The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

频率域全波形反演方法研究进展

全波形反演是一种利用地震波传播的动力学特征来获取地下介质物性参数的反演方法,可为揭示地下精细结构提供重要依据。本文以弹性波方程作为数学模型来模拟地震波传播规律并进行相应的反演方法研究。为提高计算效率与反演结果的准确性,可将近似解析离散化（NAD）算子用于频率域弹性波方程的正演模拟。本文在频率域NAD离散的基础上推导阻抗矩阵的稀疏分块结构与反演目标函数对模型参数的梯度计算公式,由此建立基于NAD算子的频率域弹性波全波形反演方法。为验证该方法的有效性,文中通过数值实验对多种典型介质模型进行反演计算,均得到了理想的反演结果。

     

Application of saddlepoint approximation in reliability analysis of dynamic systems

The application of the saddlepoint approximation to reliability analysis of dynamic systems is investigated. The failure event in reliability problems is formulated as the exceedance of a single performance variable over a prescribed threshold level. The saddlepoint approximation technique provides a choice to estimate the cumulative distribution function (CDF) of the performance variable. The failure probability is obtained as the value of the complement CDF at a specif ied threshold. The method requires computing the saddlepoint from a simple algebraic equation that depends on the cumulant generating function (CGF) of the performance variable. A method for calculating the saddlepoint using random samples of the performance variable is presented. The applicable region of the saddlepoint approximation is discussed in detail. A 10-story shear building model with white noise excitation illustrates the accuracy and effi ciency of the proposed methodology.     

Microbial community dynamics and biodegradation of polycyclic aromatic hydrocarbons in polluted marine sediments in Hong Kong

Dynamics of microbial community and biodegradation of polycyclic aromatic hydrocarbons (PAHs) in polluted marine sediments, artificially spiked with a mixture of PAHs (fluorene, phenanthrene, fluoranthene and pyrene), were examined for a period of 60 days. Microbial communities were characterised by bacterial counts, ester-linked fatty acid methyl ester (EL-FAME) analysis and denaturing gradient gel electrophoresis (DGGE). A noted reduction in species diversity occurred only in the high PAH level treatment at onset. Both EL-FAME and DGGE demonstrated a marked shift in microbial community, in all the PAH level treatments, afterwards, with increases in the number of fatty acid degraders, the relative abundance of fatty acid biomarkers for gram-negative bacteria and a decrease in species diversity. The shift was also accompanied by the significant decrease in PAH concentrations. By the end of the experiment, diversity indices, based on both approaches, recovered when PAH concentrations declined to their background levels, except in the high PAH level treatment.     

Study on uncertainty of inversion and resolution limit in the presence of noise

This study analyzed the uncertainty of inversion and the resolution limit in the presence of noise by means of statistical experiments. The exhaustive method is adopted to obtain the global optimal solution in each experiment. We found that even with small level of noise, solutions fluctuate in a large range for the thin bed. The distribution of solutions in the presence of noise is closely related to the spread of the cost function in the absence of noise. As a result, the area of a certain neighborhood around the true solution on the spread of the cost function in the absence of noise is used to evaluate the uncertainty of inversion and the resolution limit in the presence of noise. In the case that the SNR (signal-to-noise ratio) is 5 in this study, solutions focus around the true solution with a very small uncertainty only when the bed thickness is greater than the reciprocal of the double predominant frequency of the convoluting wavelet.     

地层证据--对大别造山带汇聚历史的制约

大别造山带的汇聚演化历史一直存在不同的认识,来自扬子陆块和华北陆块显生宙以来的地层记录以及北淮阳地区的地层记录可能为两个陆块的汇聚模式提供制约。通过对扬子陆块与华北陆块显生宙以来岩相古地理进行比较,其中3个阶段相似, 2个阶段差别很大。以浊积岩发育作为俯冲阶段的标志,磨拉石建造出现作为闭合的标志,显生宙以来,大别造山带曾经历了两次俯冲和两次汇聚,俯冲时间分别是晚奥陶世—早志留世和早三叠世,汇聚的时间分别为中 晚泥盆世和中三叠世,早期的汇聚具有软碰撞特征,以上认知得到了北淮阳地区地层、古生物和沉积记录的支持,同时也与大别山造山带榴辉岩的同位素年龄数据基本吻合。高压 超高压变质岩在晚三叠世处于快速折返阶段,早侏罗世以前到达地表,其平均折返隆升速率为39～66mm/a。     

