The effect of pressure on the solubility of amorphous silica in seawater at 0°C

The solubility of amorphous silica in seawater at 0°C and from 1 to 1,220 atm. was found to be a linear function of pressure above 270 atm., but to deviate from linearity below that pressure. Using a quadratic derivation of Planck's equation, ΔV for the dissolution was found to be −16.5 cm³mole⁻¹, and Δk was found to be −4.4 · 10⁻² cm³ mole⁻¹ atm⁻¹∂Δk/∂P was found to be 27.2 · 10⁻⁵ cm³ mole⁻¹ atm⁻² which is too significant a factor to allow the commonly made assumption that ∂Δk/∂P =0. North's (1973) model of hydration suggests that this non-zero ∂Δk/∂P may indicate that the silicic acid molecule is more extensively hydrated at lower pressures.If the pressure in an experiment is suddenly lowered to atmospheric pressure after equilibrium solubility had been attained at the higher pressure, the precipitation that occurs to reduce the resulting supersaturation is complete within one hour in the experimental system used in this study.     

Streamflow dynamics in a Mediterranean temporary river

Abstract

Mediterranean rivers are characterized by the irregularity of flow, harsh hydrological fluctuations and a profound transformation as the result of human activity. In this study, we investigate the streamflow response of a Mediterranean temporary river in which different groundwater, agriculture and urban contributions play an important role. Streamflow was measured at three nested gauging stations installed along Na Borges River, a lowland agricultural catchment (319 km²) on the island of Mallorca. Based on two hydrological years (2004/05 and 2005/06), potential evapotranspiration and surface water–groundwater interaction generated a succession of four different hydrological periods playing an important role in baseflow dynamics. The runoff coefficients were very low (<5%). At the event scale, groundwater also controlled runoff response, being very different according to hydrogeology, antecedent conditions and human impacts. During dry seasons, wastewater and karstic spring discharges maintain an influent regime into some streams. As a result, intense rainstorms in late summer generated water volumes over the impervious urban surfaces involved, with the result that quickflow was significant because the hydrological pathways were active. Citation Estrany, J., Garcia, C. & Alberich, R. (2010 Estrany, J., Garcia, C. and Batalla, R. J. 2010. Hydrological response of a small Mediterranean agricultural catchment. J. Hydrol., 380(1-2): 180–190. doi:10.1016/j.jhydrol.2009.10.035[Crossref] , [Google Scholar]) Streamflow dynamics in a Mediterranean temporary river. Hydrol. Sci. J. 55(5), 717–736.      

Citation analysis for the 1995 FAO Code of Conduct for Responsible Fisheries

This paper presents the results of a 2008 citation-analysis study that was undertaken for the 1995 FAO Code of Conduct for Responsible Fisheries and its associated instruments. The overall objective of this study was to contribute towards a strategy for improved dissemination, awareness raising and communication about the Code and its implementation. For each citation, additional information was collected to identify patterns by year, topic, author affiliation or type of literature. Results support previously suggested anecdotal patterns, in particular related to the diversity of publishing outlets and the high proportion of fisheries information published as grey literature. The results also point to areas of concern for long-term preservation and dissemination of fisheries information.     

Motion close to the Hopf Bifurcation Of the vertical family of periodic orbits of L4

The paper deals with different kinds of invariant motions (periodic orbits, 2D and 3D invariant tori and invariant manifolds of periodic orbits) in order to analyze the Hamiltonian direct Hopf bifurcation that takes place close to the Lyapunov vertical family of periodic orbits of the triangular equilibrium point L₄ in the 3D restricted three-body problem (RTBP) for the mass parameter, μ greater than (and close to) μ_R (Routh’s mass parameter). Consequences of such bifurcation, concerning the confinement of the motion close to the hyperbolic orbits and the 3D nearby tori are also described.     

