Internal recycling of particle reactive organic chemicals in the Chesapeake Bay water column

Hydrophobic organic contaminants (HOCs) may be used as tracers of particle dynamics in aquatic systems. Internal cycling of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were studied in the mesohaline Chesapeake Bay to assess the role of resuspension in maintaining particle and contaminant inventories in the water column, and to compare settling and suspended particle characteristics. Direct measurements of sediment resuspension and settling conducted in conjunction with one of the sediment trap deployments indicate reasonable agreement between measurements of particle flux using the two different methods. Organic carbon and PCB concentrations in settling solids collected in near-surface sediment traps were remarkably lower than concentrations in suspended particles collected by filtration during the trap deployments, but higher PAH concentrations were found in the settling particles. The different behaviors of PAHs and PCBs in the settling particles are due to their different source types and association to different types of particles. Sediment trap collections in near bottom waters were dominated by resuspension. Resuspension fluxes of HOCs measured 2 m above the bay bottom were as high as 2.5 μg/m² day for total PCBs and 15 μg/m² day for fluoranthene, and were 25 and 10 times higher than their settling fluxes from surface waters, respectively. HOC concentrations in the near bottom traps varied much less between trap deployments than HOC concentrations in the surface traps, indicating that the chemical composition of the resuspended particles collected in the near bottom traps was more time-averaged by repeated resuspension than the surface particles.     

Modelling the DC electrical response of fully and partially saturated Permo-Triassic sandstone

Results from a laboratory investigation into the electrical properties of fully and partially saturated Wildmoor Triassic Sandstone have been modelled using the Archie, Waxman–Smits and Hanai–Bruggeman equations. The results demonstrate the limitation of using simple relationships to describe samples when the matrix resistivity ρ_r is not significantly greater than the saturating electrolyte resistivity ρ_w. In these situations Archie's parameters m and n are not accurately determined. Conversely, the more sophisticated Waxman–Smits and Hanai–Bruggeman models provide parameters that better describe the electrical properties of the rock and are able to identify heterogeneity between samples that would otherwise be missed. The ranges of values for matrix resistivity (49 < ρ_r < 161 Ωm) and cementation factor (1.6 < m < 2.1) obtained from the Hanai–Bruggeman model indicate significant variation between samples. Comparison of laboratory‐determined values for cation exchange capacity (0.06 < Q_v < 0.51 meq/mL) and those obtained from the Waxman–Smits model (0.09 < Q_v < 0.55 meq/mL) indicates a very strong correlation, suggesting this model is appropriate for describing the rock. There is good agreement between parameters modelled using fully and partially saturated versions of both the Hanai–Bruggeman and Waxman–Smits equations, indicating that the data are consistent with these models and that the assumptions made are appropriate.     

Performance of Goddard earth observing system GCM column radiation models under heterogeneous cloud conditions

We test the performance of the shortwave (SW) and longwave (LW) Column Radiation Models (CORAMs) of Chou and collaborators with heterogeneous cloud fields from a single-day global dataset produced by NCAR's Community Atmospheric Model (CAM) with a 2-D Cloud Resolving Model (CRM) installed in each column. The original SW version of the CORAM performs quite well compared to reference Independent Column Approximation (ICA) calculations for boundary fluxes (global error 4 W m⁻² for reflected flux), largely due to the success of a combined overlap and cloud scaling parameterization scheme. The absolute magnitude of errors relative to ICA are even smaller (global error 2 W m⁻² for outgoing flux) for the LW CORAM which applies similar overlap. The vertical distribution of heating and cooling within the atmosphere is also simulated quite well with daily averaged zonal errors always less than 0.3 K/day for SW and 0.6 K/day for LW heating (cooling) rates. The SW CORAM's performance improves by introducing a scheme that accounts for cloud inhomogeneity based on the Gamma Weighted Two Stream Approximation (GWTSA).These results suggest that previous studies demonstrating the inaccuracy of plane-parallel models may have unfairly focused on worst case scenarios, and that current radiative transfer algorithms in General Circulation Models (GCMs) may be more capable than previously thought in estimating realistic spatial and temporal averages of radiative fluxes, as long as they are provided with correct mean cloud profiles. However, even if the errors of our particular CORAMs are small, they seem to be systematic, and their impact can be fully assessed only with GCM climate simulations.     

Coupled Os–Os enrichments in the Earth’s mantle – core–mantle interaction or recycling of ferromanganese crusts and nodules?

