The Development of Laser Ablation ICP-MS and Calibration Strategies: Examples from the Analysis of Trace Elements in Volcanic Glass Shards and Sulfide Minerals

This contribution presents a review of the recent developments in laser ablation inductively coupled plasma-mass spectrometry. We describe the important developments which have occurred in the laser systems used, leading to a spatial resolution of around 20 (im, and give an overview of the major instrument developments which have affected the geological applications of laser ablation ICP-MS. We describe the calibration of laser ablation for the analysis of trace elements in two different matrices: volcanic glass shards and sulfide minerals. We show how single glass shards can be analysed using the National Institute of Standards and Technology (NIST) glass certified reference materials for calibration and demonstrate the effect of using single spot analyses compared to rastering of the calibration sample. We show the importance of inter-shard variation and demonstrate that averaged single shard analyses produce data which compare well with bulk analyses. The calibration of the laser system for sulfide mineral analysis is discussed and two different strategies are proposed, one using spiked pressed powder pellets of sulfides and the other metal reference materials. We present conclusions and recommendations for the calibration of laser ablation ICP-MS instruments.     

On the Fréchet differentiability of the one-dimensional magnetotellurics problem

Summary. This paper proves that, subject to certain assumptions, the one-dimensional magnetotelluric response function and the associated electric fields are Fréchet differentiable with respect to the conductivity function. The flaw in the proof offered by an earlier author is explained.     

Physical studies of asteroids XXX: the asteroid 153 Hilda

The asteroid 153 Hilda was studied by photometric, spectroscopic and polarimetric observations during the apparition in 1992. The rotation period was determined to 5.11 hours with a lightcurve amplitude of 0.05 magnitudes. From our spectrum we find 153 Hilda to be of taxonomic type P. The polarization value of -0.23 at a phase angle of 3.2 degrees seems normal for a P-type asteroid. Long term integrations of the orbit shows that it is stable over time intervals of several million years.Partly based on observations collected at the European Southern Observatory, La Silla, Chile     

The project “spice”

Proposed to both the French and the European Space Agency as one possible small mission, SPICE is a project for a dedicated small satellite for a near-IR spectroscopic all-sky survey. The instrument would cover the spectral range 1.8 - 3.6µm, possibly extended to 1.8 - 7µm, at a resolution of 100, with pixels of 1 arc-min. The excellent sensitivity (0.02 MJy sr-1) results from: i) the quasi-zero level of background due to the efficient passive cooling of the whole experiment; ii) the use of large format arrays; iii) the non-stop observing mode (drift-scanning). The spectral domain, complementing the one of ISO, partially opaque from the ground, is specially rich in spectral features tracing stars and all components of the Interstellar Medium (molecular, atomic and ionized gas, dust). With a cooling below 80 K of the focal instrument, then it becomes possible to consider doubling the spectral domain and to cover the whole 1.8 - 7µm range.     

Spectroscopic evolution of nova LW serpentis 1978 during its early decline

Optical spectroscopic data are presented on nova LW Serpentis 1978, obtained during its decline fromV 9.0 to ≃10.2 (compared to a value of ∼ 8.0 at recorded maximum). The spectrum and its evolution compare well with a typical nova, though the principal absorption (∼ −750 km s^−l) was very weak in comparison with the diffuse-enhanced absorption (∼ −1300 km s⁻¹). The principal absorption could be identified only in the lines of O I λλ7774, 8446, and in moderate-resolution observations of Hα. The salient features of spectral evolution follow: The near-infrared triplet of Ca n continuously weakened. O I λ8446 was always brighter than O I λ 7774, indicating continued importance of Lyman Β fluorescence. The lines due to [O I], [N II] and N n brightened considerably near the end of our observations (37 days from maximum). The Hα emission line was asymmetric all through with more emission towards the red. Its emission profile showed considerable structure. Based on the individual peaks in the Hα line profile, a kinematical model is proposed for the shell of LW Ser. The model consists of an equatorial ring, and a polar cone on the side away from the earth. The nearer polar cone did not show significant emission of Hα during our observations. The polar axis of the shell is inclined at a small angle (∼ 15‡) to the line of sight.     

