PCBs in fish from the southern Baltic Sea: levels, bioaccumulation features, and temporal trends during the period from 1997 to 2006

Levels of seven marker polychlorinated biphenyls (PCBs) have been determined in five species of Baltic fish collected during 1997-2006. Downward time trends in the concentrations of heavier congeners of PCBs in different Baltic fish, with the exception of cod, have been observed between 1997 and 2001. In case of sprat and herring samples, the statistical significance of the time trends of the PCBs: 101, 118, 153, 138 and 180 concentrations has been proved. Species-specific bioaccumulation of PCBs has been indicated, and the lowest and highest levels of PCBs (expressed on the basis of lipid weight) have been observed in sprat and salmon samples, respectively. PCB profiles have been found to be similar in all the fish species tested. Sampling location has not been a crucial factor for the observed levels of various PCBs. In some fish species, PCB concentrations are negatively correlated with the fat content but have no relation with the fish length.     

How sediment composition and flow rate influence downstream channel morphodynamics upon dam removal

The process of dam removal establishes the channel morphology that is later adjusted by high-flow events. Generalities about process responses have been hypothesized, but broad applicability and details remain a research need. We completed laboratory experiments focused on understanding how processes occurring immediately after a sediment release upon dam removal or failure affect the downstream channel bed. Flume experiments tested three sediment mixtures at high and low flow rates. We measured changes in impounded sediment volume, downstream bed surface, and rates of deposition and erosion as the downstream bed adjusted. Results quantified the process responses and connected changes in downstream channel morphology to sediment composition, temporal variability in impounded sediment erosion, and spatial and temporal rates of bedload transport. Within gravel and sand sediments, the process response depended on sediment mobility. Dam removals at low flows created partial mobility with sands transporting as ripples over the gravel bed. In total, 37% of the reservoir eroded, and half the eroded sediment remained in the downstream reach. High flows generated full bed mobility, eroding sands and gravels into and through the downstream reach as 38% of the reservoir eroded. Although some sediment deposited, there was net erosion from the reach as a new, narrower channel eroded through the deposit. When silt was part of the sediment, the process response depended on how the flow rate influenced reservoir erosion rates. At low flows, reservoir erosion rates were initially low and the sediment partially exposed. The reduced sediment supply led to downstream bed erosion. Once reservoir erosion rates increased, sediment deposited downstream and a new channel eroded into the deposits. At high flows, eroded sediment temporarily deposited evenly over the downstream channel before eroding both the deposits and channel bed. At low flows, reservoir erosion was 17–18%, while at the high flow it was 31–41%.     

GRS 1915+105: the distance, radiative processes and energy-dependent variability

We present an exhaustive analysis of five broad-band observations of GRS 1915+105 in two variability states, χ and ω, observed simultaneously by the Proportional Counter Array (PCA) and High-Energy X-ray Timing Experiment (HEXTE) detectors aboard the Rossi X-ray Timing Explorer , and the Oriented Scintillation Spectrometer Experiment (OSSE) detector aboard the Compton Gamma-ray Observatory . We find all the spectra well fitted by Comptonization of disc blackbody photons, with very strong evidence for the presence of a non-thermal electron component in the Comptonizing plasma. Both the energy and the power spectra in the χ state are typical of the very high/intermediate state of black hole binaries. The spectrum of the ω state is characterized by a strong blackbody component Comptonized by thermal electrons and a weak non-thermal tail. We then calculate rms spectra (fractional variability as functions of energy) for the PCA data. We accurately model the rms spectra by coherent superposition of variability in the components implied by the spectral fits, namely a less variable blackbody and more variable Comptonization. The latter dominates at high energies, resulting in a flattening of the rms at high energies in most of the data. This is also the case for the spectra of the quasi-periodic oscillations present in the χ state. Then, some of our data require a radial dependence of the rms of the disc blackbody. We also study the distance to the source, and find   d ≃ 11 kpc  as the most likely value, contrary to a recent claim of a much lower value.     

Distribution of minima of the current size of the triple systems and their disruption

The dynamical evolution of triple systems has been studied by computer simulations. A function (t) has been defined, where p is the maximum distance of the components from their centre of inertia, and t is the time. The value of is used to indicate the current size of the triple system. The minima of have been followed during the course of evolution of the triples. A distribution of f(_min) has been obtained, which is described by the following statistical parameters: the mode is equal to 0.65d, the mean value _min= 0.750d, r.m.s. is 0.477d, the asymmetry is 0.218, the excess is 2.04 where d is the mean harmonic distance between the bodies in the equilibrium state of the triple system. As a rule, escapes from triples occur only after close three-body approaches.     

Lignin degradation products as palaeoenvironmental proxies in the sediments of small lakes

The quantity and quality of lignin phenols (Σ8, Λ, S/V, C/V and (Ad/Al)_v) in the sediments of three small Lobelia lakes with neither inlets nor outlets were investigated and compared with palynological data and lithology of the profiles. The method of alkaline CuO oxidation was used. Substantial differences with respect to sedimentary lignin concentration and provenance recorded along the profiles and among the sites are in good agreement with pollen data describing the dominant type of vegetation and with indices of soil erosion in the lakes’ catchments. This relation shows that the compositions of lignin degradation products in these lakes are closely related to the local environmental conditions. In all the lakes gymnosperm wood is the main source of lignin products; however, each lake is characterized by different S/V index values. Especially good correlations were obtained between pine pollen proportions in sediments and the S/V index. The correlation between the C/V and (Ad/Al)_v indices indicates a higher degradation of organic matter when non-woody tissue is more abundant. This pilot study illustrates the usefulness and potential for a wider application of lignin oxidation products in palaeoecological reconstructions. This kind of data would be of special importance when investigating local presence/absence of woody plants and the role of angiosperms/gymnosperms in local vegetation. Estimates of lignin biodegradation levels, as well as the data on diagenetic processes, may afford supplementary information on possible disturbances in sedimentation.     

