander path as previously assumed.     

SEVEN NEW BULK CHEMICAL ANALYSES OF AUBRITES

New bulk chemical analyses are given of Aubres, Bishopville, Bustee, Khor Temiki, Norton County, Peña Blanca Spring and Shallowater, Selective attack by dry chlorine (350°C) on magnetic and non-magnetic fractions was used to determine the distribution of some normally lithophile elements (Al, Ca, Cr, K, Mg, Mn, Na, P and Ti) between silicate and sulphide groups of minerals.     

Bursts of type N in Jupiter's decametric radio spectra

Dynamic spectra of Jupiter's decametric emission often display narrow-band features, referred to as events of type N (Carr et al., 1983). The average bandwidth of these emissions is in the vicinity of 200 kHz, their durations are typically in the decasecond range, and their f-t slopes are small and random. Although the N-bursts can be described as narrow-band L-bursts, it seems that they are realted to S-bursts in their area of occurrence in the Io-B region, the durations of the emission envelopes, and their bandwidths. Possible implications are discussed.     

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

The determination and analysis of the orbit of NIMBUS 1 ROCKET, 1964-52B: Part 2: Variations in orbital eccentricity

The influence of aerodynamic drag and the geopotential on the motion of the satellite 1964-52B is considered. A model of the atmosphere is adopted that allows for oblateness, and in which the density behaviour approximates to the observed diurnal variation. A differential equation governing the variation of the eccentricity, e, combining the effects of air drag with those of the Earth's gravitational field is given. This is solved numerically using as initial conditions 310 computed orbits of 1964-52B.The observed values of eccentricity are modified by the removal of perturbations due to luni-solar attraction, solid Earth and ocean tides, solar radiation pressure and low-order long-periodic tesseral harmonic perturbations. The method of removal of these effects is given in some detail. The behaviour of the orbital eccentricity predicted by the numerical solution is compared with the modified observed eccentricity to obtain values of atmospheric parameters at heights between 310 and 430 km. The daytime maximum of air density is found to be at 14.5 hours local time. Analysis of the eccentricity near 15th order resonance with the geopotential yielded values of four lumped geopotential harmonics of order 15, namely: $\text{10}{}^9\text{C}{}^{\mathrm{1,0}}{}_{15}\text{= ?78.8 ± 7.0}$, $\text{10}{}^9\text{S}{}^{\mathrm{1,0}}{}_{15}\text{= ?69.4 ± 5.3}$, $\text{10}{}^9\text{C}{}^{\mathrm{?1,2}}{}_{15}\text{= ?41.6 ± 3.5}$$\text{10}{}^9\text{S}{}^{\mathrm{?1,2}}{}_{15}\text{= ?26.1 ± 8.9}$, at inclination 98.68°.     

Diurnal variation of the dayside, ionospheric, mid-latitude trough in the southern hemisphere at 800 km: Model and measurement comparison

Our high latitude ionospheric model predicts the existence of a pronounced “dayside” trough in plasma concentration equatorward of the auroral oval in both the Northern and Southern Hemispheres for solar maximum, winter, and low geomagnetic activity conditions. The trough in the Southern Hemisphere is much deeper than that in the Northern Hemisphere, with the minimum trough density at 800 km being 2 × 10³ cm⁻³ in the Southern Hemisphere and 10⁴ cm⁻³ in the Northern Hemisphere. The dayside trough has a strong longitudinal (diurnal) dependence and appears between 11:00 and 19:00 U.T. in the Southern Hemisphere and between 02:00 and 08:00 U.T. in the Northern Hemisphere. This dayside trough is a result of the auroral oval moving to larger solar zenith angles at those universal times when the magnetic pole is on the antisunward side of the geographic pole. As the auroral ionization source moves to higher geographic latitudes, it leaves a region of declining photoionization on the dayside. For low convection speeds, the ionosphere decays and a dayside trough forms. The trough is deeper in the Southern Hemisphere than in the Northern Hemisphere because of the greater offset between the geomagnetic and geographic poles. Satellite data taken in both the Northern and Southern Hemispheres confirm the gross features of the dayside trough, including its strong longitudinal dependence, its depth, and the asymmetry between the Northern and Southern Hemisphere troughs.