Cartographic Style in the First Urban Maps of Cadiz,Spain: A Technique in Transition

This article deals with the cartometric analysis of various seventeenth-century urban maps of the city of Cadiz (Spain), from among which the so-called Vista Arámburu and the map belonging to the atlas of the Marquis of Heliche, discovered in the Krigsarkivet (Military Archive) of Stockholm, stand out for their uniqueness. These hitherto relatively unknown documents present evidence of an evolution of cartographic style towards greater topographic accuracy and hence cannot just be considered as simple drawings. In this seventeenth-century period of transition, the cartography of the city evolved from sixteenth-century aerial-view perspectives to the exhaustive planimetric maps of the eighteenth century, made by Spanish and French Military Corps of Engineers. These documents hold great historical value, not only due to the importance of Cadiz during the Modern Age but also because these maps constitute a graphic testimony of the fortification and growth of the city in this period.     

On the Harker Variation Diagrams; A Comment on “The Statistical Analysis of Compositional Data. Where Are We and Where Should We Be Heading?” by Aitchison and Egozcue (2005)

The current theoretical development of the analysis of compositional data in the article by Aitchison and Egozcue neglects the use of Harker’s variation diagrams and other similar plots as “meaningless” or “useless” on compositional data. In this work, it is shown that variation diagrams essentially are not a correlation tool but a graphical representation of the mass actions and mass balances principles in the context of a given geological system, and, when they are used correctly, they provide vital information for the igneous petrologist. The qualitative validity of the “spurious trends” in these diagrams is also shown, when they are interpreted in their proper geological framework. The example previously used by Rollinson to test the usefulness of the log-ratio transformation in the Aitchison and Egozcue article is revisited here in order to fully illustrate the proper use of this tool.     

Removal of Carbamazepine,Naproxen, and Trimethoprim from Water by Amberlite XAD‐7: A Kinetic Study

The adsorption kinetics of carbamazepine, naproxen, and trimethoprim in aqueous solution by Amberlite? XAD‐7 has been studied. The influence of adsorbent dose (1–3 g/L), stirring rate (80–240 rpm), pH (2–9), temperature (20–60°C), and initial concentration (25–75 ppm) on the adsorption kinetics has been analyzed. The removal efficiency in the first 2 h reaches 85% for carbamazepine, 60% for naproxen, and 70% for trimethoprim. pH appears to be the most important factor conditioning the removal of these latter solutes, whereas carbamazepine adsorption seems to be independent of the pH of the adsorptive solution. Initial concentration and operation temperature moderately influence the adsorption process. Finally, stirring rate scarcely affects the process. The experimental data have been fitted to four kinetic models, namely pseudo‐first and pseudo‐second order, intra‐particle diffusion and Bangham's. The model providing the best fit is the pseudo‐second order one. Again, pH is the factor that affects the adsorption rate in a more remarkable manner although other parameters such as temperature and stirring rate also contribute to accelerate the removal of the solutes. Under the optimal operation conditions, Amberlite? XAD‐7 exhibits a promising ability for the removal of the pharmaceuticals under study.     

Alteration of Platinum-Group and Base-Metal Mineral Assemblages in Ophiolite Chromitites from the Dobromirtsi Massif,Rhodope Mountains (Bulgaria)

The Dobromirtsi Ultramafic Massif, located in the Rhodope Mountains (SE Bulgaria), is a portion of a Paleozoic sub-oceanic mantle affected by polyphase regional metamorphism. This massif contains several small, podiform chromitite bodies which underwent the same metamorphic evolution as their host peridotites. Like other ophiolite chromitites, those found in Dobromirtsi carry abundant platinum-group minerals (PGM) and base-metal minerals (BMM). The PGM consist mainly of Ru-, Os-, and Ir-based PGM (laurite RuS₂-erlichmanite OsS₂, Os-Ru-Ir alloys, irarsite [IrAsS], Ru-rich pentlandite, and an unknown Ir-sulfide) but minor Rh- and Pd-based PGM (hollingworthite [RhAsS] and a series of unidentified stannides and sulfantimonides) are also present. In contrast, the BMM are dominated by pentlandite (Ni,Fe)₉S₈, followed by heazlewoodite (Ni₃S₂), breithauptite (NiSb), maucherite (Ni₁₁As₈), godlevskite (Ni₇S₆), gersdorffite (NiAsS), millerite (NiS), undetermined minerals containing Ni, As and Sb, orcelite (Ni_5-XAs₂), awaruite (Ni₃Fe) and chalcopyrite (CuFeS₂). The detailed study of the textural relationships, morphology and composition of the PGM and BMM inclusions indicate the existence of two different PGM-BMM assemblages: (i) a primary or magmatic; and (ii) a secondary related with postmagmatic alteration. The PGM and BMM inclusions in unaltered zones of chromite crystals (mainly laurite-erlichmanite and pentlandite) are considered to be primary magmatic minerals formed under variable temperature (1200–1100°C) and sulfur fugacity (between −2 and −0.5 log fS₂). In contrast, PGM and BMM located along altered edges of chromite and serpentinised silicate matrix are considered to be secondary, formed from or re-equilibrated with altering fluids. Secondary PGM and BMM assemblages are considered as result of the combination of reducing and oxidising events related with regional metamorphism. Under low fO₂ states, fS₂ also drops giving place to the formation of S-poor Ni-rich sulfides and secondary Ru-alloys by desulfurisation of primary S-containing minerals. In contrast, predominance of platinum-group elements and/or base-metal arsenides and sulfarsenides associated with the altered edges of chromite (chromite strongly enriched in Fe₂O₃) is related with the fixing of remobilised PGE (mainly Ir, Rh and Pd) and base-metals (mainly Ni and Fe) when late oxidising fluids supplied As as well as Sb and Sn.     