Dynamic modeling suggests terrace zone asymmetry in the Chicxulub crater is caused by target heterogeneity

We investigate the cause of terrace zone asymmetry in the Chicxulub impact crater using dynamic models of crater formation. Marine seismic data acquired across the crater show that the geometry of the crater's terrace zone, a series of sedimentary megablocks that slumped into the crater from the crater rim, varies significantly around the offshore half of the crater. The seismic data also reveal that, at the time of impact, both the water depth and sediment thickness varied with azimuth around the impact site. To test whether the observed heterogeneity in the pre-impact target might have affected terrace zone geometry we constructed two end-member models of upper-target structure at Chicxulub, based on the seismic data at different azimuths. One model, representing the northwest sector, had no water layer and a 3-km thick sediment layer; the other model, representing the northeast sector, had a 2-km water layer above a 4-km sediment layer. Numerical models of vertical impacts into these two targets produced final craters that differ substantially in terrace zone geometry, suggesting that the initial water depth and sediment thickness variations affected the structure of the terrace zone at Chicxulub. Moreover, the differences in terrace zone geometry between the two numerical models are consistent with the observed differences in the geometry of the terrace zone at different azimuths around the Chicxulub crater. We conclude that asymmetry in the pre-impact target rocks at Chicxulub is likely to be the primary cause of asymmetry in the terrace zone.     

Andesitic magma degassing investigated through H2O vapour–melt partitioning of halogens at Soufrière Hills Volcano, Montserrat (Lesser Antilles)

Magma degassing at Soufrière Hills Volcano (SHV) is characterised by an almost permanent SO₂ flux and a HCl production rate which mainly depends on dome growth rate. Degassing processes have been studied through textural, H₂O and halogen analyses of clasts collected between 1995 and 2006 on the dome and in pyroclastic flows and vulcanian eruption deposits. Cl, Br and I are strongly depleted in melts during H₂O degassing with no significant Cl–Br–I fractionation, whereas F is almost unaffected. All magmas erupted at SHV have followed a multi-step degassing path from the magma chamber up to a shallow depth ( 1 km, P  20 MPa). From that depth, however, effusive and explosive paths are distinct; vulcanian eruptions are the result of closed system degassing (CSD), while effusive dome growth is the result of CSD up to a very shallow depth (≤ 200 m, P  5–2 MPa) followed by open system degassing (OSD). CSD is modelled using the H₂O solubility law, the perfect gas law and partition coefficients of halogens between a rhyolitic melt and H₂O vapour (d_v − lⁱ). Gas loss characteristic of OSD is modelled using a Rayleigh law. Degassing induced crystallisation is introduced through the ratio of crystallisation and degassing rates, which ranges from 150–500. d_v − l^Cl for OSD ranges between 50–300, increasing with melt Cl content. For CSD, the lower effective d_v − l^Cl ( 20) is attributed to kinetic effects.

Dome forming activity has a greater impact on atmospheric chemistry than vulcanian eruptions because OSD is much more efficient at extracting halogens. The model shows that HCl flux is a good proxy for the dome forming eruption rate. Comparison between model and measured gas compositions suggests a high HBr–BrO conversion rate (BrO/Total Br  1/3) in the SHV gas plume.

The degassing behaviour of Cl, Br and I implies similar Cl/Br ( 160) and Br/I ( 90) in initial melts, volcanic clasts and high temperature gases. The low Cl/Br at SHV compared to other island arcs ( 250–300) is attributed to a shallow, pre-eruptive Br enrichment. The almost permanent dome extrusion at SHV since 1995 has likely had a significant regional atmospheric impact because of the very efficient effusive degassing and the high conversion rate of halogens into reactive species within the gas plume.     

A nonhydrostatic unstructured-mesh soundproof model for simulation of internal gravity waves

A semi-implicit edge-based unstructured-mesh model is developed that integrates nonhydrostatic soundproof equations, inclusive of anelastic and pseudo-incompressible systems of partial differential equations. The model builds on nonoscillatory forward-in-time MPDATA approach using finite-volume discretization and unstructured meshes with arbitrarily shaped cells. Implicit treatment of gravity waves benefits both accuracy and stability of the model. The unstructured-mesh solutions are compared to equivalent structured-grid results for intricate, multiscale internal-wave phenomenon of a non-Boussinesq amplification and breaking of deep stratospheric gravity waves. The departures of the anelastic and pseudoincompressible results are quantified in reference to a recent asymptotic theory [Achatz et al. 2010, J. Fluid Mech., 663, 120–147)].     

Crosshole seismic waveform tomography – II. Resolution analysis

In an accompanying paper, we used waveform tomography to obtain a velocity model between two boreholes from a real crosshole seismic experiment. As for all inversions of geophysical data, it is important to make an assessment of the final model, to determine which parts of the model are well-resolved and can confidently be used for geological interpretation. In this paper we use checkerboard tests to provide a quantitative estimate of the performance of the inversion and the reliability of the final velocity model. We use the output from the checkerboard tests to determine resolvability across the velocity model. Such tests can act as good guides for designing appropriate inversion strategies. Here we discovered that, by including both reference-model and smoothing constraints in initial inversions, and then relaxing the smoothing constraint for later inversions, an optimum velocity image was obtained. Additionally, we noticed that the performance of the inversion was dependent on a relationship between velocity perturbation and checkerboard grid-size: larger velocity perturbations were better-resolved when the grid-size was also increased. Our results suggest that model assessment is an essential step prior to interpreting features in waveform tomographic images.