内蒙古河套地区土壤环境质量评价

土壤污染已成为抑制农业可持续发展的一个重要因素,土壤环境质量与研究区的地质条件、自然物理化学条件和人类活动有关。以河套地区多目标区域地球化学调查取得的表层土壤元素资料为依据,参照《土壤环境质量标准》(GB15618—1995)中As、Cd、Cr、Cu、Hg、Ni、Pb、Zn分级标准,对研究区土壤的单元素环境质量进行分级并评价。以单元素土壤环境质量分级为基础,以单元素中最差的级别作为该单元土壤环境质量综合分级,评价研究区的土壤综合环境质量。通过单元素评价及综合评价认为,研究区内土壤环境质量总体状况优良,大部分地区为绿色、无公害的环境。     

Magma type and genesis of the basic-ultrabasic layered intrusions in Panzhihua-Xichang area,Southwest China

The layered intrusions in the Panzhihua-Xichang area may be grouped into two types: basic rock masses represented by the Panzhihua rockbody and basic-ultrabasic rock masses represented by the Hongge rockbody. Their major difference lies in that the former has poorly developed ultramafic facies, while the latter is characterized by well developed mafic facies and ultramafic facies. There exists apparent rhythmic stratification in the rock masses, which can be basically divided into four grades in terms of superimposition relationship and multicycle characters. Both direct and indirect evidence suggest that the magma responsible for the layered intrusions in this area should be a transition-type alkaline olivine basalt magma derived directly from partial melting of the upper mantle. In rhythmic cycles of various grades, the magmatic evolution is characterized obviously by periodicity and early enrichment of Fe and Ti, which is evidently different from the evolution of the Skaergaard magma in which Fe and Ti are enriched at the late stage. The FCA diagram can be used to describe the unique evolutionary trend of magma in this area. It is demonstrated in this diagram that the enrichment of Fe and Ti is consistent with the increase of basicity. In the upper magmatic chamber, the evolutionary trend of magma is conditioned by the difference in pressure, and this enables magma to form different types of rock assemblage. In the Fo-Di-An system, when the pressure exceeds 5 x 18⁸ Pa, forsterite is incompatible with anorthite, and the rock facies sequence of Hongge type might form; when the pressure is lower than 5 x 10⁸ Pa, forsterite can coexist with anorthite, and the rock facies sequence of Panzhihua type is likely to form if the magma is relatively rich in Mg and Fe components.     

天然闪锌矿原位高温X射线衍射研究

对天然闪锌矿进行了原位高温X射线衍射实验研究,结果表明：闪锌矿受热膨胀,27～675℃温度范围内其膨胀系数为25.61×10-6℃-1;随着温度的升高,在543℃时产生中间物相Zn3O（SO4）2,并分解产生红锌矿ZnO;在797℃时中间物相完全消失,同时出现尖晶石结构的ZnFe2O4;加热至1160℃时的产物为ZnO和ZnFe2O4。实验表明,天然闪锌矿的热改性可产生一定比例的红锌矿（ZnO）,其与闪锌矿一起形成二元复合半导体。在光的激发下,该半导体体系产生的光生载流子由一种半导体注入另一种半导体,降低了光生电子-空穴对的复合几率,提高其光催化活性。本文的研究可为热改性提高天然闪锌矿光催化活性提供理论依据。     

吉林集安铅锌矿地球化学与分散元素

吉林集安铅锌矿床是我国最早报导的少数几个典型低温铅锌矿床之一。矿化具有多期次特点 ,富矿体都是多期次矿化叠加的产物。根据矿化先后和矿物生成顺序将矿化分为五个阶段 :①石英 黄铁矿矿化阶段 ;②重晶石 闪锌矿矿化阶段 ;③石英 方铅矿矿化阶段 ;④石英 黄铁矿矿化阶段 ;⑤碳酸盐 氧化矿物矿化阶段。用均一法和爆裂法测得石英、重晶石、闪锌矿包裹体成矿温度变化在 1 1 0℃～ 1 97℃之间。矿床中除含铅锌矿外 ,还有微量的Pt和Pd,并普遍含分散元素Cd、Ga、Tl、In、Se、Ge、Te,其中以Cd含量最高 ,闪锌矿中Cd含量最高可达 71 5 5× 1 0 6。分散元素主要呈类质同象形式赋存在各种矿物之中 ,未发现独立矿物。通过矿床地质和硫铅同位素研究表明该铅锌矿床属低温沉积 改造型层控矿床。     

雪冰中的黑碳记录研究的历史回顾

黑碳(Blackcarbon)是一类大气气溶胶,也是重要的气候驱动因子之一,它与人类活动密切相关.迄今发现,雪冰是保存和记录历史时期黑碳变化的最好介质.根据前人对南极冰芯、格陵兰冰芯、中低纬度山地冰川冰芯以及雪坑样品中的黑碳记录的研究成果,讨论了不同研究地区雪冰中黑碳含量的变化,黑碳对气候环境突变、大气环流变化的响应,总结了人类活动与雪冰黑碳记录之间的关系.雪冰黑碳记录还可以获得如森林大火这样的特殊事件的信息.     