关于天气预报问题

天气预告昔日各国完全采用经验法(Empirical method);自挪威学旅之气团分析,及极面学说发生以後,最近各国已次续采纳。我国在十年前,竺可桢氏已有介绍文章,吕炯先生在数年前亦曾应用极面学说分析长江下游之风暴。其後有黄厦千,赵九章,朱炳海诸先生亦曾致力於气团分析工作,皆具卓见。近日有涂长望先生之中国气团分     

Including spatial distribution in a data‐driven rainfall‐runoff model to improve reservoir inflow forecasting in Taiwan

Multi‐step ahead inflow forecasting has a critical role to play in reservoir operation and management in Taiwan during typhoons as statutory legislation requires a minimum of 3‐h warning to be issued before any reservoir releases are made. However, the complex spatial and temporal heterogeneity of typhoon rainfall, coupled with a remote and mountainous physiographic context, makes the development of real‐time rainfall‐runoff models that can accurately predict reservoir inflow several hours ahead of time challenging. Consequently, there is an urgent, operational requirement for models that can enhance reservoir inflow prediction at forecast horizons of more than 3 h. In this paper, we develop a novel semi‐distributed, data‐driven, rainfall‐runoff model for the Shihmen catchment, north Taiwan. A suite of Adaptive Network‐based Fuzzy Inference System solutions is created using various combinations of autoregressive, spatially lumped radar and point‐based rain gauge predictors. Different levels of spatially aggregated radar‐derived rainfall data are used to generate 4, 8 and 12 sub‐catchment input drivers. In general, the semi‐distributed radar rainfall models outperform their less complex counterparts in predictions of reservoir inflow at lead times greater than 3 h. Performance is found to be optimal when spatial aggregation is restricted to four sub‐catchments, with up to 30% improvements in the performance over lumped and point‐based models being evident at 5‐h lead times. The potential benefits of applying semi‐distributed, data‐driven models in reservoir inflow modelling specifically, and hydrological modelling more generally, are thus demonstrated. Copyright © 2012 John Wiley & Sons, Ltd.     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of tuff vents in the Campi Flegrei caldera (southern Italy): toward a new chronostratigraphic reconstruction of the Holocene volcanic activity

The Campi Flegrei hosts numerous monogenetic vents inferred to be younger than the 15 ka Neapolitan Yellow Tuff. Sanidine crystals from the three young Campi Flegrei vents of Fondi di Baia, Bacoli and Nisida were dated using ⁴⁰Ar/³⁹Ar geochronology. These vents, together with several other young edifices, occur roughly along the inner border of the Campi Flegrei caldera, suggesting that the volcanic conduits are controlled by caldera-bounding faults. Plateau ages of ∼9.6 ka (Fondi di Baia), ∼8.6 ka (Bacoli) and ∼3.9 ka (Nisida) indicate eruptive activity during intervals previously interpreted as quiescent. A critical revision, involving calendar age correction of literature ¹⁴C data and available ⁴⁰Ar/³⁹Ar age data, is presented. A new reference chronostratigraphic framework for Holocene Phlegrean activity, which significantly differs from the previously adopted ones, is proposed. This has important implications for understanding the Campi Flegrei eruptive history and, ultimately, for the evaluation of related volcanic risk and hazard, for which the inferred history of its recent activity is generally taken into account.     

Recent crustal subsidence at Yellowstone Caldera,Wyoming

Following a period of net uplift at an average rate of 15±1 mm/year from 1923 to 1984, the east-central floor of Yellowstone Caldera stopped rising during 1984–1985 and then subsided 25±7 mm during 1985–1986 and an additional 35±7 mm during 1986–1987. The average horizontal strain rates in the northeast part of the caldera for the period from 1984 to 1987 were: ₁ = 0.10 ± 0.09 strain/year oriented N33° E±9° and ₂ = 0.20 ± 0.09 strain/year oriented N57° W±9° (extension reckoned positive). A best-fit elastic model of the 1985–1987 vertical and horizontal displacements in the eastern part of the caldera suggests deflation of a horizontal tabular body located 10±5 km beneath Le Hardys Rapids, i.e., within a deep hydrothermal system or within an underlying body of partly molten rhyolite. Two end-member models each explain most aspects of historical unrest at Yellowstone, including the recent reversal from uplift to subsidence. Both involve crystallization of an amount of rhyolitic magma that is compatible with the thermal energy requirements of Yellowstone's vigorous hydrothermal system. In the first model, injection of basalt near the base of the rhyolitic system is the primary cause of uplift. Higher in the magmatic system, rhyolite crystallizes and releases all of its magmatic volatiles into the shallow hydrothermal system. Uplift stops and subsidence starts whenever the supply rate of basalt is less than the subsidence rate produced by crystallization of rhyolite and associated fluid loss. In the second model, uplift is caused primarily by pressurization of the deep hydrothermal system by magmatic gas and brine that are released during crystallization of rhyolite and them trapped at lithostatic pressure beneath an impermeable self-sealed zone. Subsidence occurs during episodic hydrofracturing and injection of pore fluid from the deep lithostatic-pressure zone into a shallow hydrostatic-pressure zone. Heat input from basaltic intrusions is required to maintain Yellowstone's silicic magmatic system and shallow hydrothermal system over time scales longer than about 10⁵ years, but for the historical time period crystallization of rhyolite can account for most aspects of unrest at Yellowstone, including seismicity, uplift, subsidence, and hydrothermal activity.