Source rock-crude oil correlation by isotopic type-curves

An isotopic type-curve has been defined based on the ${}^{13}\text{C}{}^{12}\text{C}$ ratios of the saturated, aromatic, heterocomponent (NOSs), and asphaltene fractions of crude oils. These fractions show ¹³C enrichments with increasing polarity or polarizability. This systematic pattern can be used to estimate the ${}^{13}\text{C}{}^{12}\text{C}$ ratio of the kerogen from which the oil had been generated. Genetically associated source rock oil pairs have been used to show that the difference between the measured and the estimated δ-values of kerogen is about ?0.5%., and between the δ-values of the kerogen and the asphaltene fraction is approximately +0.6%.     

The chemistry of orthophosphate uptake from seawater on to calcite and aragonite

The chemistry of orthophosphate uptake from synthetic seawater onto the surfaces of synthetic calcite, aragonite and low-magnesium biogenic calcite has been studied, in order to elucidate the kinetics of the process (generally believed to be the major control of dissolved reactive phosphate in carbonate-rich marine sediments). Our results differ from those obtained by others, who have studied orthophosphate uptake in low ionic strength solutions and at much higher supersaturations relative to apatite.In both ‘free drift’ and chemostat experiments, Mg and F have only a minor effect on the reaction rate. Even at constant solution composition the rate of orthophosphate uptake was found to decrease by 10⁶ over a two week period. The data from the ‘free drift’ experiments can be fitted to the Elovich equation. This indicates that the kinetics observed for this reaction can be explained by an exponential decrease in available surface reaction sites and/or a linear increase in the activation energy associated with chemisorption as the reaction proceeds.     

Amino acid composition of organic matter associated with carbonate and non-carbonate sediments

Amino acids comprise from 15 to 36% by weight of humic substances from carbonate and non-carbonate sediments. Humic and fulvic acids extracted from carbonate sediments are characterized by an amino acid composition consisting primarily of the acidic amino acids, aspartic and glutamic acid. Humic substances from non-carbonate sediments have a distinctly different amino acid composition consisting primarily of glycine and alanine. Amino acid analyses of various molecular weight fractions of fulvic acids extracted from carbonates show that lower molecular weight fractions have appreciably higher relative abundances of the acidic amino acids compared to higher molecular weight fractions. Based on typical values for carboxyl group content in humic substances, acidic amino acids may be a significant contributor of these functional groups. Carbonate surfaces appear to selectively adsorb aspartic acid-enriched organic matter while non-carbonates do not have this property.     

Fair weather and storm sand transport on the Long Island, New York, inner shelf

Both spring-summer and fall-winter sand transport have been observed on the Long Island, New York, inner shelf at water depths of 20-22 m using a radio-isotope sand tracer system. The extent of dispersal of the tagged, fine sand was measured at 3 week intervals in two 70 day experiments. In the late spring and early summer, movement was primarily diffusive in nature, extending 100 m around the line of tracer injection, while late fall-winter patterns had strong advective features, including an ellipsoidal outline extending approximately 1500 m westward of the injection points after the passage of several storms with strong northeasterly winds. Near-bottom current observations made with Savonius rotor sensors identify the event responsible for the bulk of the transport over the 135 day observation period as a storm flow of 2 days duration. Tracer and current observations together suggest that westward winter storm flow along the Long Island shelf is the major mechanism of sand transport at these depths on a yearly time scale. A least-squares fit of several of the observed winter patterns with a plume model yields average sediment mass flux lower bounds of 3.2 × 10^?3 gm/cm/sec and 1.7 × 10^?1 gm/cm/sec for ‘typical’ and extreme winter storm activity.     

The formation and clay mineral reactions of melanoidins

Sugars and amino acids condense readily to form polymers known as melanoidins that closely resemble natural humic substances. In this study melanoidins are formed by reacting glucose with each of three amino acids: glutamic acid, valine and lysine. The basic amino acid, lysine, reacts with glucose at a much greater rate than either of the other two compounds. The chemical properties of the melanoidins are strongly influenced by the amino acid from which they are formed. The nitrogen contents, acidities and electrophoretic behavior of the polymers all reflect functional group distributions inherited from the amino acids. These chemical differences strongly influence the extent of association of the melanoidins with kaolinite and montmorillonite clay minerals. Laboratory simulations suggest that melanoidin formation may be favored in marine environments where basic amino acids should preferentially condense with sugars to form nitrogen-rich polymers that have a great affinity for clay mineral surfaces.     

Absolute spectrophotomery of comets 1973XII and 1975IX: II. Profiles of the Swan bands

Absolute spectrophotometric measurements of the Swan bands of two comets have been compared with computed synthetic spectra using modern Franck-Condon and Hönl-London factors, and varying rotational, vibrational, and electronic excitation temperatures. Rotational and vibrational temperatures were obtained for the comets. Although the electronic excitation temperature and the molecular column density cannot be separated, a relationship is found between these two quantities. A review is made of recent determinations of column densities for CN in comets.     

Radiative transfer in spherical shell atmospheres: I. Rayleigh scattering

A comparison is made between the plane-parallel approximation and the more realistic spherical shell approximation for the radiance reflected from a planetary atmosphere. In this paper we have considered a planet of radius 6371 km (the Earth) with a homogeneous, conservative, Rayleigh scattering atmosphere extending to a height of 100 km. We have found significant departures from the plane-parallel approximation. Radiance versus height distributions for both single and multiple scattering are presented. Results are presented for the fractional radiance from altitudes in the atmosphere which contribute to the total unidirectional reflected radiance at the top of the atmosphere. We have referred to this as the radiance versus height distribution in the sequel. These data will be very useful for both remote sensing applications and planetary spectroscopy. We have also found that gross violations of the principle of reciprocity do occur in the spherical shell approximation.