Photobleaching of chromophoric dissolved organic matter (CDOM) in rainwater

Significant photodegradation of chromophoric dissolved organic matter (CDOM) in rainwater was observed after exposure to simulated sunlight. Fluorescence excitation emission spectra (EEMS) of precipitation revealed the presence of four major peaks all of which degraded upon photolysis with the greatest loss in the region characteristic of marine CDOM. Photobleaching of absorbance also occurred in the wavelength region between 250 and 375 nm with the greatest loss of absorbance in the upper end of the UV-A region near 275 nm. There was a strong positive correlation between absorbance loss and total integrated fluorescence loss suggesting these optical properties and the degree to which they are photobleached in rainwater are directly related. The quantum yield of CDOM photodegradation in rainwater decreased dramatically with increasing wavelength and decreasing energy of incoming radiation with the average quantum yield at 325 nm approximately an order of magnitude greater than at 460 nm. The similarity of photolytic response between rainwater and Cape Fear estuarine CDOM indicates that some fraction of the compounds that make up rainwater CDOM may be derived from surface sources and/or that the processes that produce or modify humic-like substances in the atmosphere result in similar types of compounds as non-atmospheric processes.     

Velocity Oscillations in Active Sunspot Groups

Time series of two-dimensional spectra were taken with the Göttingen 2D spectrometer at the VTT on Tenerife in 1996. They were investigated for Doppler velocities and velocity oscillations in small spots and pores of rapidly evolving sunspot groups. For the present measurements the magnetically insensitive lines Fe i 557.6 nm and Fe i 709.0 nm were selected. Spots with penumbrae exhibit the Evershed effect. Some pores seem to be connected with downflows, but the centres of the downflows are somewhat displaced from their associated pores. The surroundings of the pores show red shifts relative to the whole field of view. The power in the 5-min range is reduced inside the spots and pores as well as in their immediate vicinity. This reduction inside the spots is in agreement with former results. Outside the area of the spot group the 5-min power has a patchy structure with a typical size of 5 arc sec. For periods below 3.3 min, the behaviour of individual spots and pores is different. Some spots show clearly enhanced power for these periods, and it remains high down to the Nyquist period at 1.5 min. The small pores do not show enhanced three-minute oscillations compared with their vicinity. Inside one spot we find a ring of enhanced power in the period range between 8 and 20 min corresponding to the time scales of granular variations. This result could be an indication of a relation between spots and convection, but magneto-accoustic waves are also possible. The same ring exhibits also enhanced power for short periods.     

Relationship between waterfowl and the seagrassRuppia maritima in a Southwestern Atlantic coastal lagoon

We evaluated the distribution of waterfowl in relation to a seagrass (Ruppia maritima) patch, to infauna, and on its relationship with substrate characteristics. An experiment performed in the Mar Chiquita coastal lagoon (37°46′S, 57°27′W; Argentina) was used to evaluate the effect of herbivory on widgeon grass,R. maritima. Control plots of equal size, located between bird exclosures, were exposed to herbivory. The experiment ran for 31 d, starting on December 1, 1994. Censuses showed that black-necked swan ( $\bar x = 50$ birds ha^?1, SD = 37, n = 10) and coots ( $\bar x = 42$ birds ha^?1, SD = 28, n = 10) were the most important (always present) of the waterfowl seen feeding onR. maritima. The results of the experiment showed greater leaf lengths, lower belowground (rhizomes and roots) biomass, greater aboveground (leaves and shoots) biomass, and greater abundance of the polychaeteHeteromastus similis in exclosure plots. There were no exclosure effects on total biomass (belowground plus aboveground), reproductive parts (fruits and pre- and postpollination flowers), or abundance of most benthic infauna. Topographic surveys showed that sediment surface was higher within theR. maritima patches, but there were no significant differences in granulometric composition. Surveys also showed that bird distribution was strongly associated with the presence ofR. maritima.     

From subduction to transform motion: a seabeam survey of the Hellenic trench system

Preliminary results of a multi-narrow beam survey of the Hellenic trench system, in the Eastern Mediterranean, are presented. The southwestern Ionian branch is divided in small basins, partly filled with Pleistocene sediments. The morphology suggests that the basins are deformed by a compressional stress acting roughly perpendicularly to the trench along N50°E. This direction is the direction of the regional slip vector of the shallow thrust-type earthquakes. The structure of the southeastern Pliny-Strabo branch is quite different. Narrow en-e´chelon slots, oriented N40°E, have been mapped within the main troughs oriented N60°E. The regional earthquake slip vector is also oriented along N40°E. We conclude that the Hellenic trench system is an active subduction system, dominated by thrust along the Ionian branch and by transform motion along the Pliny-Strabo branch.     

The partial molal volume of silicic acid in 0.725 m NaCl

The partial molal volume ($\text{V}\text{?}$) of silicic acid in 0.725 m NaCl at 20°C has been calculated from (1) direct volume changes due to the dissolution of anhydrous sodium silicate and (2) some literature values for the partial molal volumes of NaOH and water. , unconnected for electrostriction effects, was found to be 53 ± 2 ml mole^?1. , corrected for volume changes due to solvent electrostriction by charged Si species, was estimated to be in the range 58–62 ml mole^?1; this range is 7–11 ml mole^?1 greater than the calculated from Willey's (Mar. Chem. 2, 239–250, 1974) solubility data obtained from the dissolution, in seawater, of amorphous silica subjected to hydrostatic pressure. Our does, however, agree within experimental error with the calculated from Jones and Pytkowicz's (Bull. Soc. Roy. Sci. Liege 42, 118–120, 1973) data for the solubility of amorphous silica in seawater at high pressure and is nearly in agreement with Willey's (Ph.D. thesis, Dalhousie University, 1975) solubility data for amorphous silica in 0.6 m NaCl.     

