Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.     

海州湾淤泥质海滩剖面堆积过程的计算模式

分别于1986年12月和1985年3月1日—1987年3月1日在海州湾进行了波浪和含沙量观测，运用所获资料以及本区长期水文、地形资料，采用流体力学、沉积学和泥沙运动力学相结合的研究方法，建立了海州湾淤泥质海滩剖面堆积过程的二维计算模式。结果表明，在堆积型淤泥质海滩，由于浮泥的经常性存在，使波浪急剧衰减，其对岸滩的作用甚为微弱，潮流成为塑造淤泥质海滩的主要动力，岸滩在淤涨过程中，在平均高潮位厂沿和平均低潮位附近出现两个凸点，上一个凸点外推速率大于下一个凸点，潮下带变化缓慢。     

科氏力对河口分汊的影响

以长江口、黄河口、珠江口、闽江口等几个分汊河口为例,分析了科氏力在河口分汊中的作用。结果表明,涨落潮流路分歧主要通过形成涨落潮冲刷槽和中央缓流区浅滩而逐渐使河口产生分汊;水面横比降则以横向环流和横向切滩两种形式,或堆积或冲刷,导致河口分汊。     

长江口海水的密度

为了核对1980年国际海水状态方程应用于中国近岸海水的可靠性,高精度的磁力浮沉子密度计在15—25℃,盐度5—35,一个大气压条件下,测量了长江口附近海水及其人工稀释海水的相对密度。结果表明,海水密度直接测量值系统地偏高于状态方程计算值,二者之间的偏差随水样盐度值降低而增大,且与海水[Ca~(2+))/s比值成明显正相关关系。经计算机拟合,导出了长江口附近海水及其稀释海水的状态方程,该方程计算值与实验值的平均标准偏差为±3.9×10~(-3)kg/m~3。     

长江口南港水道潮流特征分析

根据１９９６年长江口南港水道枯、丰水期（１月、７月）大、中、小潮两次各２６ｈ以上的全潮水文实测资料,统计分析了实测流的特征和潮流类型、运动形式、潮流垂直变化、余流、Ｍ２分潮流及分潮流对涨、落潮流不等的影响。     

Instrumentation and Numerical Analysis of Cylindrical Diaphragm Wall Movement During Deep Excavation at Coastal Area

The lateral deflection of a cylindrical diaphragm wall and the associated ground movement induced by deep excavation are analyzed by performing site instrumentations and numerical analyses in the coastal area of Korea. Wall lateral deflection, rebar stress, and pore water pressure were measured and analyzed in eight directions. Variations of soil properties with the decrease of confining pressure are compared by performing various in situ tests before ad after excavation. To calculate the wall lateral deflection accurately, the effects of small strain nonlinearity, confining pressure, and the hysteresis loading/unloading loop developed during excavation are considered in the proposed numerical analysis. By comparing numerical results with measured ones, the importances of considering small strain nonlinearity and confining pressure reduction in the nonlinear (FEM) are emphasized. Also, the effects of wall stiffness on the performance of cylindrical diaphragm walls are studied for future similar excavation in the coastal area.     

Changing anthropogenic influence on the Santa Monica Bay watershed

Santa Monica Bay is an open coastal embayment located directly seaward of Los Angeles, California. The Bay provides vital economic value through its water-dependent activities, such as swimming, diving, boating, and fishing. An increase from 100,000 residents in 1900 to 10 million in 2000 has imposed numerous environmental stressors on the Bay, including urbanization of the watershed. Pollutant discharges into the Bay increased throughout the early part of the century, but declined following passage of the Clean Water Act in 1972. Since that time, the predominant source of pollutant inputs has changed from point sources to non-point urban runoff. To assess how present-day and historical pollution interact to affect the environmental quality of Santa Monica Bay, three organizations collaborated on a multi-disciplinary study in 1997, towards which this volume is focused. This paper details the temporal patterns of anthropogenic influence on Santa Monica Bay to provide context for the papers that follow.     

The origin and biogeochemistry of organic matter in surface sediments of Lake Shihwa and Lake Hwaong

To understand the origin and biogeochemistry of the organic matter in surface sediments of Lake Shihwa and Lake Hwaong, organic nitrogen, inorganic nitrogen, labile organic carbon, and residual organic carbon contents as well as stable isotope ratios for carbon and nitrogen were determined by KOBr-KOH treatment. Ratios of organic carbon to organic nitrogen (C_org/N_org) (mean = 24) were much higher than ratios of organic carbon to total nitrogen (C_org/N_tot) (mean=12), indicating the presence of significant amounts of inorganic nitrogen in the surface sediments of both lakes. Stable isotope ratios for organic nitrogen were, on average, 5.2‰ heavier than ratios of inorganic nitrogen in Lake Shihwa, but those same ratios were comparable in Lake Hwaong. This might be due to differences in the origin or the degree of degradation of sedimentary organic matter between the two lakes. In addition, stable isotope ratios for labile organic carbon were, on average, 1.4‰ heavier than those for residual organic carbon, reflecting the preferential oxidation of¹³C-enriched organic matter. The present study demonstrates that KOBr-KOH treatment of sedimentary organic matter can provide valuable information for understanding the origin and degradation state of organic matter in marine and brackish sediments. This also suggests that the ratio of C_org/N_org and stable isotope ratios for organic nitrogen can be used as indexes of the degree of degradation of organic matter.     

Fault Characteristics in Longmen Mountain Thrust Belt,Western Sichuan Foreland Basin,China

Through field geological survey,the authors found that abundant thrust faults developed in the Longmen (龙门) Mountain thrust belt.These faults can be divided into thrust faults and strike-slip faults according to their formation mechanisms and characteristics.Furthermore,these faults can be graded into primary fault,secondary fault,third-level fault,and fourth-level fault according to their scale and role in the tectonic evolution of Longmen Mountain thrust belt.Each thrust fault is composed of several secondary faults,such as Qingchuan (青川)-Maowen (茂汶) fault zone is composed of Qiaozhuang (乔庄) fault,Qingxi (青溪) fault,Maowen fault,Ganyanggou (赶羊沟) fault,etc..The Longmen Mountain thrust belt experienced early Indosinian movement,Anxian (安县) movement,Yanshan (燕山)movement,and Himalayan movement,and the faults formed gradually from north to south.     

一种新型遥感影像快速匹配算法(英文)

An iterative algorithm to calculate mutual correlation using hierarchical key points and the search space mark principle is proposed. An effective algorithm is designed to improve the matching speed. By hierarchical key point algorithm and mutual correlation coefficients of the matching images, the important points can be iteratively calculated in the images hierarchically, and the correlation coefficient can be obtained with satisfactory precision. Massive spots in the parameter space which are impossible to match can be removed by the search space mark principle. Two approximate continuities in the correlation image matching process, the image gray level distribution continuity and the correlation coefficient value in the parameter space continuity, are considered in the method. The experiments show that the new algorithm can greatly enhance matching speed and achieve accurate matching results.