EURD Data Provide Strong Evidence Against the Sciama Model of Radiative Decay of Massive Neutrinos

Data obtained with a high resolution, high sensitivity spectrometer flown on the Spanish MINISAT 01 satellite wereused to test the Sciama model of radiatively decaying massive neutrinos. The observed emission is far less intense than that expected in the Sciama model.     

EURD: The Mission and the Stellar Absolute Fluxes of B-Type Stars

We present here stellar spectra of B stars obtained with the EURD spectrograph, one of the three instruments on board MINISAT-01. EURD is a spectrograph specially designed to detect diffuse radiation in thewavelength range between 350 and 1100 Å with 5 Å spectral resolution. EURD main scientific targets are: the spectrum of interstellar medium,atmospheric airglow, decaying neutrinos, Moon and early type stars.     

The Homo habitat niche: using the avian fossil record to depict ecological characteristics of Palaeolithic Eurasian hominins

Although hardly applied to human palaeoecology, bird fossils offer a unique opportunity for quantitative studies of the hominin habitat. Here we reconstruct the Homo habitat niche across a large area of the Palaearctic, based on a database of avian fauna for Pleistocene sites. Our results reveal a striking association between Homo and habitat mosaics. A mix of open savannah-type woodland, wetlands and rocky habitats emerges as the predominant combination occupied by Homo across a wide geographical area, from the earliest populations of the Lower Palaeolithic to the latest hunter-gatherer communities of the Upper Palaeolithic. This observation is in keeping with the view that such landscapes have had long standing selective value for hominins.     

Sensitivity analysis of a Penman–Monteith type equation to estimate reference evapotranspiration in southern Spain

Sensitivity analysis is crucial in assessing the impact of climatic variables on reference evapotranspiration estimations. The sensitivity of the standardized ASCE–Penman–Monteith evapotranspiration equation for daily estimations to climatic variables has not yet been studied in Spain. Andalusia is located in southern Spain where almost 1 million ha are irrigated under quite different conditions; it has a high inter‐annual variability in rainfall. In this study, sensitivity analyses for this equation were carried out for temperature, relative humidity, solar radiation and wind speed data from 87 automatic weather stations, including coastal and inland locations, from 1999 to 2006. Topography and Mediterranean climate characterize the heterogeneous landscape and vegetation of this region. Simulated random and systematic errors have been added to meteorological data to obtain ET₀ deviations and sensitivity coefficients for different time periods. BIAS and SEE (standard error of estimate) have been used to evaluate the effect of both types of errors. The results showed a large degree of daily and seasonal variability, especially for temperature and relative humidity. In general, the effect on ET₀ values of introduced random errors was larger than that of systematic errors. ET₀ overestimations were produced using positive errors in temperature, solar radiation and wind speed data, while these errors in relative humidity resulted in ET₀ underestimations. The sensitivity of ET₀ to the same climatic variables showed significant differences among locations. The geographical distribution of sensitivity coefficients across this region was also studied. As an example, during spring months, ET₀ equation was more sensitive to temperature in stations located along the Guadalquivir Valley. Copyright © 2009 John Wiley & Sons, Ltd.     

Multi-platform model assessment in the Western Mediterranean Sea: impact of downscaling on the surface circulation and mesoscale activity

Ocean Dynamics - In numerical ocean modeling, dynamical downscaling is the approach consisting in generating high-resolution regional simulations exploiting the information from coarser resolution...