The calculation of estuarine turnover times using freshwater fraction and tidal prism models: A critical evaluation

Freshwater fraction and tidal prism models are simple methods for estimating the turnover time of estuarine water. The freshwater fraction method prominently features flushing by freshwater inflow and has sometimes been criticized because it appears not to include flushing by seawater, but this is accounted for implicitly because the average estuary salinity used in the calculation reflects all the processes that bring seawater into the estuary, including gravitational circulation and tidal processes. The model relies on measurable salinity differences among water masses and so must be used for estuaries with substantial freshwater inflow. Tidal prism models are based on flushing by flood tide inflow and ignore seawater inflow due to gravitational circulation. These models should only be applied to estuaries with weak or nonexistent gravitational circulation, which are generally those with little freshwater inflow. Using a framework that is less ambioguous and more directly applicable to the estimation of turnover times than those used previously, this paper critically examines the application of tidal prism models in well-mixed estuaries with complete tidal exchange, partial ebb return, or incomplete flood mixing and in partially mixed estuaries. Problems with self-consistency in earlier versions of these models also apply to the budgeting procedure used by the LOICZ (Land-Ocean Interactions in the Coastal Zone) program. Although freshwater fraction and tidal prism models are different approaches to estimating turnover times in systems with very different characteristics, consistent derivation shows that these models have much in common with each other and that they yield equivalent values that can be used to make comparisons across systems.     

Geochronology of Quaternary glaciations from the tropical Cordillera Huayhuash, Peru

The Cordillera Huayhuash in the central Peruvian Andes (10.3°S, 76.9°W) is an ideal mountain range in which to study regional climate through variations in paleoglacier extents. The range trends nearly north-south with modern glaciers confined to peaks >4800 m a.s.l. Geomorphology and geochronology in the nearby Cordillera Blanca and Junin Plain reveal that the Peruvian Andes preserve a detailed record of tropical glaciation. Here, we use ASTER imagery, aerial photographs, and GPS to map and date glacial features in both the western and eastern drainages of the Cordillera Huayhuash. We have used in situ produced cosmogenic ¹⁰Be concentrations in quartz bearing erratics on moraine crests and ice-polished bedrock surfaces to develop an exposure age chronology for Pleistocene glaciation within the range. We have also collected sediment cores from moraine-dammed lakes and bogs to provide limiting ¹⁴C ages for glacial deposits. In contrast to the ranges to the north and south, most glacial features within the Cordillera Huayhuash are Lateglacial in age, however we have identified features with ages that span 0.2 to 38 ka with moraine sets marking the onset of glacier retreat at 0.3 ka, 9–10 ka, 13–14 ka, 20–22 ka, and >26 ka. The range displays a pronounced east-west variation in maximum down-valley distance from the headwall of moraine crests with considerably longer paleoglaciers in the eastern drainages. Importantly, Lateglacial paleoglaciers reached a terminal elevation of 4000 m a.s.l. on both sides of the Cordillera Huayhuash; suggesting that temperature may have been a dominant factor in controlling the maximum glacier extent. We suggest that valley morphology, specifically valley slope, strongly influences down-valley distance to the maximum glacier extent and potential for moraine preservation. While regionally there is an extensive record of older (>50 ka) advances to the north (Cordillera Blanca) and to the south (Junin region), the apparent lack of old moraines in this locality may be explained by the confined morphology of the Cordillera Huayhuash valleys that has inhibited the preservation of older glacial geomorphic features.     

Study of the total lightning activity in a hailstorm

A thunderstorm that developed over northeastern Spain on 16 June 2006 is analyzed. This severe thunderstorm produced hailstones as large as 40 mm and had a lifetime of 3 h and 30 min. Radar cross-sections show strong vertical development with cloud echo tops reaching an altitude of 13 km. The specific characteristics of the lightning activity of this storm were: (i) a large amount (81%) of negative cloud-to-ground (−CG) flashes with very low peak currents (< 10 kA in absolute value), (ii) a very large proportion of intra-cloud (IC) flashes with an IC/CG ratio reaching about 400, (iii) a large number of “short” IC flashes (with only 1-VHF source according to SAFIR detection), (iv) a large increase of the −CG flash rate and of the CG proportion near the end of the storm. The rate of −CG flashes with a low peak current were observed to evolve similarly to the rates of IC flashes. Most of them have been assumed to be IC flashes misclassified by the Spanish Lightning Detection Network (SLDN). They have been filtered as it is usually done for misclassified +CG flashes. After this filtering, CG flash rates remained very low (< 1 min^− 1) with +CG flashes sometimes dominant. All the particular lightning activity characteristics similar to those observed in the Severe Thunderstorm Electrification and Precipitation Study (STEPS) campaigns support the hypothesis that this thunderstorm could have had an inverted-polarity or complex charge structure. The maximum IC flash rate (67 min^− 1) peaked 24 min before the presence of reflectivity higher than 60 dBZ. The IC activity abruptly decreased during the period when reflectivity was dramatically increasing. The time of maximum reflectivity observed by radar was consistent with the times of reported hail at the ground.     