Caledonian Low-Temperature Granulite-Facies Metamorphism in the West Kunlun Orogenic Belt—SHRIMP Chronological Evidence from Zircon

The West Kunlun orogenic belt is located at the conjunction of the paleo-Asian tectonic system and the Tethys tectonic system. Petrological and mineralogical studies of the Early Cambrian metamorphic surface crust in this region have shown that in case the metamorphism reached low-temperature granulate facies, the typical mineral assemblage is biotite-garnet-silimanite-K feldspar-plagioclase-quartz. The peak metamorphic temperatures are within the range of 720–740°C and the pressure is 0.6 GPa ±. Three types of metamorphic zircon have been detected in the metamorphic rocks: the complex inclusion-bearing type ; the early relic zircon inclusion-bearing type; and the inclusion-free type. SHRIMP age determination of these three types of metamorphic zircon have revealed that these zircons were formed principally during 400–460 Ma, indicating that pre-Cambrian metamorphic surface crust rocks underwent low-temperature granulite facies metamorphism during the Caledonian. In combination with the geological characteristics of this region, it is considered that when the oceanic basin was closed, there occurred intense intracontinental subduction (type A), bringing part of the Early Cambrian metamorphic basement in this region downwards to the lower crust. Meanwhile, there were accompanied with tectonic deformation at deep levels and medium- to high-grade metamorphism. This study provided important chronological and mineralogical evidence for the exploration of the evolutionary mechanism and process of the West Kunlun Early Paleozoic. Part of the results from the research project “ Research on the West Kunlun pre-Cambrian tectonic events” under the program “ Research on the important geological problems of China’ s pre-Cambrian” (No. 200113900070) sponsored by the China National Geological Surveying Bureau.     

Impacts of Climatic Factors on Runoff Coefficients in Source Regions of the Huanghe River

Runoff coefficients of the source regions of the Huanghe River in 1956–2000 were analyzed in this paper. In the 1990s runoff of Tangnaihai Hydrologic Station of the Huanghe River experienced a serious decrease, which had at- tracted considerable attention. Climate changes have important impact on the water resources availability. From the view of water cycling, runoff coefficients are important indexes of water resources in a particular catchment. Kalinin baseflow separation technique was improved based on the characteristics of precipitation and streamflow. After the separation of runoff coefficient (R/P), baseflow coefficient (Br/P) and direct runoff coefficient (Dr/P) were estimated. Statistic analyses were applied to assessing the impact of precipitation and temperature on runoff coefficients (including Dr/P, Br/P and R/P). The results show that in the source regions of the Huanghe River, mean annual baseflow coefficient was higher than mean annual direct runoff coefficient. Annual runoff coefficients were in direct proportion to annual pre- cipitation and in inverse proportion to annual mean temperature. The decrease of runoff coefficients in the 1990s was closely related to the decrease in precipitation and increase in temperature in the same period. Over different sub-basins of the source regions of the Huanghe River, runoff coefficients responded differently to precipitation and temperature. In the area above Jimai Hydrologic Station where annual mean temperature is –3.9oC, temperature is the main factor in- fluencing the runoff coefficients. Runoff coefficients were in inverse relation to temperature, and precipitation had nearly no impact on runoff coefficients. In subbasin between Jimai and Maqu Hydrologic Station Dr/P was mainly affected by precipitation while R/P and Br/P were both significantly influenced by precipitation and temperature. In the area be-tween Maqu and Tangnaihai hydrologic stations all the three runoff coefficients increased with the rising of annual precipitation, while direct runoff coefficient was inversely proportional to temperature. In the source regions of the Huanghe River with the increase of average annual temperature, the impacts of temperature on runoff coefficients be-come insignificant.