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This study uses 2 years of data from a detailed weekly water sampling programme in a 11·4 km2 upland peat catchment in the Northern Pennines, UK. The sampling comprised precipitation, soil‐water samples and a number of streams, including the basin outlet. Samples were analysed for: pH, conductivity, alkalinity, Na, K, Ca, Mg, Fe, Al, Total N, SO4, Cl and colour. Principal component analysis (PCA) was used to identify end‐members and compositional trends in order to identify controls on the development of water composition. The study showed that the direct use of PCA had several advantages over the use of end‐member mixing analysis (EMMA) as it combines an analysis of mixing and evolving waters without the assumption of having to know the compositional sources of the water. In its application to an upland peat catchment, the study supports the view that shallow throughflow at the catotelm/acrotelm boundary is responsible for storm runoff generation and shows that baseflow is controlled by cation exchange in the catotelm and mixing with a base‐rich groundwater. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
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In an attempt to discover planetary eclipses, we observed the open cluster NGC 7086. On one night we observed the cluster and standard stars through the B and V filters, enabling us to make a colour-magnitude diagram. Plots of the differential magnitudes were inspected for variability, but no planetary eclipses were found. New variable stars were discovered and their light curves show some of them to be eclipsing binary stars. The location on the colour-magnitude diagram of some of the variable stars is consistent with cluster membership.  相似文献   
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Armoured jawless fish, or 'ostracoderms', lived 450–360 million years ago, and display unusual morphologies, unlike any modern fish group. Since they left no living descendants, their mode of swimming has, until recently, remained speculative, although this is a crucial question as the first true pectoral fins evolved within the 'ostracoderms'. The discovery of the oldest-known fish trails, from the Early Devonian (400 million year old) 'Lower Old Red Sandstone' of south-east Wales offers new insights into the swimming behaviour of these early fish, notably the osteostracan 'ostracoderms' (or cephalaspids), whose horseshoe-shaped head and paddle-shaped pectoral fins have remained a functional riddle.  相似文献   
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Klauea historical summit lavas have a wide range in matrix 18OVSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, 18O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine 18O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma 18O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine 18O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination  相似文献   
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