¹⁸⁶Os enrichments in volcanic rocks and peridotite-derived iridosmine grains have been attributed to contributions from Earth’s outer core to the mantle, and apparently constrain the scale of mantle convection and an early timing for inner–outer core segregation more than 3.5 Gyr ago. Here, we highlight that marine ferromanganese crusts and nodules are characterised by high Pt/Os ratios and Pt–Os contents that develop much larger ¹⁸⁶Os excesses over geological time (≥0.2%/Gyr) than those hypothesised for Earth’s outer core (<0.005–0.01%/Gyr). ¹⁸⁷Os/¹⁸⁸Os ratios in ferromanganese crusts are radiogenic due to sequestering of continental Os from seawater. Similarly, ancient ferromanganese materials may have had ¹⁸⁶Os excesses (>0.1%) as a result of high Pt/Os ratios in continental crust, even prior to in-growth of ¹⁸⁶Os after formation due to their high Pt/Os ratios. Past recycling of small amounts of these materials into the Earth’s mantle will produce coupled ¹⁸⁷Os–¹⁸⁶Os excesses and little change in Re and platinum-group-element concentrations, as observed in Hawaiian picrites, and in contrast to the predicted result of outer core addition to the mantle. ¹⁸⁷Os and ¹⁸⁶Os enrichments in the Hawaiian mantle source are potentially consistent with it comprising recycled oceanic lithosphere, pelagic sediments and ferromanganese materials, and questions the notion that Os isotopes can be used to uniquely identify core–mantle interactions and the depth at which mantle sources for volcanism originate.     

A late diagenetic (syn-folding) magnetization carried by pyrrhotite: implications for paleomagnetic studies from magnetic iron sulphide-bearing sediments

Paleomagnetic, rock magnetic, and sedimentary micro-textural data from an early Miocene mudstone sequence exposed in Okhta River, Sakhalin, Russia, indicate the presence of pyrrhotite and magnetite at different stratigraphic levels. Sites that contain only magnetite have a reversed polarity characteristic remanent magnetization (ChRM) with a low-coercivity overprint, which coincides with the present-day geomagnetic field direction. Pyrrhotite-bearing sites have stable normal polarity ChRMs that are significantly different from the present-day field direction. After correction for bedding tilt, the ChRM data fail a reversals test. However, the normal polarity pyrrhotite ChRM directions become antipodal to the tilt-corrected magnetite ChRM directions and are consistent with the expected geocentric axial dipole field direction at the site latitude after 40% partial unfolding. These data suggest that the pyrrhotite magnetization was acquired during folding and after lock-in of the magnetite remanences. Electron microscope observations of polished sections indicate that fluid-associated halos surround iron sulphide nodules. Pyrrhotite is present in randomly oriented laths in and around the nodules, and the nodules do not appear to have been deformed by sediment compaction. This observation is consistent with a late diagenetic origin of pyrrhotite. Documentation of a late diagenetic magnetization in pyrrhotite-bearing sediments here, and in recent studies of greigite-bearing sediments, suggests that care should be taken to preclude a late origin of magnetic iron sulphides before using such sediments for geomagnetic studies where it is usually crucial to establish a syn-depositional magnetization.     

Evaluation of an air bubbler to mitigate fish impingement at an electric generating plant

To determine whether fish impingement at an electric generating plant was significantly reduced during the operation of an air bubbler, impingement monitoring data was subjected to statistical analysis. Daily impingement rates were calculated for total fish collections and for three impinged species, and associated with water chemistry conditions and air curtain operation during impingement periods. Analysis for each species by season indicated that the air curtain was not an effective fish deterrent.     

A maritime boundary-layer model for the prediction of fog

A two-dimensional boundary-layer model is described. The model is designed to predict and study the effects of meteorological changes on the formation and dissipation of fog and stratus. Radiational heat loss along with the transport of static energy, moisture and momentum are treated. Cloud droplet distributions are parameterized using a gamma distribution from which radiative properties and droplet fall velocities are computed. Turbulent exchange coefficients are calculated using the Monin-Obukhov theory of similitude which accounts for variations in atmospheric stability. Although the boundary-layer depth depends only on turbulent intensity during stable atmospheric conditions, its growth during unstable conditions is determined from the capping inversion's intensity and the amount of turbulence generated at the surface.Several experiments are presented which demonstrate the effects of various meteorological parameters on the formation and duration of stratus and fog. Energy-budget analyses show the importance of each of the physical processes being modeled.Although not new, radiative transfer processes are shown to be extremely important in the transfer of heat from the boundary layer and in the process of fog formation. Fog formation location is highly sensitive to the moisture content upstream, whereas changes in wind speed had much less effect in the variance of fog location.Numerical experiments with other processes such as back radiation from the atmosphere, haze and cloud droplet population, are described and shown to have smaller effects.