Delineating coastal groundwater discharge processes in a wetland area by means of electrical resistivity imaging, 224Ra and 222Rn

Coastal groundwater discharge (CGD) plays an important role in coastal hydrogeological systems as they are a water resource that needs to be managed, particularly in wetland areas. Despite its importance, identifying and monitoring CGD often presents physical and logistical constraints, restraining the application of more traditional submarine groundwater discharge surveying techniques. Here we investigate the capability of electrical resistivity imaging (ERI) in the Peníscola wetland (Mediterranean coast, Spain). ERI surveying made it possible to identify and delineate an ascending regional groundwater flow of thermal and Ra‐enriched groundwater converging with local flows and seawater intrusion. The continuous inputs of Ra‐rich groundwater have induced high activities of Ra isotopes and ²²²Rn into the marsh area, becoming among the highest previously reported in wetlands and coastal lagoons. Geoelectrical imaging enabled inferring focused upward discharging areas, leaking from the aquifer roof through a confining unit and culminating as spring pools nourishing the wetland system. Forward modelling over idealized subsurface configurations, borehole datasets, potentiometric records from standpipe piezometers, petrophysical analysis, and four natural and independent tracers (²²⁴Ra, ²²²Rn, temperature and salinity) permitted assessing the geoelectrical model and a derived hydrogeological pattern. The research highlights the potential of ERI to improve hydrogeological characterization of subsurface processes in complex contexts, with different converging flows. Additionally, a hydrogeological conceptual model for a groundwater‐fed coastal wetland was proposed, based on the integration of surveying datasets. Copyright © 2013 John Wiley & Sons, Ltd.     

GEOEssential – mainstreaming workflows from data sources to environment policy indicators with essential variables

ABSTRACT

When defining indicators on the environment, the use of existing initiatives should be a priority rather than redefining indicators each time. From an Information, Communication and Technology perspective, data interoperability and standardization are critical to improve data access and exchange as promoted by the Group on Earth Observations. GEOEssential is following an end-user driven approach by defining Essential Variables (EVs), as an intermediate value between environmental policy indicators and their appropriate data sources. From international to local scales, environmental policies and indicators are increasingly percolating down from the global to the local agendas. The scientific business processes for the generation of EVs and related indicators can be formalized in workflows specifying the necessary logical steps. To this aim, GEOEssential is developing a Virtual Laboratory the main objective of which is to instantiate conceptual workflows, which are stored in a dedicated knowledge base, generating executable workflows. To interpret and present the relevant outputs/results carried out by the different thematic workflows considered in GEOEssential (i.e. biodiversity, ecosystems, extractives, night light, and food-water-energy nexus), a Dashboard is built as a visual front-end. This is a valuable instrument to track progresses towards environmental policies.     

Phase distribution of hydrocarbons in the water column after a pelagic deep ocean oil spill

Spills from wrecks are a potential major source of pollution in the deep ocean. However, not much is known about the fate of a spill at several kilometers depth, beyond the oceans continental shelves. Here, we report the phase distribution of hydrocarbons released from the wrecks of the Prestige tanker, several years after it sank in November 2002 to depths between 3500 and 3800 m. The released oil reached the surface waters above the wrecks without any signs of weathering and leaving an homogenous signature throughout the water column. At depths of several kilometers below the sea surface, the occurrence and spread of the deep sea oil spill could be evaluated better by quantifying and characterizing the dissolved hydrocarbon signature, rather than just the investigation of hydrocarbons in the suspended particulate matter.