IMPACT: an implicit time integration scheme for chemical species and families

The implicit time integration scheme of Stott and Harwood (1993) was proposed as an efficient scheme for use in three-dimensional chemical models of the atmosphere. The scheme was designed for chemistry schemes using chemical families, in which species with short lifetimes are grouped into longer-lived families. Further study with more complex chemistry, more species and reactions showed the scheme to be non-convergent and unstable under certain conditions; particularly for the perturbed chemical scenarios of polar stratospheric winters. In this work the scheme has been improved by revising the treatment of families and the convergence properties of the scheme. The new scheme has been named IMPACT (IMPlicit Algorithm for Chemical Time-stepping). It remains easy to implement and produces simulations that compare well with integrations using more accurate higher order schemes.     

Soil water dynamics under different forest vegetation cover: Implications for hillslope stability

Though it is well known that vegetation affects the water balance of soils through canopy interception and evapotranspiration, its hydrological contribution to soil hydrology and stability is yet to be fully quantified. To improve understanding of this hydrological process, soil water dynamics have been monitored at three adjacent hillslopes with different vegetation covers (deciduous tree cover, coniferous tree cover, and grass cover), for nine months from December 2014 to September 2015. The monitored soil moisture values were translated into soil matric suction (SMS) values to facilitate the analysis of hillslope stability. Our observations showed significant seasonal variations in SMS for each vegetation cover condition. However, a significant difference between different vegetation covers was only evident during the winter season where the mean SMS under coniferous tree cover (83.6 kPa) was significantly greater than that under grass cover (41 kPa). The hydrological reinforcing contribution due to matric suction was highest for the hillslope with coniferous tree cover, while the hillslope with deciduous tree cover was second and the hillslope with grass cover was third. The greatest contributions for all cover types were during the summer season. During the winter season, the wettest period of the monitoring study, the additional hydrological reinforcing contributions provided by the deciduous tree cover (1.5 to 6.5 kPa) or the grass cover (0.9 to 5.4 kPa) were insufficient to avoid potential slope failure conditions. However, the additional hydrological reinforcing contribution from the coniferous tree cover (5.8 to 10.4 kPa) was sufficient to provide potentially stable hillslope conditions during the winter season. Our study clearly suggests that during the winter season the hydrological effects from both deciduous tree and grass covers are insufficient to promote slope stability, while the hydrological reinforcing effects from the coniferous tree cover are sufficient even during the winter season. Copyright © 2018 John Wiley & Sons, Ltd.     

An Open,Object-Based Framework for Generating Anisotropy in Sedimentary Subsurface Models

The spatial distribution of hydraulic properties in the subsurface controls groundwater flow and solute transport. However, many approaches to modeling these distributions do not produce geologically realistic results and/or do not model the anisotropy of hydraulic conductivity caused by bedding structures in sedimentary deposits. We have developed a flexible object-based package for simulating hydraulic properties in the subsurface—the Hydrogeological Virtual Realities (HyVR) simulation package. This implements a hierarchical modeling framework that takes into account geological rules about stratigraphic bounding surfaces and the geometry of specific sedimentary structures to generate realistic aquifer models, including full hydraulic-conductivity tensors. The HyVR simulation package can create outputs suitable for standard groundwater modeling tools (e.g., MODFLOW), is written in Python, an open-source programming language, and is openly available at an online repository. This paper presents an overview of the underlying modeling principles and computational methods, as well as an example simulation based on the Macrodispersion Experiment site in Columbus, Mississippi. Our simulation package can currently simulate porous media that mimic geological conceptual models in fluvial depositional environments, and that include fine-scale heterogeneity in distributed hydraulic parameter fields. The simulation results allow qualitative geological conceptual models to be converted into digital subsurface models that can be used in quantitative numerical flow-and-transport simulations, with the aim of improving our understanding of the influence of geological realism on groundwater flow and solute transport.     

Schotcrete as permanent lining for the Furka base tunnel

Summary The lining concept of the 15.4 km long one-track Furka railway tunnel is described with particular emphasis on shotcrete application as a permanent support Altogether 70000 m³ dry aggregate/ cement mix and 115000 rock bolts have been applied. The tunnel was lined at a rate of approx. 400 tunnel metres per month using up to five shotcrete machines simultaneously. Systematic quality control throughout the construction work indicated an average uniaxial compressive strength of shotcrete of 40 N/mm². The support requirements were grouped into 16 different classes and an additional special class accounting for extreme geological conditions in some relatively short stretches.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

Formation of large-scale dust lanes in spiral arms of galaxies

We consider the interaction of interstellar dust grains with a galactic shock in the gaseous component. Typical parameters of dust grains and spiral density waves imply that the formation of large-scale dust lanes at the front of a galactic shock is possible only in models taking into account a self-focusing phenomenon. In the case of an isothermal flow of interstellar gas through a spiral arm in a model with a gaseous disk of variable thickness, dust lanes can be projected onto the region of increased gas density, although this is not associated with a galactic shock. The dust density peak derived from the classical model of a galactic shock (isothermal flow and a constant thickness of the gaseous disk) is appreciably shifted downstream of the gas flow, so that it does not outline the gas density maximum.