Thermal decomposition of NH4-analcime

The thermal decomposition of ammonium-exchanged natural analcime is characterized by gas chromatography, IR spectroscopy and X-ray diffraction. The de-ammoniation and dehydroxylation proceed in parallel throughout the decomposition, which evidences the instability of the protonated analcime framework. The mechanism of degassing of NH₄-analcime changes throughout its decomposition. At the initial step, the mechanism of de-ammoniation consists in thermal dissociation of NH₄⁺ molecule onto NH₃ and proton (framework OH group) and diffusion of NH₃ out of the structure. Subsequent decomposition and removal of the OH groups lead to a progressive loss of crystallinity. At this step, an apparent activation energy for NH₃ desorption is estimated to be 145(±13) kJ mol^–1. This value is within the upper limit of the activation energy characteristic for the NH₃ desorption from proton centres in large-pore zeolites. At the final step, the adsorption of NH₃ and protons onto the defect centres in the amorphosed aluminosilicate framework results in a significant increase of an apparent activation energy for the de-ammoniation and dehydroxylation up to 270(±20) kJ mol^–1.     

The Classification of Calcium Phosphates of Phosphorites

Lithology and Mineral Resources -     

Are isolated stable rigid clasts in shear zones equivalent to voids?

Particles in shear enclose important information about a rock's past and can potentially be used to decipher the kinematic history and mechanical behavior of a certain outcrop or region. Isolated rigid clasts in shear zones often exhibit systematic inclinations with respect to the shear-plane at small angles, tending towards the instantaneous stretching direction of the shear zone. This shape preferred orientation cannot be easily explained by any of the analytical theories used in geology. It was recently recognized that a weak mantle surrounding the clast or a slipping clast–matrix interface might be responsible for the development of the observed inclinations. Physical considerations lead us to conjecture that such mantled, rigid clasts can be effectively treated as voids that are not allowed to change their shape. The resulting equivalent void conjecture agrees well with numerical and field data and has the following important geological implications. (i) Clasts in shear zones can have stable positions in simple shear without the requirement of an additional pure shear component. (ii) The stable orientation can be approached either syn- or antithetically; hence, the clast can rotate against the applied shear sense. (iii) The strain needed to develop a strong shape preferred orientation is small (γ≈1) and therefore evaluations based on other theories may overestimate strain by orders of magnitude. (iv) The reconstruction of far-field shear flow conditions and kinematic vorticity analysis must be modified to incorporate these new findings.     

幂函数对建筑物沉降的回归分析

通过实例推导幂函数对建筑物沉降进行回归分析，并且得出较为精确的结果，同时也说明在选择回归函数的时候，还会受到很多条件影响。     

Data Fusion in Distributed Multi-sensor System

This paper presents a data fusion method in distributed multi-sensor system including GPS and INS sensors“ data processing. First, a residual X^2-test strategy with the corresponding algorithm is designed.Then a coefficient matrices calculation method of the information sharing principle is derived. Finally, the federated Kalman filter is used to combine these independent, parallel, real-time data. A pseudolite (PL) simulation example is given.     

图像控制点数据库的设计与实现

地面控制点数据是航天航空图像摄影测量几何处理的必需数据。文中首先比较了控制点数据的存储管理方式，即采用文件系统方式与数据库方式的优缺点；接着分析了控制点图像数据的特征，从而提出了图像控制点数据的数据库存储方案，讨论了图像控制点数据库的查询方法；最后结合文中的方法，设计并且实现了一个控制点图像数据库管理与应用实验系统。通过分析认为，建立控制点图像数据库是重复利用控制点资源的有效途径。     

基于神经网络的建筑物沉降原因分析

在我们应用回归方法对建筑物沉降原因分析及沉降趋势的预测中，由于实际情况的复杂性及主观认识的局限性，这样所得的结果含有较多的人为因素，可能会与实际情况有所差异。针对这种情况，讨论了应用神经网络方法来发现和验证引起建筑物沉降的因素及对沉降趋势的预测。实例表明，该方法能取得较好的效果。     

基于受限汉语的GIS路径重建研究

主要研究基于自然语言 (汉语 )的GIS路径重建问题 ,通过分析带有路径表述信息的汉语文本 ,建立了汉语的NLRP句法模型 ,它是由带有空间语义的动作以及作为动作对象的地理要素构成的集合。考虑到自然语言理解实现的需求 ,论文基于NLRP句法模型定义了受限汉语的NLRP文法 ,在此基础上 ,描述了路径重建算法PRA ,并探讨了算法实现中由于空间认知原因带来的不确定性问题以及其解决方案。最后 ,基于该算法进行了相关实例研究 ,从而验证了该算法的正确性     

Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

The lacustrine sedimentary records of coal-burning atmospheric pollution

With the acceleration of industrialization, coal- burning atmospheric pollution is getting more and more serious in many regions in China. However, there are only about ten odd years literature records about pollution in some large and mid-sized cities, where the atmosphere has perhaps been polluted for several decades, and therefore it is difficult to know the process and characteristic of pollution, and diffi-cult to evaluate its damage to environment. Lacustrine sediment, a natural record w…