The impact of land use change and check‐dams on catchment sediment yield

Extensive land use changes have occurred in many areas of SE Spain as a result of reforestation and the abandonment of agricultural activities. Parallel to this the Spanish Administration spends large funds on hydrological control works to reduce erosion and sediment transport. However, it remains untested how these large land use changes affect the erosion processes at the catchment scale and if the hydrological control works efficiently reduce sediment export. A combination of field work, mapping and modelling was used to test the influence of land use scenarios with and without sediment control structures (check‐dams) on sediment yield at the catchment scale. The study catchment is located in SE Spain and suffered important land use changes, increasing the forest cover 3‐fold and decreasing the agricultural land 2·5‐fold from 1956 to 1997. In addition 58 check‐dams were constructed in the catchment in the 1970s accompanying reforestation works. The erosion model WATEM‐SEDEM was applied using six land use scenarios: land use in 1956, 1981 and 1997, each with and without check‐dams. Calibration of the model provided a model efficiency of 0·84 for absolute sediment yield. Model application showed that in a scenario without check dams, the land use changes between 1956 and 1997 caused a progressive decrease in sediment yield of 54%. In a scenario without land use changes but with check‐dams, about 77% of the sediment yield was retained behind the dams. Check‐dams can be efficient sediment control measures, but with a short‐lived effect. They have important side‐effects, such as inducing channel erosion downstream. While also having side‐effects, land use changes can have important long‐term effects on sediment yield. The application of either land use changes (i.e. reforestation) or check‐dams to control sediment yield depends on the objective of the management and the specific environmental conditions of each area. Copyright © 2008 John Wiley & Sons, Ltd.     

Evaluating infiltration losses in a Mediterranean wetland: Las Tablas de Daimiel National Park,Spain

Las Tablas de Daimiel National Park is a series of wetlands which naturally originated from groundwater discharges from the Mancha Occidental aquifer, Spain. Despite the relatively large size of this aquifer, 30 years of intensive groundwater pumping have significantly depleted the water table. As a result, wetlands only remain functional due to artificial inflows. Infiltration loss is therefore a key parameter to evaluate how much water is needed to maintain ecosystem functionality. Although yearly infiltration estimates existed prior to this work, these did not take into account key parameters such as the temporal evolution of the flooded area. This paper presents a more concrete estimate of the average infiltration losses. Infiltration is calculated as the closure term of daily water balances during a period of time where all other elements were known to an acceptable accuracy. A validation mechanism is provided to check the potential utility of the calculated infiltration in wetland management practices. Copyright © 2008 John Wiley & Sons, Ltd.     

Numerical modelling of the potential effects of a dam on a coastal aquifer in S. Spain

This study presents the results of a three‐dimensional variable‐density numerical modelling of the Motril‐Salobreña coastal aquifer and the possible effects of the entry into service in May 2005 of the Rules Dam, located just 17 km from the coast. Present parameters of the Motril‐Salobreña aquifer show that the system's conditions are very similar to a natural regime. The dam will substantially alter aquifer recharge, as the entry flow through the alluvial sediments of the Guadalfeo River will be entirely cut off or drastically reduced. Different scenarios reproducing the possible evolution of the aquifer under operation of the Rules Dam have been modelled. In most cases, results indicate that the conditions of the aquifer would worsen, with a general advance of the freshwater–saltwater interface. The area with most risk of saltwater intrusion is the old mouth of the Guadalfeo River, where the mixing zone could advance 1200 m inland. It is proposed that maintaining a 5–6 Mm³ year^?1 ‘ecological flow’ in the Guadalfeo River could prevent this saline advance. This application demonstrates that variable‐density models are potentially useful tools for estimating the effects of dams on the hydrodynamic and hydrochemical conditions of a coastal aquifer. Copyright © 2009 John Wiley & Sons, Ltd.     

Postglacial climates inferred from a lake at treeline,southwest Yukon Territory,Canada

Pollen, chironomid, and ostracode records from a lake located at alpine treeline provide regional paleoclimate reconstructions from the southwest Yukon Territory, Canada. The pollen spectra indicate herbaceous tundra existed on the landscape from 13.6–11 ka followed by birch shrub tundra until 10 ka. Although Picea pollen dominated the assemblages after 10 ka, low pollen accumulation rates and Picea percentages indicate minimal treeline movement through the Holocene. Chironomid accumulation rates provide evidence of millennial-scale climate variability, and the chironomid community responded to rapid climate changes. Ostracodes were found in the late glacial and early Holocene, but disappeared due to chemical changes of the lake associated with changes in vegetation on the landscape. Inferred mean July air temperature, total annual precipitation, and water depth indicate a long-term cooling with increasing moisture from the late glacial through the Holocene. During the Younger Dryas (12.9–11.2 ka), cold and dry conditions prevailed. The early and mid-Holocene were warm and dry, with cool, wet conditions after 4 ka, and warm, dry conditions since the end of the Little Ice Age.