莲沱砂岩——南华大冰期前气候转冷的沉积记录

湖北宜昌地区出露的莲沱组中上部细屑岩的化学蚀变指数(CLA)介于60～70之间,表明是在寒冷干燥的气候条件下沉积的。比较莲沱组与板溪群中下部沉积岩的主化学成分和 CIA 值表明,板溪群源区遭受过强烈的化学风化,相应的古气候是温暖湿润的,而莲沱组源区化学风化弱,可见两者形成时的古气候环境明显不同。根据 CIA 值推测,地层层序上莲沱组位于板溪群的中上部,莲沱砂岩的 CIA 研究表明南华大冰期前全球气候已经从温暖湿润转变为寒冷干燥,CIA 值继续降低预示着全球性的冰期到表,不久就发生了"雪球地球"事件。     

Major element geochemistry of purple soils/rocks in the red Sichuan Basin, China: implications of their diagenesis and pedogenesis

Major element compositions and chemical weathering features of the purple soils and their corresponding rocks in the Red Sichuan Basin, China were studied in this paper to infer the diagenetic features of the purple rocks and the pedogenetic features of the purple soils. The results showed that all of the rock and soil samples, except those from Yibin, have strongly similar major element compositions and the distribution patterns of their major element compositions are similar to those of the upper continental crust. Chemical index of alteration, chemical index of weathering and Na₂O/K₂O indicate that the purple soils and rocks have similar chemical weathering intensities, whereas the Al₂O₃–CaO* + Na₂O–K₂O (A–CN–K) relationship, suggests that chemical weathering was strong during diagenesis of the purple rocks, but weak during pedogenesis of the purple soils. Variations in major element compositions of the purplish rock samples, except that from Yibin, do not primarily reflect differences in compositions of the sediment source, sediment recycling and potassium metasomatism, and therefore the effects of chemical weathering on the major element compositions were mainly dependent on climate condition and the residence time of material exposed to chemical weathering. Chemical weathering of the purple rocks reached only moderate degrees under the general influence of warm and humid climate during Jurassic and Cretaceous. Warmer and more humid climate conditions partly resulted in stronger chemical weathering of rocks in the southern region of the basin than in the central and western region, whereas shorter residence time of material in upslope position partly resulted in weaker chemical weathering of rocks in the eastern region than in the central and western region. The same climate and stable tectonic setting led to comparable chemical weathering intensities of rocks in the Ziliujing and Jiaguan Formations. Gradually colder and dryer climate from Early Jurassic to Middle Jurassic then to Late Jurassic and shorter residence time in tectonically active setting of Middle Jurassic and late Late Jurassic resulted in the following order of chemical weathering intensity of the purple Jurassic rocks: Ziliujing Formation ? Shaximiao Formation ≈ Suining Formation > Penglaizhen Formation.     

新疆西准噶尔苏云河钼矿床含矿岩体地球化学和年代学

苏云河钼矿床位于新疆西准噶尔巴尔鲁克山西段,容矿岩石为二长花岗岩和二长花岗斑岩。这些花岗岩具有类似的地球化学特征:富集Rb、Th、U和LREE,相对亏损Ba、P、Ti,属于高钾钙碱性I型花岗岩系列,局部经历过强烈的分离结晶作用。LA-ICPMS锆石U-Pb定年结果显示苏云河钼矿区的成岩年龄为309.3~310.2 Ma,这表明与成矿有关的岩浆活动发生于晚石炭世。黑云母的Ti温度计表明Ⅰ号和Ⅲ号岩体的结晶温度相近,为695~728℃;而Ⅱ号岩体的结晶温度较低,为642~668℃。同时根据角闪石-斜长石压力计获得Ⅰ号和Ⅲ号岩体的结晶压力为(3.0~3.9)×108Pa。综合地球化学研究表明,苏云河钼矿区3个岩体均形成于岛弧环境。此外,以苏云河钼矿床为代表的巴尔鲁克山成矿带与哈萨克斯坦境内的巴尔喀什成矿带在岩石地球化学、成岩成矿时代等方面具有许多类似的特点,表明巴尔鲁克山成矿带可能是巴尔喀什成矿带在中国境内的延伸。     

西藏得几蛇绿岩体中玻安岩的地球化学特征及其地质意义

西藏日喀则蛇绿岩是我国发育最好的蛇绿岩之一，目前有关日喀则蛇绿岩形成的构造背景存在多种不同的认识。作者在研究得几蛇绿岩剖面时发现存在玻安岩，从而为日喀则蛇绿岩具有弧前背景提供了直接证据。得几蛇绿岩中玻安岩类样品具有高硅、高镁、低铁的特征，岩石中Zr、Yb和Y的含量也较低，具有明显的玻安岩特征。根据这些岩石的地球化学性质，认为岩石是由早期经历过较高程度的部分熔融的残余在含水条件下再发生部分熔融形成的。得几蛇绿杂岩体部分形成于弧前环境。     

基于残余强度修正的岩石损伤软化统计本构模型研究

岩石随着围压的增大,残余强度的增加幅度比峰值强度大,残余强度逐渐成为影响岩石全应力-应变曲线峰后段的主要因素,因此,建立岩石损伤软化统计本构模型时,对残余强度进行修正是非常必要的。基于岩石应变强度理论以及岩石微元强度服从Weibull随机分布的假设,考虑岩石峰后残余强度对损伤变量进行修正,在微元破坏符合Hoek-Brown屈服准则条件下,建立了能够反映岩石峰后软化特征的三维损伤统计本构模型;依据岩石试验全应力-应变曲线的几何特征,推导出本构模型参数的数学表达式,并基于花岗岩室内试验数据对模型参数进行探讨,研究了Weibull分布参数与本构模型的关系,探讨了损伤修正系数的取值和岩石累积损伤的扩展过程;将建立的本构模型理论曲线与4种岩石（斑状二长花岗岩、细晶大理岩、砂岩和粉砂质泥岩）不同围压下的常规三轴压缩试验曲线进行对比分析,结果表明,该模型能很好地描述岩石破裂过程的全应力-应变关系和表征岩石残余强度特征。这对于岩石损伤软化问题以及岩石加固处理措施的研究均具有重要的意义。